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化学学报
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化学学报 ›› 1987, Vol. 45 ›› Issue (8): 805-807. 上一篇    下一篇

研究论文

气液色谱法测定一些Lewis碱与Ni(ENAC).H2O的加合常数

游效曾;施舒;余晓斌   

  1. 南京大学配位化学研究所
  • 发布日期:1987-08-15

The determination of stability constants for adducts of several Lewis bases with Ni(ENAC).H2O by gas-liquid chromatography

YOU XIAOZENG;SHI SHU;YU XIAOBIN   

  • Published:1987-08-15

PDF

416

被引次数

3

关键词: 气液色谱, 戊二酮 P, 过渡金属络合物, 镍络合物, 席夫碱, 甲胺 P, 角鲨烷, 配位场理论, 络合常数, 电子给予体

Apparent partition coefficient (KR) and real partition coefficient (KR0) of some aliphatic alcs. and amines in squalane and stability constants (K1) of adducts between these Lewis bases and Ni{[CH3COCHC(CH3)=CH2]2}.H2O in squalane solution are reported. KR0 Made more contribution to KR. The values of both KR and KR0 increased with increasing C nos. in a homologous series of the bases, but K1 changed reversely. The possible reasons for these changes were discussed.

Key words: GAS LIQUID CHROMATOGRAPHY, PENTANEDIONE P, TRANSITION METAL COMPLEX, NICKEL COMPLEX, SCHIFF BASE, METHANAMINE P, SPINACANE, LIGAND FIELD THEORY, COMPLEX CONSTANT, ELECTRON DONOR

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