关键词: 氧化还原反应, 红外分光光度法, 钼络合物, 过氧化物, 恒电位器, 循环伏安法, 钨络合物, 分解电位, 拉曼光谱法

K4Mo4O12(O2)2 and K4W4O12(O2)2.4H2O were prepared from K2MoO4 or K2WO4, resp., and H2O2 at pH 7.3. The products were characterized by IR, Raman and cyclic voltammetry studies. Both compounds were reduced at a Pt electrode vs. SCE at E1 = 0.317, 0.172 V, resp. and E2 = 0.226, <-0.2 V, resp. They were oxidized at E3 = 0.862, 0.786 V, resp. The Mo compound decomposed after a 1-electron reduction Both compounds decomposed after the 4-electron oxidation at E3.

Key words: OXIDATION REDUCTION REACTION, INFRARED SPECTROPHOTOMETRY, MOLYBDENUM COMPLEX, PEROXIDE, POTENTIOSTAT, CYCLOVOLTAMGRAPH, TUNGSTEN COMPLEX, DECOMPOSITION ELECTRIC POTENTIAL, RAMAN SPECTROMETRY