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化学学报
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化学学报 ›› 1991, Vol. 49 ›› Issue (12): 1450-1456. 上一篇    下一篇

研究论文

新型Pd系聚吡咯配合物的合成、结构和吸附行为的研究

高扬;苏锋;刘尚长;吴林友;于保强;张德奇   

  1. 辽宁大学化学系.沈阳(110036)
  • 发布日期:1991-12-15

Studies on the synthesis, structure and adsorption behaviors of a new palladium bipyrrole complex

Gao Yang;Su Feng;Liu Shangchang;Wu Linyou;Yu Baoqiang;Zhang Deqi   

  1. Liaoning Univ, Dept Chem.Shenyang(110036)
  • Published:1991-12-15

PDF

572

被引次数

4

本文首次报道了一种新的二氯-二聚吡咯合钯(简称DCBPP)配合物的合成、结构和吸附H~2行为的实验和理论研究。确定了DCBPP的稳定性结构,探究了吸附过程的表面行为和微观机制,理论计算和实验测定的结果符合较好,圆满合理地说明一些实验现象。

关键词: 合成, 络合物, 聚吡咯, 结构, 行为, 吸附, 吸附过程, 稳定性

Studies on synthesis, stracture of a new palladium dichloride bipyrrole complex (DCBPP) and its adsorption behaviors for H~2 are first reported. The macrophenomenon and micromechanisum of the adsorption of H~2 on DCBPP are discussed. The theoretic calculations are good in agreement with the experimental determinations. The experimental phenomena are explained resonably and satisfactorily.

Key words: SYNTHESIS, COMPLEX COMPOUNDS, POLYPYRROLE, STRUCTURE, BEHAVIOR, ADSORPTION, ADSORPTION PROCESS, STABILITY

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