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化学学报
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化学学报 ›› 1994, Vol. 52 ›› Issue (2): 150-154. 上一篇    下一篇

研究论文

二维聚硫杂酞菁铜的合成与性质

陈晓贵;彭正合;秦子斌   

  1. 武汉大学化学系;南京大学配位化学国家重点实验室
  • 发布日期:1994-02-15

Synthesis and properties of two dimensional poly (copper- octathiotetraazaporphyrin)

CHEN XIAOGUI;PENG ZHENGHE;QIN ZIBIN   

  • Published:1994-02-15

PDF

409

被引次数

14

以四氰基-1,4-二噻英为原料,分别用无溶剂法和溶剂法合成了平面稠合型网状聚硫杂酞菁铜PCuS~8Pc(A)和(B),经元素分析,热谱,IR, 电子吸收与发射光谱表征.PCuS~8Pc具有光敏性和本征半导体性能,σ~2~9~8~K(A):2.29×10^-^6Ω^-^1 ·cm^-^1,(B):5.83×10^-^6Ω^-^1·cm^-^1

关键词: 铜络合物, 氰基, 杂环高聚物, 导电性, 电子吸收光谱, 网状聚合物, 二噻英 P, 电子发射光谱, 聚硫杂酞菁铜

Two-dimensional poly(copper octathiotetraazaporphyrins), A and B, were prepared by treating 2,3,5,6-tetracyano-1,4-dithiin with Cu(AcAc)2 in vacuo or with CuCl2 in quinoline, resp. The polymers were characterized by elemental anal., TG-DTA, IR, UV, and fluorescence spectra. At room temperature in H2SO4 A fluoresces intensively at 300 ~ 520 nm under UV light. A semiconduction study yielded s298K = 2.29 ?10-6 W-1 cm-1, and 5.83 ?10-6 W-1 cm-1 for A and B, resp.

Key words: COPPER COMPLEX, CYANO GROUP, HETEROCYCLIC POLYMER, ELECTRICAL CONDUCTIVITY, NETWORK POLYMER

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