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化学学报
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化学学报 ›› 1995, Vol. 53 ›› Issue (8): 812-815. 上一篇    下一篇

研究论文

C60与环己烷及环己烯离子体系的气相反应

刘子阳;A郝国仑;郭兴华;刘淑莹   

  1. 中国科学院长春应用化学研究所
  • 发布日期:1995-08-15

Gas-phase reactions of C60 with the ion systems of cyclohexane and cyclohexene

LIU ZIYANG;A郝国仑;GUO XINGHUA;LIU SHUYIN   

  • Published:1995-08-15

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418

被引次数

2

在气相条件下研究了C60与环己烷及环己烯的离子-分子反应。C60可与上述体系中多种离子发生反应, 生成相应的加合离子, 表现出C60化学性质的活泼性和多样性。C60与C4H7^+和C5H7^+离子反应可能生成[2+4]环加成的加合离子。

关键词: 环己烷, 环己烯, 气相反应, 富勒烯, 离子－分子反应

The DCI MS of C60 with the reactions of gaseous cyclohexane and cyclohexene have been studied. Several kinds reactions of C60 have been observed. The results show that the gas-phase C60 has very active chemical properties. The adduct ions of [C60C4H7]^+ and [C60C5H7]^+ may be formed by [2+4] cycloaddition where one of double bonds of C60 acted as dienophilic unit.

Key words: CYCLOHEXANE, CYCLOHEXENE, GAS PHASE REACTION, FULLERENES

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