化学学报 ›› 2001, Vol. 59 ›› Issue (8): 1163-1164.    下一篇

研究论文

H3+nPMo12-nVnO40(n=0,1)掺杂聚苯胺功能材料新的 制备方法及性质

王守国;赫泓;崔秀君;龚剑;瞿伦玉   

  1. 东北师范大学化学学院
  • 发布日期:2001-08-15

New preparation method and properties of polyaniline function materials doped with H3+nPMo12-nVnO40(n=0,1)

Wang Shouguo;He Hong;Cui Xiujun;Gong Jian;Qu Lunyu   

  • Published:2001-08-15

本文用一种新的合成方法,即不用其他质子酸和氧化剂,利用H3PMo12O40·nH2O和H4PMo11VO40·nH2O杂多酸独特的性质—集质子酸和氧化性于一身,将HPA直接与苯胺作用,制备了仅以杂多阴离子为唯一掺杂抗衡离子的PANI/HPA掺杂材料。所合成的材料具有导电性和荧光性。

关键词: 聚苯胺, 导电性, 荧光材料, 无机材料, 合成法, 杂多酸, 掺杂效应

Polyaniline function materials doped with H3+nPMo12- nVnO40(n=0,1) have been prepared by a new method where in the heteropolyacid acts as both proton acid and oxidizer without using other proton acid and oxidizer during the synthesis reaction. These materials were characterized by IR, Vis-NIR, 31^P NMR, XRD. The materials exhibit conductivity and fluorescence property.

Key words: POLYANILINE, ELECTRICAL CONDUCTIVITY, FLUORESCENCE MATERIALS, INORGANIC MATERIALS, SYNTHESIS METHODS, HETEROPOLYACID, DOPE EFFECT

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