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化学学报
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化学学报 ›› 2002, Vol. 60 ›› Issue (8): 1465-1472. 上一篇    下一篇

研究论文

一维链状冠醚配合物[K(B18-C-6)]_2[M(SCN)_4](M=Pd,Pt)的合成与结构

李增新;张子红;王彤;李大成;王大奇;窦建民;郑培菊   

  1. 青岛大学师范学院化学系,青岛(266071);聊城师范学院化学系, 聊城(252000);复旦大学分析测试中心.上海(200433)
  • 发布日期:2002-08-15

One-Dimensional Chain Crown Ether Complexes: Syntheses and Crystal Structures of [K(B18-C-6)]_2[M(SCN)_4] (M = Pd, Pt)

Li Zengxin;Zhang Zihong;Wang Tong;;Wang Daqi;Dou Jianmin$DZheng Peiju   

  1. Department of Chemistry, Qingdao Teacher's College, Qingdao University,Qingdao(266071);Department of Chemistry, Liaocheng Teacher's University,Liaocheng(252000);Li Dacheng,Liaocheng(252000)$DResearch Center of Analysis and Measurement, Fudan University(200433)
  • Published:2002-08-15

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679

被引次数

21

合成了苯并18-冠-6（B18-C-6）与K_2[Pd(SCN)_4]生成的配合物[K（B18-C-6 ）]_(12) [Pd(SCN)_4] (1), [K(B18-C-6)]_2[Pt(SCN)_4] (2)和[K(B18-C-6)]_2 [Pt(SCN)_4]·C_2H_4Cl_2 (3)，并通过元素分析、红外光谱、单晶X射线衍射进行 了表征。1和2为单斜晶系，空间群P2_l/n，晶体学数据：1， a = 1.00970(17) nm, b = 1.3157(2) nm, c = 1.7303(3) nm, β = 94.841(2)°, V = 2.2852(7) nm~3, Z = 2, F(000) = 1136, R_1 = 0.0257。3为三斜晶系，空间群P1，晶体学 数据：a = 0.95914(18) nm, b = 1.2137(2) nm, c = 2313(2) nm, α = 63.693 (2)°, β = 76.293(2)°, γ-1.2406(4) n~3, Z = 1 F(000)618,R_1 = 0.0366 。在固态，三个配合物相邻的两个[K（B18-C-6）]~+基团通过冠醚氧化原子与钾的 子的相边接而形成一维链状结构。

关键词: 冠醚, 晶体结构, 钯络合物, 元素分析, 红外分光光度法, X射线衍射分析, 结构表征

The reactions of benzo-18-crown-6 (B18-C-6) with K_2[M(SCN)_4] (M = Pd, Pt)were studied and the complexes [K(B18-C-6)]_2 [Pd(SCN)]_4 (1), [K(B18-C-6)]_2 [Pt(SCN)_4] (2) and [K(B18-C-6)]_2[Pt(SCN_4]·C_2H_4Cl_2] (3) were characterized by elemental analysis, IR and X-ray diffraction analysis. 1 and 2 belong to monoclinic, space group P2_l/n with crystal data: 1, a = 1.00970(17) nm, b = 1.3157(2) nm, c = 1.7303(3) nm, β = 94.954(2)°, V = 2.2902(7) nm~3, Z = 2, F(000) = 1072, R_1 = 0.0627; 2, a = 1.00908(18) nm, b = 1.3124(2) nm, c = 1.7317(3) nm, β = 94.841(2)°, V = 2.2852(7) nm~3, Z = 2, F(000) = 1136, R_1 = 0.0257. 3 belongs to triclinic, space group P1 with crystal data: a = 0.95914 (18) nm, b = 1.2137(2) nm, c = 1.2313(2) nm, α = 63.693(2)°, β = 76. 293(2)°, γ = 78.353(2)°, V=1.2406(4) nm~3, Z = 1, F(000) = 618, R1 = 0.036. In the solid state, the complexes exhibit one-dimensional chain structure of two [K(B18-C-6]~+ complex cations bridged by K atom and O atom of crown ether between adjacent complex cations.

Key words: CROWN ETHER, CRYSTAL STRUCTURE, PALLADIUM COMPLEX, ELEMENTAL ANALYSIS, IR, XRD, STRUCTURE CHARACTERISTICS

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