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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (13): 1237-1241. 上一篇    下一篇

研究论文

嵌入式超薄碳糊膜银离子传感器的研究

汪振辉, 赵志娟, 张玲玲, 赵凤娟, 郭国强, 周漱萍   

  1. 河南师范大学化学与环境科学学院, 河南省高校环境科学与工程重点学科开放实验室, 新乡, 453002
  • 投稿日期:2003-09-01 修回日期:2003-12-11 发布日期:2014-02-17
  • 通讯作者: 汪振辉,E-mail:wang728@public.xxptt.ha.cn E-mail:wang728@public.xxptt.ha.cn
  • 基金资助:
    河南省自然科学基金(No.311021000)、河南省高校环境科学与工程重点学科开放实验室资助项目.

Study of the Inlaid Super-thin Carbon Paste Film Silver Ion Sensor

WANG Zhen-Hui, ZHAO Zhi-Juan, ZHANG Ling-Ling, ZHAO Feng-Juan, GUO Guo-Qiang, ZHOU Shu-Ping   

  1. College of Chemistry and Environmental Science, Key Laboratory of Environmental Science and Engineering, Education Commission of Henan Province, Henan Normal University, Xinxiang 453002
  • Received:2003-09-01 Revised:2003-12-11 Published:2014-02-17

PDF

497

被引次数

14

研制了一种新颖的超薄碳糊膜银离子传感电极.在镍铬合金基体上通过嵌入碳糊薄膜而制得该电极.用电位法研究了电极的响应特性,电极电位E(mV)与银离子浓度在1.0×10-6～1.0×10-2 mol/L范围内呈良好的线性关系,相关系数为0.9998,检测限为6.0×10-7 mol/L,对银离子的响应斜率为58.3～60.3 mV/(-logcAg+).电极制作简单、费用很低、稳定性良好,可用作银离子指示电极.

关键词: 超薄碳糊膜电极, 传感器, 嵌入式电极

A novel super-thin carbon paste film electrode was introduced as a silver ion sensor.The electrode was prepared by inlaying carbon paste onto the surface of nickel-chromium substrate.The electrode response characteristics were investigated by potentiometry.The calibration curve of the electrode shows a linear potentiometric response to Ag+ in the range of 10-6～10-2 mol/L with a slope of 58.3～60.3 mV/(-logcAg+).The limit of detection is 6.0×10-7 mol/L.The electrode described in this paper is very simple, stable and unexpensive.It was used as an indicator electrode for the determination of Ag+.

Key words: super-thin carbon paste film electrode, sensor, inlaid electrode