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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (24): 2425-2430. 上一篇    下一篇

研究论文

具有手性侧链的卟啉液晶化合物的合成和发光性能研究

骆开均1,2, 谢明贵1, 蒋青1, 邹德春3   

  1. 1. 四川大学化学学院, 成都, 610016;
    2. 四川师范大学分析测试中心, 成都, 610066;
    3. 北京大学化学与分子工程学院, 北京, 100871
  • 投稿日期:2004-04-28 修回日期:2004-07-05 发布日期:2014-02-17
  • 通讯作者: 蒋青,E-mail:jiangq@scu.edu.cn E-mail:jiangq@scu.edu.cn
  • 基金资助:
    国家自然科学基金(No.20102004)资助项目.

Synthesis of Liquid Crystal Porphyrin Compounds with Chiral Side Chains and Their Luminescent Characterization

LUO Kai-Jun1,2, XIE Ming-Gui1, JIANG Qing1, ZOU De-Chun3   

  1. 1. College of Chemistry, Sichuan University, Chengdu 610016;
    2. Testing Center, Sichuan Normal University, Chengdu 610066;
    3. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871
  • Received:2004-04-28 Revised:2004-07-05 Published:2014-02-17

PDF

286

被引次数

13

通过在卟啉环上引入手性侧链的方法合成了两类(4个)卟啉液晶化合物,并用元素分析,UV-vis, FT-IR, 1H NMR, MS, DSC,圆二色谱(CD)和偏光显微镜对化合物的结构进行了表征.研究结果表明,这些化合物具有液晶性质,固体荧光和电致发光性质,其中两个卟啉配体有较强的CD吸收性能.

关键词: 卟啉液晶, 合成, 圆二色谱(CD), 光致发光(PL), 电致发光(EL)

Two series of liquid crystal tetraporphyrins with chiral side chains were synthesized. Their structures were characterized by elemental analysis, UV-vis, FT-IR, 1H NMR, MS, DSC and CD. The results show that they have the liquid crystal, solid photoluminescent and electroluminescent properties. Among them, two porphyrin compounds have the strong cotton absorption effect.

Key words: porphyrin liquid crystal, synthesis, circular dichroism(CD), photoluminescence(PL), electroluminescence(EL)