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化学学报
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化学学报 ›› 2005, Vol. 63 ›› Issue (14): 1365-1370. 上一篇    下一篇

研究论文

反胶束模板制备聚甲基丙烯酸甲酯/无机纳米粒子/石墨纳米复合材料及其表征

莫尊理*1 2，孙银霞1，陈红1，王坤杰1，刘艳芝1，李贺军2   

  1. (1西北师范大学化学化工学院 兰州 730070)
    (2西北工业大学材料科学与工程学院 西安 710072)
  • 投稿日期:2004-08-26 修回日期:2005-03-14 发布日期:2010-12-10
  • 通讯作者: 莫尊理

Synthesis of PMMA/Inorganic Nanoparticle/EG Nanocomposite through Reverse Micelle Template and Its Characterization

MO Zun-Li*1,2, SUN Yin-Xia1, CHEN Hong1, WANG Kun-Jie1, LIU Yan-Zhi1, LI He-Jun2   

  1. (1 College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070)
    (2 College of Material Science and Engineering, Northwestern Polytechnical University, Xi'an 710072)
  • Received:2004-08-26 Revised:2005-03-14 Published:2010-12-10
  • Contact: MO Zun-Li

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1915

被引次数

53

以甲基丙烯酸甲酯(MMA)和三氯甲烷(CHCl3)为油相制备反胶束微乳液, 依靠表面活性剂十六烷基三甲基溴化铵(CTAB)自组装形成的“微反应器”作为模板成功地制备了PMMA/Eu(OH)3/EG和PMMA/Ni(OH)2/EG纳米复合材料. 并用红外光谱(IR)、扫描电镜(SEM)、透射电镜(TEM)、X射线衍射(XRD)和差热-热重(TG-DTA)对该复合材料进行了表征和分析. 研究结果表明, 反胶束法可以有效地应用于有机-无机纳米复合材料的制备.

关键词: 膨胀石墨, 甲基丙烯酸甲酯, 纳米复合材料, 反胶束

The PMMA/inorganic nanoparticle/EG nanocomposite was prepared by polymerization of methyl methacrylate (MMA) in situ through reverse micelle template, in which the methyl methacrylate (MMA) and CHCl3 was used as oily phase. The advantage of this method is that nanocomposites were prepared without the process of modification of nanoparticles with organic substance and dispersion of them in the matrix. The morphology of nanocomposites was observed by scanning and transmission electron microscope methods. The structures were determined by IR spectra, X-ray diffraction analysis and TG-DTA. These results show that reverse micelle is an effective method for preparing organic-inorganic nanocomposites.

Key words: expanded graphite, methyl methacrylate, nanocomposite, reverse micelle