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化学学报
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化学学报 ›› 2008, Vol. 66 ›› Issue (1): 1-4.    下一篇

研究通讯

新型添加剂全氟辛酸铵对提高锂离子电池安全性能的研究

黄倩，严曼明，江志裕*   

  1. (复旦大学化学系 上海市分子催化和功能材料重点实验室 上海 200433)
  • 投稿日期:2007-05-30 修回日期:2007-07-13 发布日期:2008-01-14
  • 通讯作者: 江志裕

Study on a Novel Electrolyte Additive Ammonium Perfluorocaprylate to Improve the Safety of Lithium-ion Battery

HUANG Qian YAN Man-Ming JIANG Zhi-Yu*   

  1. (Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433)
  • Received:2007-05-30 Revised:2007-07-13 Published:2008-01-14
  • Contact: JIANG Zhi-Yu

PDF

765

被引次数

22

报导可显著提高锂离子电池安全性的新型电解液添加剂全氟辛酸铵(APC). UL 94 可燃性试验显示添加0.70 wt% APC能使有机电解液的火焰传播速率下降33%. 差示扫描量热法(DSC)测试表明APC显著减弱了嵌锂碳电极和电解液之间的放热反应, 并将其热不稳定温度由138.0 ℃提高到167.5 ℃. 交流阻抗检测显示APC的加入明显降低了碳材料电极的界面阻抗, 并且提高了在储存过程中其固态电解质界面(SEI)层的稳定性. 添加APC还能有效地提高Li/MCMB电池充放电循环性能和库仑效率.

关键词: 锂离子电池, 电解液添加剂, 全氟辛酸铵, 阻燃剂

This paper firstly revealed that the safety of lithium-ion battery could be greatly improved by using a novel electrolyte additive: ammonium perfluorocaprylate (APC). In a UL 94 flammability test, even with APC concentration in an organic electrolyte as low as 0.70 wt%, the flame propagation rate was significantly decreased by about 33%. The differential scanning calorimetry (DSC) analysis showed that less heat released in the reaction between lithiated Mesocarbon microbead (MCMB) anode and electrolyte, and the thermal unstable temperature of electrolyte increased from 138.0 to 167.5 ℃ by adding APC in the electrolyte. A lower charge-transfer resistance of an MCMB anode and a higher stability of SEI film were well determined by EIS in the APC-containing electrolyte system. The Li/MCMB cell with additive APC presented better capability of capacity retention and charge-discharge coulombic efficiency in cycling testing.

Key words: lithium-ion battery, electrolyte additive, ammonium perfluorocaprylate, flame-retardant