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化学学报
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化学学报 ›› 2008, Vol. 66 ›› Issue (4): 492-495. 上一篇    

研究简报

新型葡萄糖氮苷化合物的合成与表征

王小明1,2, 李耀先1, 刘昊琰2, 李鑫源2, 杨永华2, 贾高峰2, 张锁秦*,1   

  1. (1吉林大学化学学院有机化学系 长春 130021)
    (2南京大学生命科学学院 医药生物技术国家重点实验室 南京 210093)
  • 投稿日期:2007-06-20 修回日期:2007-09-06 发布日期:2008-02-28
  • 通讯作者: 张锁秦

Synthesis and Characterization of Novel N-Glucoside

WANG Xiao-Ming1,2; LI Yao-Xian1; LIU Hao-Yan2; LI Xin-Yuan2; YANG Yong-Hua2; JIA Gao-Feng2; ZHANG Suo-Qin*,1   

  1. Bromo-pendimethalin was prepared by radical brominating reaction from starting material of pendimethalin, and then reacted with 2,3,4,6-tetra-O-actyl-β-glycosyl amine to obtain the novel N-glucoside, and characterized by NMR and mass spectra.
  • Received:2007-06-20 Revised:2007-09-06 Published:2008-02-28
  • Contact: ZHANG Suo-Qin

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906

被引次数

5 | 1

通过自由基溴代反应得到活性中间体溴代二甲戊乐灵, 再以2,3,4,6-四-O-乙酰化-β-葡萄糖胺亲核取代得到一种新型糖苷化合物, 产物经MS和NMR进行表征.

关键词: 二甲戊乐灵, 溴代反应, 葡萄糖氮苷, 合成

Bromo-pendimethalin was prepared by radical brominating reaction from starting material of pendimethalin，and then reaction with 2,3,4,6-tetra-O-actyl-β-glycosyl amine obtained the Novel N-glucoside，and characterized by NMR and mass spectra.

Key words: pendimethalin, brominating reaction, N-glucoside, synthesis