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化学学报
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化学学报 ›› 2007, Vol. 65 ›› Issue (12): 1140-1148. 上一篇    下一篇

研究论文

氢键稳定的苯并菲盘状液晶的合成及介晶性

余文浩, 赵可清*, 汪必琴, 胡平   

  1. (四川师范大学化学与材料科学学院 成都 610066)
  • 投稿日期:2006-09-21 修回日期:2007-01-24 发布日期:2007-06-28
  • 通讯作者: 赵可清

Synthesis and Mesomorphism of Hydrogen-bonding Stabilized Triphenylene Discotic Liquid Crystals

YU Wen-Hao; ZHAO Ke-Qing*; WANG Bi-Qin; HU Ping   

  1. (College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066)
  • Received:2006-09-21 Revised:2007-01-24 Published:2007-06-28
  • Contact: ZHAO Ke-Qing

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1172

被引次数

47 | 9

盘状液晶分子能自组装成高度有序的六方柱状介晶相. 其各向异性的载流子高速迁移率使其成为较理想的有机光电子材料. 采用分子间氢键锚定柱状相, 获得介晶相温度范围宽、有序度高的苯并菲盘状液晶是本研究的目的. 本文通过分子设计, 合成了3个系列, 共18个有两种不同软链的苯并菲盘状液晶化合物C18H6(OR)5(OCH2COOEt), C18H6(OR)5(OCH2COOBu)和C18H6(OR)5(OCH2CONHBu), 其中R＝CnH2n＋1, n＝4～9. 化合物的纯度和结构通过1H NMR和元素分析确证. 化合物热稳定性通过热重分析(TGA)测定, 并显示出较高的热稳定性. 通过偏光显微镜(POM)和差示扫描量热法(DSC)对这些化合物的热致液晶性进行了研究. 结果显示对于分子中含有酰胺基的苯并菲液晶化合物C18H6(OR)5(OCH2CONHBu), 与具有同样软链长度的分子中不含酰胺键的化合物系列C18H6(OR)5(OCH2COOBu)相比较, 前者由于柱内分子间氢键的形成, 具有更高的熔点和清亮点.

关键词: 苯并菲, 盘状液晶, 柱状相, 分子间氢键, 柱状相锚定

Discotic liquid crystals self-assemble to highly ordered hexagonal columnar mesophase (Colho) and exhibit anisotropic high charge carrier mobility, and can be used as organic opto-electronic materials. Hydrogen bonding stabilized triphenylene discotic liquid crystals with ordered Colho phases and wider mesophase ranges are the goals of present research. In this paper, three series with total of eighteen triphenylene discotic liquid crystalline compounds possessing two different kinds of peripheral chains, which are abbreviated as C18H6(OR)5(OCH2COOEt), C18H6(OR)5(OCH2COOBu) and C18H6(OR)5- (OCH2CONHBu), R＝CnH2n＋1, n＝4～9, were synthesized. The structural characterization of these compounds was carried out with 1H NMR and elemental analysis. The thermal gravimetry analysis showed that all these compounds had good thermal stability up to 300 ℃. Their thermotropic liquid crystal properties were studied through polarized optical microscopy and differential scanning calorimetry. The results showed that, for compounds C18H6(OR)5(OCH2CONHBu) and C18H6(OR)5(OCH2COOBu), the former has higher melting and clearing points than the latter due to the intra-columnar intermolecular hydrogen bonding.

Key words: triphenylene, discotic liquid crystal, columnar mesophase, intermolecular hydrogen bonding, anchorage of columnar mesophase