化学学报 ›› 1994, Vol. 52 ›› Issue (9): 902-909. 上一篇    下一篇

研究论文

气相色谱柱温的智能最佳化I. 理论基础

许国旺;张玉奎;卢佩章   

  1. 中国科学院大连化学物理研究所;国家色谱研究分析中心
  • 发布日期:1994-09-15

Intelligent optimization of column temperatures in gas chromatography.I.theory

XU GUOWANG;ZHANG YUKUI;LU PEIZHANG   

  • Published:1994-09-15

本文提出了智能最佳化气相色谱柱温的理论基础, 解决了最佳温度求解区间及控温方式的预测、 最难分离物质对及交叉点的预测、围绕最难分离物质对及交叉点的最佳化分离温度的预测三个问题, 为智能最佳化柱温程序奠定了基础。

关键词: 气相色谱, 柱温, 智能最佳化

This paper gives the theory on intelligent optimization of column temps. in a given gas chromatog. column system. Based on the structure-retention relation between solutes and solvents, and the dependence of retention values on temps., most difficult separating component pairs and temperature separability range can be predicted, ideal optimum temperature programming, in which every step is determine by a most difficult separating component pair, can be further obtained.n

Key words: GAS CHROMATOGRAPHY, COLUMN TEMPERATURE

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