化学学报 ›› 1994, Vol. 52 ›› Issue (3): 285-289. 上一篇    下一篇

研究论文

超微盘电极上准稳态可逆波循环伏安法理论

张祖训   

  1. 南京大学化学系
  • 发布日期:1994-03-15

The theory of quasi-steaty-state reversible wave for cyclic voltammetry at ultramicro-disk electrode

ZHANG ZUXUN   

  • Published:1994-03-15

本文提出了超微盘电极上准稳态可逆波循环伏安理论, 并对环形氧化还原波的性质进行了深入的讨论, 选择K~4Fe(CN)~6KCl体系在铂微盘电极上对理论进行验证, 实验结果与理论相符合。

关键词: 铁氰化钾, 微电极, 循环伏安法, 准稳态可逆波

The theory of quasi-steady-state reversible wave for voltammetry is described. The behavior of cyclic voltammetric waves is discussed. It is verified experimental by electrooxidn. of K4Fe(CN)6 in the presence of KCl at ultra-micro-disk electrode. The experimental results are in good agreement with the theor. conclusions.

Key words: POTASSIUM FERRICYANIDE, MICROELECTRODE, CYCLOVOLTAMGRAPH

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