SIOC English
化学学报
高级检索

化学学报 ›› 2009, Vol. 67 ›› Issue (15): 1803-1807. 上一篇    下一篇

研究论文

悬液电极萃取碘伏安法的研究

谢少艾*,a 舒菲菲b 史常艳b 时夏君a 贾金平*,b

  

  1. (a上海交通大学化学化工学院 上海 200240)
    (b上海交通大学环境科学与工程学院 上海 200240)

  • 投稿日期:2008-10-13 修回日期:2009-03-07 发布日期:2009-08-14
  • 通讯作者: 谢少艾

Voltammetry Study of Extracting Iodine with Hanging Electrolyte Electrode

Xie, Shaoai*,a Shu, Feifeib Shi, Changyanb Shi, Xiajuna Jia, Jinping*,b   

  1. (a School of Chemistry and Chemical Technology, Shanghai Jiaotong University , Shanghai 200240)
    (b School of Environmental Science and Engineering, Shanghai Jiaotong University , Shanghai 200240)
  • Received:2008-10-13 Revised:2009-03-07 Published:2009-08-14
  • Contact: Xie, Shaoai

PDF

1081

分别以硝基苯(NB)、苯乙酮(ACP)、4-甲基-2-戊酮(MIBK)三种不同的有机溶剂作为悬液电极, 利用三电极体系伏安法比较其在液/液界面上对碘的不同的电化学特性. 在上述研究的基础上, 选用MIBK作为有机溶剂对碘进行萃取分析, 利用伏安法测定了水溶液中Cu(II)的含量, 同时研究了温度和萃取时间对该体系的影响.

关键词: 悬液电极, 液/液界面, 三电极系统, 4-甲基-2-戊酮, 循环伏安法

Three different organic solvents, nitrobenzene (NB), acetophenone (ACP) and methyl isobutyl ketone (MIBK) have been used as an electrolyte hanging electrode respectively. The voltammetric behavior of the iodine at the liquid/liquid interfaces was compared with a classic three-electrode system. The content of the Cu(II) in solution was determined with voltammetry of extracting iodine with MIBK. And the effects of temperature and extracting time were also studied.

Key words: electrolyte hanging electrode, liquid/liquid interface, three electrode system, methyl isobutyl ketone (MIBK), cyclic voltammetry