化学学报 ›› 1989, Vol. 47 ›› Issue (10): 990-995. 上一篇    下一篇

研究论文

芳香族羟肟的合成及其萃取铜的结构-性能研究

袁承业;向才立;李树林;蒋锡琪;王娇;潘柏熙;曹炽明   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1989-10-15

Synthesis of aromatic hydroxyoximes and their structure-reactivity studies in copper extraction

YUAN CHENGYE;XIANG CAILI;LI SHULIN;JIANG XIQI;WANG JIAO;PAN BAIXI;CAO ZHIMING   

  • Published:1989-10-15

合成了一系列不同结构高纯度的芳香族羟肟, 测得了它们的反式羟肟含量和解离常数, 用HMO法计算了配位原子的电荷密度, 并用多元线性回归法研究了这类化合物的结构参数与其萃取铜反应平衡常数的关系。

关键词: 结构参数, 芳香族烃, 铜, 反式, 萃取, 平衡常数, 肟, 回归分析, 结构与性能关系, 分子轨道理论

The charge d. of phenolic oxygen and oximido nitrogen obtained by the HMO method plays an important role in copper extration by the title compounds The relation between chem. structure and extration properties was evaluated; pKa was not important with the 15 title compounds prepared The structural effect was rationalized by the formation of the stable square planar coordination compound

Key words: STRUCTURE PARAMETER, AROMATIC HYDROCARBON, COPPER, TRANSFORM, EXTRACTION, EQUILIBRIUM CONSTANT, OXIME, REGRESSION ANALYSIS, STRUCTURE AND PROPERTY CORRELATION, MOLECULAR ORBITAL THEORY

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