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化学学报
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化学学报 ›› 2005, Vol. 63 ›› Issue (18): 1656-1660. 上一篇    下一篇

研究论文

化学溶液沉积法制备单分散氧化锌纳米棒阵列

罗志强1，张孝彬*,1，程继鹏1，陶新永1
李昱1，刘芙1，唐小明2，王幼文2   

  1. (1浙江大学材料科学与工程系 硅材料国家重点实验室 杭州 310027)
    (2浙江大学分析测试中心 杭州 310027)
  • 投稿日期:2005-01-20 修回日期:2005-05-27 发布日期:2010-12-10
  • 通讯作者: 张孝彬

Synthesis of Monodispersed ZnO Nanorod Array Films by Chemical Solution Deposition

LUO Zhi-Qiang1, ZHANG Xiao-Bin*,1, CHENG Ji-Peng1, TAO Xin-Yong1, LI Yu1, LIU Fu1, TANG Xiao-Ming2, WANG You-Wen2   

  1. (1State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027)
    (2Analysis and Measurement Center of Zhejiang University, Zhejiang University, Hangzhou 310027)
  • Received:2005-01-20 Revised:2005-05-27 Published:2010-12-10
  • Contact: ZHANG Xiao-Bin

PDF

2284

被引次数

77

在由溶胶凝胶法制备的纳米ZnO薄膜基底上, 采用化学溶液沉积法制备了单分散、高度取向的ZnO纳米棒阵列膜. 通过控制纳米ZnO薄膜的制备工艺, 可以调节氧化锌纳米棒的直径. 利用FESEM, TEM, HRTEM, SAED和XRD表征了氧化锌纳米棒阵列的形貌和晶体结构. ZnO纳米棒的室温PL谱具有很高的紫外带边发射峰, 在可见光波段无发射峰, 表明该方法制备的ZnO纳米棒晶体结构完整, 晶体中O空位的浓度很低.

关键词: ZnO, 纳米棒阵列, 化学溶液沉积

Monodispersed and well-aligned ZnO nanorod arrays have been synthesized by chemical solution deposition on spin-coated and preheated ZnO sol films. The diameter of ZnO nanorods was controllable by adjusting the process of nano-ZnO film substrates. The morphology and crystalline structures of ZnO nanorods were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and X-ray diffraction (XRD). The room temperature photoluminescence spectrum of the as-prepared ZnO nanorod arrays exhibits a strong UV emission at about 384 nm and no defects related visible emissions.

Key words: ZnO, nanorod array, chemical solution deposition