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化学学报
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化学学报 ›› 2005, Vol. 63 ›› Issue (5): 341-351.    下一篇

研究专题

钐试剂在有机合成中应用的若干新进展

刘永军，张永敏*   

  1. (浙江大学化学系 杭州 310028)
  • 投稿日期:2004-06-17 修回日期:2004-12-07 发布日期:2010-12-10
  • 通讯作者: 张永敏

New Progress in the Application of Samarium Reagent to Organic Synthesis

LIU Yong-Jun, ZHANG Yong-Min*   

  1. (Department of Chemistry, Zhejiang University, Hangzhou 310028)
  • Received:2004-06-17 Revised:2004-12-07 Published:2010-12-10
  • Contact: ZHANG Yong-Min

PDF

1950

被引次数

36

综述了本课题组最近几年关于钐试剂在有机合成中应用的研究进展. 主要包括以下几部分内容: (1) 二碘化钐促进的有机反应研究; (2) 金属钐直接应用于有机合成的研究; (3) 其它钐试剂 (三碘化钐, 烯丙基溴化钐) 促进的有机反应研究.

关键词: 有机合成, 钐试剂, 二碘化钐, 金属钐, 三碘化钐, 烯丙基溴化钐

The recent studies of our group on the application of samarium reagent to organic synthesis were reviewed in this paper, which mainly include the following contents: (1) studies on organic reactions promoted by samarium diiodide; (2) the direct use of metallic samarium in organic synthesis; (3) the application of other samarium reagent such as samarium triiodide and organosamarium (allyl samarium bromide) to organic reactions.

Key words: organic synthesis, samarium reagent, samarium diiodide, metallic samarium, samarium triiodide, allyl samarium bromide