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化学学报
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化学学报 ›› 1987, Vol. 45 ›› Issue (10): 1005-1008. 上一篇    下一篇

研究论文

强红外激光场作用下固体甲酸铀酰的光解反应研究

徐葆裕;陈达明   

  1. 复旦大学原子核科学系
  • 发布日期:1987-10-15

Photodecomposition of solid uranyl formate under intense infrared laser field

XU BAOYU;CHEN DAMING   

  • Published:1987-10-15

PDF

618

被引次数

6

关键词: 光化学反应, 反应机理, 红外分光光度法, 激发态, 二氧化碳激光器, 甲酸 P, 光分解, 付里叶变换, 铀酰络合物

The photodecompn. of solid uranyl formate and basic uranyl formate was investigated by using the TEA-CO2 laser. The characteristics of the photodecompn. reactions were similar to those which occurred in the multiphoton photodissocn. in gases, and the reactions were nonthermal ones in nature. A mechanism for the laser induced-reaction is proposed.

Key words: PHOTOCHEMICAL REACTION, REACTION MECHANISM, INFRARED SPECTROPHOTOMETRY, EXCITED STATE, CO2 LASER, FORMIC ACID P, PHOTODECOMPOSITION, FOURIER TRANSFORM, URANYL COMPLEX

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