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化学学报
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化学学报 ›› 1987, Vol. 45 ›› Issue (6): 619-621. 上一篇    下一篇

研究论文

昆虫信息素结构鉴定和合成的研究XXV.用三乙胺作烯铜锂试剂配位体合成棉铃虫和午毒蛾性信息素

刘玲玉;林国强;王咸庆   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1987-06-15

Studies on the identification and syntheses of insect pheromones XXV.Syntheses of the sex pheromones of old world bollworm moth and gypsy moth by application of triethyl amine liganded vinyl cuprate

LIU LINGYU;LIN GUOQIANG;WANG XIANQING   

  • Published:1987-06-15

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关键词: 三乙胺 P, 十六碳化合物, 乙烯, 铜, 碳烯, 环氧化物, 醛, 昆虫激素, 性信息素, 十八碳化合物

Tri-Et amine liganded vinyl cuprate was employed in the synthesis of the major components of the sex pheromone of old world bollworm moth (Heliothis armigera), cis-7-hexadecenal (I) and cis-11-hexadecenal (II), and gypsy moth (Porthetria dispar), 7,8-epoxy-2-methyloctadecane (III), with high Z purity (99.9%). The overall yields of I and II from octyllithium and BuLi were 70% in 3 steps, and that of III from decyllithium was 60% in 2 steps.

Key words: TRIETHYL AMINE P, C16 COMPOUNDS, ETHYLENE, COPPER, CARBENE, EPOXIDE, ALDEHYDES, INSECT HORMONE, SEX PHEROMONE, C18 COMPOUNDS

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