关键词: 对甲苯磺酸, 苯乙醇 P, 催化, 大环化合物, 香料, 苯乙酮 P, 结构与性能关系, 乙二醇 P, 异构体, 十二碳化合物

The odoriferous material formed in the reaction of cyclododecanone and phenylethylene glycol under acidic condition, was not the ketal of cyclododecanone, but the acetal of phenylacetaldehyde with phenylethylene glycol. The cis-trans isomers of the acetal, I and II, were separated by chromatog., and the configurations were established via the anal. of their 1H NMR spectra.

Key words: P-METHYLBENZENESULFONIC, PHENYLETHYL ALCOHOL P, CATALYSIS, MACROCYCLIC COMPOUNDS, PERFUMES, ACETOPHENONE P, STRUCTURE AND PROPERTY CORRELATION, ETHANEDIOL P, ISOMER, C12 COMPOUNDS