化学学报 ›› 1983, Vol. 41 ›› Issue (4): 297-301. 上一篇    下一篇

研究论文

(Ca,Sr)GeO3晶体中环-链结构的共生长

温树林;Jeffer,D.A.;Thomas,J.M   

  1. 中国科学院上海硅酸盐研究所;英国剑桥大学物理化学系
  • 发布日期:1983-04-15

Ring-chain intergrowths in strontium metagermanates

WEN SHULIN;JEFFERSON,D.A.;THOMAS,J.M.   

  • Published:1983-04-15

关键词: 晶体生长, 钙化合物, 复盐, 链结构, 锶化合物, 锗酸盐 P, 环状结构, 晶粒

A structure phenomenon which is called ring-chain intergrowth was found in the grains of (Ca, Sr) GeO2 crystals. the samples here were prepared by reaction of CaO SrO + GeO2 -- (Ca, Sr) GeO3, followed by quenching to form a glassy initial product. AFter a subsequent annealing, the final crystalline products were preliminarily characterized by X-ray diffractometry and then analytical electron microscopy. High resolution lattice images were recorded by JEOL JEM 200 CX electron microscope. The results show that there are some intergrowths of ring-chain structure in the grains of (Ca, Sr) GeO3 with cofntact planes being (100)SrGeO2/(101)CaGeO3.

Key words: CRYSTAL GROWTH, CALCIUM COMPOUDS, DOUBLE SALTS, CHAIN STRUCTURE, STRONTIUM COMPOUNDS, GERMANATE P, RING STRUCTURE, GRAIN

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