化学学报 ›› 2001, Vol. 59 ›› Issue (5): 784-787. 上一篇    下一篇

研究论文

细胞壁模板诱导介观尺寸生物SiO~2材料合成

王荔军;吴学民;郭中满;李敏;张福锁;李铁津;王运华   

  1. 中国农业大学植物营养系;中国农业大学应用化学系;吉林大学化学系.长春 (130023);华中农业大学资源环境化学系
  • 发布日期:2001-05-15

Cell wall template: Mediated synthesis of mesostructured biosllica

Wang Lijun;Wu Xuemin;Guo Zhongman;Li Min;Zhang Fusuo;Li Tiejin;Wang Yunhua   

  1. Jilin Univ, Dept Chem.Changchun(130023)
  • Published:2001-05-15

在人工培养年下施用正硅酸乙酯(TEOS)在结缕草叶外表皮细胞间隙,以细胞壁为模板生物矿化合成介观尺寸有序SiO~2材料,植物吸收和矿化构筑单元的硅化学形态显著影响有序SiO~2结构的形成,这反映出TEOS和细胞壁模板分子作用时有较强的结构控制能力和缓慢的凝聚硅化过程。X-ray(EDX)能谱分析显示一根完整的硅柱是含有SiO~2和C元素,表明TEOS部分水解后在植物外表皮细胞间隙合成了不同于自然的地球化学条件下形成SiO~2。

关键词: 二氧化硅, 模板合成, 生物矿化, 细胞壁

Cell wall template -mediated elaborate mesoscopic silica sttructuresin intercellular spaces of epidermal cells of zoysiagrass leaves were synthesized when SiO(OC~2H~5)~4 was supplied instead of monosilicic acid. The synthesis of organized silica structures in zoysia was correlated with the chemnical form of the silicon applied, reflecting a slower condensation from TEOS and thus providing greater opportunities for structural control by the underlying molecular substrates of cell walls. The composition was estimated by energy dispersive X-ray (EDX) spectra on a scnning electron microscope. All organized structures showed carbon, oxygen and silicon peaks, indicating that their formation differs from natural siliceous process.

Key words: SILICON DIOXIDE, CELL WALL

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