化学学报 ›› 1998, Vol. 56 ›› Issue (10): 999-1003. 上一篇    下一篇

研究论文

SrS/α-SiO~2界面的XPS研究

徐春祥;徐征;娄志东;徐叙Rong$D吴建新$D季明荣   

  1. 东南大学分子与生物分子电子学开放实验室;北方交通大学光电子技术研究;天 津大学应用物理系$D中国科学技术大学结构分析开放研究实验室.合肥(230026)
  • 发布日期:1998-10-15

Study of XPS of SrS/α-SiO~2 interface

Xu Chunxiang;Xu Zheng;Lou Zhidong;XU XURong$DWu Jianxin$DJi Mingrong   

  1. Univ Sci & Technol China, Struct Chem Lab.Hefei(230026)
  • Published:1998-10-15

TFEL器件中绝缘层与发光层之间的界面对电荷的输运特性、发光特性等有着十分重要的作用。本文通过XPS的测量,分析了新结构器件中SrS/α-SiO~2界面的各成分的芯电子能谱的变化和深度分布,发现Sr^2^+向SiO~2中扩散较深并以氧化物的形态存在,介质层以SiO~x(x=1.65~1.70)的形态存在。这些丰富的界面态有可能成为TFEL器件的初电子源而对SrS:Ce发光有贡献。

关键词: 硫化物, 锶化合物, 二氧化硅, 界面, X射线光电子谱法, 化学位移, 电子态, 界面态, 电子结构, 输运

The interface between the insulator and the phosphor layers in TFEL devices is important for charge transfer and luminescent characteristics. In this study the XPS of SrS/α-SiO~2 interface was measured. The concentration of each element and their chemical forms were analysed by Sr3d, S2p, Si2p and O1s core levels electron spectroscopy. The results indicated that Sr^2^+ and S^2^- diffused into the SiO~2 layer. O vacancies and strontium oxide were found in the SiO~2 layer. The primary electrons for TFEL devices can come from these interface states.

Key words: SULFIDE, STRONTIUM COMPOUNDS, SILICON DIOXIDE, INTERFACES, X-RAY PHOTOELECTRON SPECTROMETRY, CHEMICAL SHIFT, ELECTRONIC STATES, INTERFACE STATE, ELECTRONIC STRUCTURE, TRANSPORT

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