树状碳水化合物Ⅱ——液晶性的研究

doi:10.6023/A1109097

化学学报 ›› 2012, Vol. 70 ›› Issue (01): 27-34.DOI: 10.6023/A1109097 上一篇下一篇

研究论文

树状碳水化合物Ⅱ——液晶性的研究

杨柳林^a,b, 董炎明^b, 胡晓兰^b, 刘安华^b

a. 厦门大学化学化工学院, 厦门 361005;
b. 厦门大学材料学院, 厦门 361005

投稿日期:2011-09-09 修回日期:2011-11-01 发布日期:2012-02-25
通讯作者: 董炎明,胡晓兰 E-mail:ymdong@xmu.edu.cn;xlhu@xmu.edu.cn
基金资助:
国家自然科学基金(No.20774077)资助项目.

Dendronized CarbohydratesⅡ—Liquid Crystallinity Study

Yang Liulin^a,b, Dong Yanming^b, Hu Xiaolan^b, Liu Anhua^b

a. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005;
b. College of Materials, Xiamen University, Xiamen 361005

Received:2011-09-09 Revised:2011-11-01 Published:2012-02-25
Supported by:
Project supported by the National Natural Science Foundation of China(No.20774077).

文章分享

摘要/Abstract

以基于单糖为内核,楔形液晶基元DOBOB酸(3,4,5-三[对-(十二烷氧基)苄氧基]苯甲酸)为分枝的树状碳水化合物液晶为研究对象,利用DSC、热台偏光显微镜、XRD和CD/UV光谱等手段研究该类化合物的液晶性.研究发现分枝的数目对该类化合物的液晶性有显著影响,以2-乙酰氨基葡萄糖为内核的包含四个分枝的树状分子具有最高的液晶结构有序性,清亮点也显著高于另两种单糖内核(含五个分枝)的树状分子.此外,该类碳水化合物液晶形成的液晶相都具备超分子手性,为探索碳水化合物手性液晶相提供了一条新的思路.

关键词: 树状碳水化合物液晶, 3,4,5-三[对-(十二烷氧基)苄氧基]苯甲酸, 手性液晶相

Liquid crystallinity of dendronized carbohydrate liquid crystals,which contain carbohydrate core and mesogen branches DOBOB(3,4,5-tris(p-dodecyloxybenzyloxy)benzoic acid),was studied by DSC, thermal polarized optical microscopy,XRD and CD/UV spectrum.The number of branches affects the liq-uid crystallinity significantly.Dendrimer that contains four branches has the highest liquid crystal structure order,and the clearing point is also higher than the other two dendrimers which contain five branches.Oth-erwise,supramolecular chirality is also expressed in the mesophase formed by these dendronized carbohy- drates,which may provide inspiration in searching for chiral mesophase of carbohydrate liquid crystals.

Key words: dendronized carbohydrate liquid crystal, 3,4,5-tris(p-dodecyloxybenzyloxy)benzoic acid, chiral mesophase

引用此文

杨柳林, 董炎明, 胡晓兰, 刘安华. 树状碳水化合物Ⅱ——液晶性的研究[J]. 化学学报, 2012, 70(01): 27-34.

Yang Liulin, Dong Yanming, Hu Xiaolan, Liu Anhua. Dendronized CarbohydratesⅡ—Liquid Crystallinity Study[J]. Acta Chimica Sinica, 2012, 70(01): 27-34.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

1 Vill, V. ; Hashim, R. Curr. Opin. Colloid Interface Sci. 2002, 7, 395.

2 Goodby, J. W. ; Gortz, V. ; Cowling, S. J. ; Mackenzie, G. ; Martin, P. ; Plusquellec, D. ; Benvegnu, T. ; Boullanger, P. ; Lafont, D. ; Queneau, Y. ; Chambert, S. ; Fitremann, J. Chem. Soc. Rev. 2007, 36, 1971.

3 Morris, N. L. ; Zimmermann, R. G. ; Jameson, G. B. ; Dalziel, A. W. ; Reuss, P. M. ; Weiss, R. G. J. Am. Chem. Soc. 1988, 110, 2177.

4 Kohne, B. ; Praefcke, K. Angew. Chem. , Int. Ed. Engl. 1984, 23, 82.

5 Takaragi, A. ; Sugiura, M. ; Minoda, M. ; Miyamoto, T. ; Watanabe, J. Macromol. Chem. Phys. 1997, 198, 2583.

6 Sugiura, M. ; Minoda, M. ; Watanabe, J. ; Miyamoto, T. Polym. J. 1994, 26, 1236.

7 Sugiura, M. ; Minoda, M. ; Fukuda, T. ; Miyamoto, T. ; Watanabe, J. Liq. Cryst. 1992, 12, 603.

8 Hirani, B. ; Nakata, Y. ; Watanabe, J. Mol. Cryst. Liq. Cryst. 1996, 288, 223.

9 Zhang, B. ; Xiao, W. ; Cong, Y. ; Zhang, Y. Liq. Cryst. 2007, 34, 1129.

10 Jeffrey, G. A. ; Wingert, L. M. Liq. Cryst. 1992, 12, 179.

11 Doren, H. A. V. ; Smits, E. ; Pestman, J. M. ; Engberts, J. B. F. N. ; Kellogg, R. M. Chem. Soc. Rev. 2000, 29, 183.

12 Malthete, J. ; Collet, A. ; Levelut, A. Liq. Cryst. 1989, 5, 123.

13 Malthete, J. ; Collet, A. J. Am. Chem. Soc. 1987, 109, 7544.

14 Sugiura, M. ; Minoda, M. ; Watanabe, J. ; Fukuda, T. ; Miyamoto, T. Bull. Chem. Soc. Jpn. 1992, 65, 1939.

15 Ma, Y. D. ; Takada, A. ; Sugiura, M. ; Fukuda, T. ; Miyamoto, T. ; Watanabe, J. Bull. Chem. Soc. Jpn. 1994, 67, 346.

16 Boyer, R. F. Macromolecules 1973, 6, 288.

17(a)Kawaguchi, T. J. Appl. Polym. Sci. 1959, 2, 56. (b)Willbourn, A. H. Trans. Faraday Soc. 1958, 54, 717.

18 Rosen, B. M. ; Wilson, C. J. ; Wilson, D. A. ; Peterca, M. ; Imam, M. R. ; Percec, V. Chem. Rev. 2009, 109, 6275.

19 Percec, V. ; Imam, M. R. ; Peterca, M. ; Wilson, D. A. ; Heiney, P. A. J. Am. Chem. Soc. 2009, 131, 1294.

20 Percec, V. ; Imam, M. R. ; Peterca, M. ; Wilson, D. A. ; Graf, R. ; Spiess, H. W. ; Balagurusamy, V. S. K. ; Heiney, P. A. J. Am. Chem. Soc. 2009, 131, 7662.

21 Peterca, M. ; Percec, V. ; Imam, M. R. ; Leowanawat, P. ; Mo- rimitsu, K. ; Heiney, P. A. J. Am. Chem. Soc. 2008, 130, 14840.

22 Rudick, J. G. ; Percec, V. Acc. Chem. Res. 2008, 41, 1641.

23 Brittiger, H. ; Bittiger, H. ; Keilich, G. Biopolymers 1969, 7, 539.

24 Harkness, B. R. ; Gray, D. G. Liq. Cryst. 1990, 8, 237.

25 Heinze, T. ; Koschella, A. Polym. Bull. 2001, 46, 7.

26 Murer, P. ; Seebach, D. Angew. Chem. , Int. Ed. Engl. 1995, 34, 2116.

27 Seebach, D. ; Lapierre, J. ; Greiveldinger, G. ; Skobridis, K. Helv. Chim. Acta 1994, 77, 1673.

28 Seebach, D. ; Lapierre, J. ; Skobridis, K. ; Greiveldinger, G. Angew. Chem. , Int. Ed. Engl. 1994, 33, 440.

29 Percec, V. ; Won, B. C. ; Peterca, M. ; Heiney, P. A. J. Am. Chem. Soc. 2007, 129, 11265.

30 Lin, T. ; Ho, R. ; Sung, C. ; Hsu, C. Chem. Mater. 2006, 18, 5510.

树状碳水化合物Ⅱ——液晶性的研究

Dendronized CarbohydratesⅡ—Liquid Crystallinity Study

PDF

可视化

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 0

编辑推荐

相关统计

本文评价