化学学报 ›› 1962, Vol. 28 ›› Issue (1): 1-4.    下一篇

论文

利用甲基乙烯基酮与醇类加成以制取β-醚酮

丁新腾, 吴钧和   

  1. 复旦大学化学系
  • 投稿日期:1960-04-09 发布日期:2013-06-03

THE PREPARATION OF ETHERS OF 4-HYDROXYBUTANONE-[2]

TIN XIN-TEN, OU KIUN-HOUO   

  1. Department of Chemistry, Fu-Dan University
  • Received:1960-04-09 Published:2013-06-03

以强碱型阴离子交换树脂为催化剂,可使甲基乙烯基酮与醇类反应而制得β-醚酮。所适应的醇包括脂肪族醇、脂环族醇、芳香族醇以及杂环醇。部分产品可用作维生素A醚类合成中的中间体。

Anion exchange resin in the hydroxy form was successfully used as a catalyst in the reaction of methyl vinyl ketone and alcohols to furnish ethers of 4-hydroxybutanone-[2]. Some aliphatic, aromatic, cyclic, and heterocyclic alcohols were used. The method was shown to provide a simple preparative route to such ketoethers. Seven ethers of 4-hydro- xybutanone-[2] were prepared and their physical constants determined. Some of the products had been used previously as intermediates in the synthesis of Vitamin A ethers.