化学学报 ›› 2024, Vol. 82 ›› Issue (5): 471-476.DOI: 10.6023/A24020060 上一篇 下一篇
研究通讯
投稿日期:
2024-02-22
发布日期:
2024-04-09
基金资助:
Yuanjin Chen, Dajiang Huang, Xianghui Shi, Zhenfeng Xi, Junnian Wei()
Received:
2024-02-22
Published:
2024-04-09
Contact:
*E-mail: jnwei@pku.edu.cn; Tel.: 010-62755835
Supported by:
文章分享
本工作报道了还原条件下, 非对称钳形钴配合物PNNCoCl (1) (PNN: [6-(tBu2PN)C5H3N-2-(3-Mes)C3H2N2])和有机分子的反应性. 利用PNNCoCl、还原剂与异腈或一氧化碳反应, 实现了异腈和一氧化碳配位一价钴配合物2和3的合成. 通过更换还原剂, 实现了偶氮苯C—H、N=N键的选择性断裂反应. 当使用石墨钾作为还原剂时, PNNCoCl (1)与偶氮苯在四氢呋喃中反应, 得到偶氮苯C—H键断裂产物5; 而当使用KHBEt3作为还原剂时, PNNCoCl与偶氮苯反应, 则能得到偶氮苯N=N键断裂产物PNNCoNHPh (6). 此外, PNNCoCl (1)还可以与卡宾或邻苯醌反应, 得到了相应配合物4和7. 这些配合物均通过了X射线衍射、元素分析、红外光谱和溶液相磁化率测试等表征.
陈元金, 黄大江, 石向辉, 席振峰, 魏俊年. 还原条件下非对称钳形PNN钴配合物的反应性研究[J]. 化学学报, 2024, 82(5): 471-476.
Yuanjin Chen, Dajiang Huang, Xianghui Shi, Zhenfeng Xi, Junnian Wei. Reactivities of Nonsymmetric PNN Pincer Cobalt Complex Under Reductive Conditions[J]. Acta Chimica Sinica, 2024, 82(5): 471-476.
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