铝基金属有机框架材料的主客体化学研究进展★

doi:10.6023/A26020059

化学学报 ›› 2026, Vol. 84 ›› Issue (5): 697-708.DOI: 10.6023/A26020059 上一篇下一篇

综述

铝基金属有机框架材料的主客体化学研究进展^★

邬佳悦^a, 王文伯^a, 谢玉龙^b, 方伟慧^a^,^b^,^*()

^a 福州大学化学学院福州 350108
^b 中国科学院福建物质结构研究所结构化学全国重点实验室福州 350002

投稿日期:2026-02-14 发布日期:2026-04-14
通讯作者: 方伟慧
作者简介:
★ “框架材料化学”专辑
基金资助:
国家自然科学基金(22371278)

Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials^★

Jiayue Wu^a, Wenbo Wang^a, Yulong Xie^b, Weihui Fang^a^,^b^,^*()

^a School of Chemistry, Fuzhou University, Fuzhou 350108, China
^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:2026-02-14 Published:2026-04-14
Contact: Weihui Fang

About author:

Wu, Jiayue, postgraduate of Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, mainly focuses on the design and synthesis of crystalline metal-oxo clusters.

Wang, Wenbo, postgraduate of Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, mainly focuses on the design and synthesis of crystalline metal-oxo clusters.

Xie, Yulong, Ph.D. candidate of Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, mainly focuses on the design and synthesis of crystalline metal-oxo clusters.

Prof. Dr. Fang Weihui is a researcher, doctoral supervisor, and group leader from Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. She dedicates to the chemical research of metal-oxo cluster synthesis, including rare earth-oxo clusters, transition metal-oxo clusters, and main group metal-oxo clusters, with a recent focus on precise structural assembly and performance research of aluminum oxygen clusters. She has presided over and completed the cultivation project of “Major Research Plan on Cluster Structure, Function and Multi level Evolution of the National Natural Science Foundation of China”, and the Youth and General Project of the National Natural Science Foundation of China. She is selected as a distinguished youth of Fujian Province, “Star of Innovation”, an outstanding member of the Youth Innovation Promotion Association of the Chinese Academy of Sciences, and serves as a young editorial board member of Structural Chemistry, POM, and Chin. Chem. Lett.

★ For the VSI “Chemistry of Framework Materials”.

Supported by:
National Natural Science Foundation of China(22371278)

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摘要/Abstract

铝基金属有机框架(Al-MOFs)因其主体金属的天然丰度较高, 为构筑经济友好的功能材料提供了新途径. 然而, 由于Al^3＋的较快的水解动力学, Al-MOFs的结晶过程较为困难, 导致相比于其他金属基MOF发展较为缓慢, 以Al-MOF为平台的主客体化学研究也因此受限. 随着对Al^3＋水解过程认识的深入, 近年来Al-MOFs得到蓬勃发展, 对该领域进展进行具有时效性的总结具备重要意义. 基于此, 本综述详细总结了Al-MOFs的合成方法、结构的多样性以及其在主客体化学方面的应用. 在合成方法方面, 于传统溶剂热法的基础上加入了对新兴的微波合成法与电化学合成法的介绍, 在结构多样性方面则对迄今为止Al-MOFs中所出现过的所有次级结构单元(Secondary building unit, SBU)进行分类总结, 从次级构筑单元出发, 详细介绍2023年后报道的Al-MOFs结构. 此外, 针对Al-MOFs的主客体化学应用进行调研, 通过对其吸附的客体分子进行分类, 归纳了Al-MOFs作为主体吸附客体分子的机理及其作用位点. 最后, 对Al-MOFs的主客体化学的研究趋势进行了展望.

关键词: 铝基金属有机框架, 铝基次级构筑单元, 主客体化学

Due to the high natural abundance of host metal, exploration of aluminum-based metal-organic frameworks (Al-MOFs) provides a new approach to construct economical-friendly functional materials. However, compared with other metal-based MOFs, the fast hydrolysis kinetic of Al^3＋ leads to great difficulty in crystallization, limiting their investigations in structure and host-guest chemistry. As the understanding towards the hydrolysis of Al^3＋ deepens, recently the development of Al-MOFs boomed, thus an up-to-date summary of this area is of great importance. Based on this, this review provides a detailed summary of the synthetic methods, structural diversity, and applications in host-guest chemistry of Al-MOFs. Regarding synthetic methods, in addition to the traditional solvothermal method, the emerging microwave-assisted synthesis and electrochemical synthesis are included as well. In terms of structural diversity, all secondary building units (SBUs) reported in Al-MOFs to date are classified and summarized. Starting from these SBUs, the derived Al-MOF structures reported after 2023 are discussed in detail. Moreover, the host-guest chemistry of Al-MOFs is highlighted. By categorizing the guest molecules, this review summarizes the corresponding absorption mechanism and binding sites. Finally, this review provides a perspective on the host-guest chemistry of Al-MOFs.

Key words: aluminum-based metal-organic framework, aluminum-based secondary building unit, host-guest chemistry

引用此文

邬佳悦, 王文伯, 谢玉龙, 方伟慧. 铝基金属有机框架材料的主客体化学研究进展^★[J]. 化学学报, 2026, 84(5): 697-708.

Jiayue Wu, Wenbo Wang, Yulong Xie, Weihui Fang. Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials^★[J]. Acta Chimica Sinica, 2026, 84(5): 697-708.

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MOFs	Formula	Linker	SBU	Condition	BET/(m²•g^－1)^a	Ref.
ZJU-520	AlC₁₈H₁₀O₅N₂	H₂DBP	[Al(OH)(COO)₂]_n	130 ℃, 72 h	2235	[47]
MCF-66	AlC₁₄H₁₁O₅	HBA	[Al(OH)(COO)₂]_n	160 ℃, 48 h	—	[48]
ZJU-928	Al₁₆C₉₀O₇₉H₄₂	H₃BTA	[Al₈(OH)₁₅(COO)₉]	130 ℃, 72 h	2344	[3]
HIAM-340	Al₂₇C₂₂₂H₁₅₃O₁₄₁	H₆btei	[Al₉(OH)₁₅(COO)₁₂], [Al₃O(COO)₄]	155 ℃, 72 h	2800	[43]
HIAM-341	Al₃C₃₀H₁₂O₁₆	H₆BHB	[Al₃O(OH)₃(COO)₆]	180 ℃, 72 h	1094	[49]
CAU-63	Al₇C₂₁H₂₄O₂₇N₃	2,4-H₂Pydc	Al₄O₁₄N₂	135 ℃, 6 h	—	[50]
AlOC-200-Cu	Al₁₂C₇₂H₇₆O₅₆N₄₈Cu₁₂	HPyzc	[Al₁₂(µ₃-O)₄(Hpyzc)₁₂(COO)₆(H₂O)₁₂]	100 ℃, 24 h	1526.2	[45]
AlOC-200-Ag	Al₁₂C₇₂H₄₈O₄₀N₄₈Ag₁₂	Hpyzc	[Al₁₂(µ₃-O)₄(Hpyzc)₁₂(COO)₆(H₂O)₁₂]	100 ℃, 24 h	1461.8	[45]
MAl-bcp-pacs	(M)_3－_x(Al₂)_x(O/OH)(bcp)₃(tpbz)	tpbz	M₂Al(OH) (M=Mg, Mn, Co, Ni)	130 ℃, 24 h	1027	[51]
MAl-bdc-pacs	(M)_3－_x(Al₂)_x(O/OH)(bdc)₃(tpt)	tpt	M₂Al(OH) (M=Mg, Mn, Co, Ni)	150 ℃, 15 h	1328	[51]
MAl-bdc-pacs	(M)_3－_x(Al₂)_x(O/OH)(bdc)₃(tppy)	tppy	M₂Al(OH) (M=Mg, Mn, Co, Ni)	130 ℃, 15 h	—	[51]
AlOC-132	Al₄C₈₈H₁₂₀O₃₂N₁₆Eu₄Cu₄I₄	Hpyba	[Al₄Eu₄(IN)₈(COO)₈(H₂O)]	100 ℃, 96 h	—	[52]
AlOC-197	Al₈C₉₆H₁₁₀N₁₂O_37.25Cu₂Cl₃	HNA	[Al₈(µ-OH)₄(OⁱPr)₈(COO)₁₂(Cl)]	100 ℃, 120 h	—	[53]
Ag-Al₈	Al₈C₁₀₁H₇₆O₄₆N₁₉Ag₂F₆S₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
AgCl-Al₈	Al₈C₉₈H₈₆O₄₆N₁₆Ag₆Cl₂₀F₆S₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
CuBr-Al₈-1	Al₈C₁₀₇H₈₀O₄₄N₁₉Cu₄Br₃	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
CuBr-Al₈-2	Al₈C₁₀₈H₇₂O₄₄N₁₈Cu₄Br₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]

MOFs	Formula	Linker	SBU	Condition	BET/(m²•g^－1)^a	Ref.
ZJU-520	AlC₁₈H₁₀O₅N₂	H₂DBP	[Al(OH)(COO)₂]_n	130 ℃, 72 h	2235	[47]
MCF-66	AlC₁₄H₁₁O₅	HBA	[Al(OH)(COO)₂]_n	160 ℃, 48 h	—	[48]
ZJU-928	Al₁₆C₉₀O₇₉H₄₂	H₃BTA	[Al₈(OH)₁₅(COO)₉]	130 ℃, 72 h	2344	[3]
HIAM-340	Al₂₇C₂₂₂H₁₅₃O₁₄₁	H₆btei	[Al₉(OH)₁₅(COO)₁₂], [Al₃O(COO)₄]	155 ℃, 72 h	2800	[43]
HIAM-341	Al₃C₃₀H₁₂O₁₆	H₆BHB	[Al₃O(OH)₃(COO)₆]	180 ℃, 72 h	1094	[49]
CAU-63	Al₇C₂₁H₂₄O₂₇N₃	2,4-H₂Pydc	Al₄O₁₄N₂	135 ℃, 6 h	—	[50]
AlOC-200-Cu	Al₁₂C₇₂H₇₆O₅₆N₄₈Cu₁₂	HPyzc	[Al₁₂(µ₃-O)₄(Hpyzc)₁₂(COO)₆(H₂O)₁₂]	100 ℃, 24 h	1526.2	[45]
AlOC-200-Ag	Al₁₂C₇₂H₄₈O₄₀N₄₈Ag₁₂	Hpyzc	[Al₁₂(µ₃-O)₄(Hpyzc)₁₂(COO)₆(H₂O)₁₂]	100 ℃, 24 h	1461.8	[45]
MAl-bcp-pacs	(M)_3－_x(Al₂)_x(O/OH)(bcp)₃(tpbz)	tpbz	M₂Al(OH) (M=Mg, Mn, Co, Ni)	130 ℃, 24 h	1027	[51]
MAl-bdc-pacs	(M)_3－_x(Al₂)_x(O/OH)(bdc)₃(tpt)	tpt	M₂Al(OH) (M=Mg, Mn, Co, Ni)	150 ℃, 15 h	1328	[51]
MAl-bdc-pacs	(M)_3－_x(Al₂)_x(O/OH)(bdc)₃(tppy)	tppy	M₂Al(OH) (M=Mg, Mn, Co, Ni)	130 ℃, 15 h	—	[51]
AlOC-132	Al₄C₈₈H₁₂₀O₃₂N₁₆Eu₄Cu₄I₄	Hpyba	[Al₄Eu₄(IN)₈(COO)₈(H₂O)]	100 ℃, 96 h	—	[52]
AlOC-197	Al₈C₉₆H₁₁₀N₁₂O_37.25Cu₂Cl₃	HNA	[Al₈(µ-OH)₄(OⁱPr)₈(COO)₁₂(Cl)]	100 ℃, 120 h	—	[53]
Ag-Al₈	Al₈C₁₀₁H₇₆O₄₆N₁₉Ag₂F₆S₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
AgCl-Al₈	Al₈C₉₈H₈₆O₄₆N₁₆Ag₆Cl₂₀F₆S₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
CuBr-Al₈-1	Al₈C₁₀₇H₈₀O₄₄N₁₉Cu₄Br₃	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
CuBr-Al₈-2	Al₈C₁₀₈H₇₂O₄₄N₁₈Cu₄Br₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]

铝基金属有机框架材料的主客体化学研究进展^★

Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials^★

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[2]	吴明港, 杨勇, 薛敏. 四氨基柱[5]芳烃二聚体的合成、结构及性质研究[J]. 化学学报, 2022, 80(8): 1057-1060.
[3]	周丽, 徐立进, 龚汉元. 自组装中的苯二甲酸阴离子形貌及质子化效应[J]. 化学学报, 2014, 72(4): 447-455.
[4]	岳诗雨, 周玉娟, 姚勇, 薛敏. 柱芳烃化学：从合成、主客体性质到自组装性能的研究进展[J]. 化学学报, 2014, 72(10): 1053-1069.
[5]	韩成友, 张子彬, 池小东, 张明明, 喻国灿, 黄飞鹤. 1,4-双正丙氧基柱[7]芳烃的合成及主客体化学[J]. 化学学报, 2012, 70(17): 1775-1778.
[6]	杨登科, 曾志坚, 陈木娟, 潘绍武, 杨宇, 李媚, 雷春燕, 蒋腊生. 二酰胺大环化合物与吡啶N-氧化物的络合作用研究[J]. 化学学报, 2012, 70(12): 1385-1393.

铝基金属有机框架材料的主客体化学研究进展★

Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials★

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铝基金属有机框架材料的主客体化学研究进展^★

Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials^★