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2012 , Vol. 70 >Issue 07: 838 - 842

DOI: https://doi.org/10.6023/A1110112

研究论文

含席夫碱基二茂铁-蒽二元化合物的合成及其阳离子多信号识别

  • 赵小芳 ,
  • 曹迁永 ,
  • 卢鑫 ,
  • 杨震宇 ,
  • 唐建成
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  • 南昌大学化学系 南昌 330031

收稿日期: 2011-10-11

  修回日期: 2011-12-07

  网络出版日期: 2012-01-20

基金资助

国家自然科学基金(Nos. 21162017, 50801037)资助项目.

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Ferrocene-anthracene Dyad Bearing Schiff base Donor and Its Multi-respond to Metal Ions

  • Zhao Xiaofang ,
  • Cao Qianyong ,
  • Lu Xin ,
  • Yang Zhenyu ,
  • Tang Jiancheng
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  • Department of Chemistry, Nanchang University, Nanchang 330031

Received date: 2011-10-11

  Revised date: 2011-12-07

  Online published: 2012-01-20

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21162017, 50801037).

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摘要

合成了一种含席夫碱基团的二茂铁-蒽二元化合物1, 并研究了其金属离子识别时紫外-可见光谱, 荧光光谱及电化学变化. 在各种金属离子中, 1 对Cr3+, Cu2+及Hg2+显示出多种信号响应识别: 1 位于407 nm 的Fe(II)→Cp 的荷移光谱发生约100 nm 红移, 且颜色由黄色变为红色, 同时使其Fe(III)/Fe(II)电位向阳极移动. 同时, 荧光光谱表明1 仅对Cr3+显示荧光增强效应.

关键词： 二茂铁-蒽二元化合物; 席夫碱; 金属离子识别; 多信号响应

本文引用格式

赵小芳 , 曹迁永 , 卢鑫 , 杨震宇 , 唐建成 . 含席夫碱基二茂铁-蒽二元化合物的合成及其阳离子多信号识别[J]. 化学学报, 2012 , 70(07) : 838 -842 . DOI: 10.6023/A1110112

Abstract

A new ferrocene-anthracene dyad bearing Schiff base donor, 1, has been synthesized and characterized. Its metal ions recognition ability was investigated by UV-Vis spectra, emission spectra and cyclic voltammetry (CV). Among various metal ions, 1 shows multi-respond to Cr3+, Cu2+ and Hg2+, with a ca. 100 nm red-shift of the low energy Fe(II)→Cp charge transfer located at 407 nm, which can be observed color change from yellow to red by naked eyes, and an anode shift of the Fe(II)/Fe(III) potential. In addition, 1 shows exclusive emission-on sensing to Cr3+.

Key words： ferrocene-anthracene dyad; Schiff-base; metal ions recognition; multi-respond sensing

参考文献

1 Renzoni, A.; Zino, F.; Franchi, E. Environ. Res. 1998, 77,68.  

2 Que, E. L.; Domaille, D. W.; Chang, C. J. Chem. Rev. 2008,108, 1517.  

3 Turner, F. Science 2000, 290, 1315.  

4 Quang, D. T.; Kim, J. S. Chem. Rev. 2010, 110, 6280.  

5 Nolan, E. M.; Lippard, S. J. Chem. Rev. 2008, 108, 3443.  

6 Beer, P. D.; Cadman, J. Coord. Chem. Rev. 2000, 205, 131.  

7 Beer, P. D.; Hayes, E. J. Coord. Chem. Rev. 2003, 240, 167.  

8 Molina, P.; Tárraga, A.; Caballero, A. Eur. J. Inorg. Chem.2008, 3401.  

9 Cozzi, P. G. Chem. Soc. Rev. 2004, 33, 410.  

10 Zapata, F.; Caballero, A.; Espinosa, A.; Tárraga, A.; Molina, P. Org. Lett. 2007, 9, 2385.  

11 Caballero, A.; Garcia, R.; Espinosa, A.; Tárraga, A.; Molina, P. J. Org. Chem. 2007, 72, 1161.  

12 Cao, Q.-Y.; Zhang, J.-F.; Ren, W.-X.; Choi, K.; Kim, J. S. Tetrahedron Lett. 2011, 52, 4464.  

13 Cao, Q.-Y.; Lee, M. H.; Zhang, J.-F.; Ren, W.-X.; Kim, J. S. Tetrahedron Lett. 2011, 52, 2786.  

14 Cao, Q.-Y.; Lu, X.; Kuang, R.-Y.; Li, Z.-H.; Yang, Z.-Y. Acta Phys.-Chim. Sin. 2010, 26, 2158 (in Chinese). (曹迁永, 卢鑫, 匡仁云, 李志华, 杨震宇, 物理化学学 报, 2010, 26, 2158.)

15 Cao, Q.-Y.; Lu, X.; Li, Z.-H.; Zhou, L.; Yang, Z.-Y.; Liu, J.-H. J. Organomet. Chem. 2010, 695, 1323.  

16 Polin, J.; Schottenberger, H. Org. Synth. 1996, 73, 262.

17 Perrin, D. D.; Armarego, W. L. F.; Perrin, D. R. Purification of Laboratory Chemicals, Pergamon, New York, 1980, pp.3～29.  

18 Negishi, E.; Anastasia, L. Chem. Rev. 2003, 103, 1979.  

19 Fery-Forgues, S.; Delavaux-Nicot, B. J. Photochem. Photobiol. A: Chem. 2000, 132, 137.  

20 Caballero, A.; Martínez, R.; Lloveras, V.; Ratera, I.; Vidal- Gancedo, J.; Wurst, K.; Tárraga, A.; Molina, P.; Veciana, J. J. Am. Chem. Soc. 2005, 127, 15666.  

21 Chen, S.-M.; Lu, J.-X.; Sun, C.-D.; Ma, H.-M. Analyst2010, 135, 577.

22 Ramón, M. M.; Félix, S. Chem. Rev. 2003, 103, 4419.  

23 Fabbrizzi, L.; Poggi, A. Chem. Soc. Rev. 1995, 24, 197.  

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