二氧化碳与不饱和烃的还原羧化反应
收稿日期: 2015-09-26
网络出版日期: 2015-11-13
基金资助
项目受国家自然科学基金(Nos. 21472103, 21421001)、教育部博士点基金(No. 20130031110013)和教育部创新团队(No. IRT13022)资助.
Reductive Carboxylation of Unsaturated Hydrocarbons with Carbon Dioxide
Received date: 2015-09-26
Online published: 2015-11-13
Supported by
Project supported by the National Natural Sciences Foundation of China (Nos. 21472103, 21421001), the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20130031110013), the MOE Innovation Team (No. IRT13022) of China.
张帅 , 李雪冬 , 何良年 . 二氧化碳与不饱和烃的还原羧化反应[J]. 化学学报, 2016 , 74(1) : 17 -23 . DOI: 10.6023/A15090631
Transition metal-catalyzed reductive carboxylation of unsaturated hydrocarbons with CO2 is a promising and potential strategy, offering an excellent alternative access to carboxylic acids/acrylic acids. The active transition metal species could react with unsaturated hydrocarbons and CO2 to generate the stable metallalactones or carboxylic salts. The transmetalation between reductants and metallalactones/carboxylic salts regenerates the active catalytic species. As a result, the reductive carboxylation is able to run in a catalytic mode rather than stoichiometric version. Organometal species, silanes/boranes, metal powder, methanol and hydrogens have been developed as reducing reagents in reductive carboxylation with CO2. In this perspective, the latest advances on the transition metal-catalyzed reductive carboxylation are summarized, with particular focus on the application of reductants and related reaction mechanism at a molecular level.
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