喹喔啉类红光热活化延迟荧光材料研究进展
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周路, 广东工业大学轻工化工学院2019级硕士研究生, 化学工程与技术专业. 主要从事有机发光材料的设计合成及其性能研究. |
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陈嘉雄, 广东工业大学化工与轻工学院副教授、硕士生导师, 有机光电材料与功能高分子团队骨干成员. 2010年获得广东工业大学学士学位, 并分别在汕头大学(2013年)和苏州大学(2018年)获得硕士和博士学位, 2018年~2021年在苏州大学能源学院从事博士后工作. 2018年~2021年在香港城市大学超金刚石及先进薄膜研究中心进行访问学习. 目前主要研究方向为有机光电功能材料及基于热活化延迟荧光材料的有机发光二极管. |
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陈文铖, 广东工业大学化工与轻工学院副教授、硕士生导师, 有机光电材料与功能高分子团队骨干成员. 2011年获得北京化工大学学士学位, 并分别在汕头大学(2014年)和香港城市大学(2018年)获得硕士和博士学位. 2018年5月~2019年11月在香港城市大学超金刚石及先进薄膜研究中心进行博士后研究. 目前研究方向主要包括有机光功能材料的设计合成及其在发光二极管、光学防伪与加密、生物医疗等领域的应用. |
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霍延平, 广东工业大学化工与轻工学院教授、博士生导师, 现任学院副院长, 有机光电材料与功能高分子团队负责人. 2006年获得中国科学院广州化学研究所博士学位. 广东省“千百十工程”省级培养对象、广东省有机化学专业委员会委员及国家自然科学基金通讯评审专家. 目前研究方向为有机电致发光材料和有机功能材料的绿色合成方法. |
收稿日期: 2021-12-27
网络出版日期: 2022-02-08
基金资助
国家自然科学基金(52003058); 国家自然科学基金(U2001222); 国家自然科学基金(21975053); 国家自然科学基金(21975055); 国家自然科学基金(52003059); 广东省基础和应用基础研究基金(2019B1515120023); 广东省基础和应用基础研究基金(2019B1515120035); 广东省基础和应用基础研究基金(2021A1515010607); 广东省分子聚集发光重点实验室开放基金(2019-kllma-06)
Research Progress of Red Thermally Activated Delayed Fluorescent Materials Based on Quinoxaline
Received date: 2021-12-27
Online published: 2022-02-08
Supported by
National Natural Science Foundation of China(52003058); National Natural Science Foundation of China(U2001222); National Natural Science Foundation of China(21975053); National Natural Science Foundation of China(21975055); National Natural Science Foundation of China(52003059); Guangdong Basic and Applied Basic Research Foundation(2019B1515120023); Guangdong Basic and Applied Basic Research Foundation(2019B1515120035); Guangdong Basic and Applied Basic Research Foundation(2021A1515010607); Open Fund of Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates(2019-kllma-06)
红光材料是显示三基色材料之一, 具有发射能量小、穿透能力强和背景荧光干扰小等优点, 被广泛应用于全彩显示、生物传感和光动力治疗等领域. 红光材料目前存在的问题主要有: (1)跃迁能级小, 其非辐射跃迁速率快, 导致量子效率普遍较低; (2)分子共轭较大, 存在较强的π-π堆积作用, 容易导致荧光淬灭; (3)分子设计需要更大的共轭, 在分子合成上较为困难. 热活化延迟荧光(thermally activated delayed fluorescence, TADF)材料作为具有全新的发光机制的材料能够通过反向系间窜越过程利用三重态激子发射荧光, 极大地提高了量子效率, 因此, 基于TADF机制的红光材料成为了近年来人们研究的热点. 由于结构的特点, 喹喔啉及其衍生物非常适合用来构建红光TADF分子. 从喹喔啉类TADF红光材料的分子结构视角出发, 对红光TADF材料的近年来的研究进行概述, 讨论分子结构对材料性能影响, 并且对其发展进行展望.
周路 , 陈嘉雄 , 籍少敏 , 陈文铖 , 霍延平 . 喹喔啉类红光热活化延迟荧光材料研究进展[J]. 化学学报, 2022 , 80(3) : 359 -372 . DOI: 10.6023/A21120587
Red emitter is one of the three primary materials for display, which is widely used in full-color display, biosensing and photodynamic therapy due to the advantages of small emission energy, strong penetrating ability and low background fluorescence interference. At present, the main bottlenecks for the development of red emitters are as follows. (1) The narrow energy gaps of red emitters often lead to serious non-radiative transition and low quantum efficiency. (2) The largely conjugated structure of red emitters results in strong π-π stacking for emission quenching. (3) Molecular design requires greater conjugation, which is difficult in molecular synthesis. Red thermally activated delayed fluorescence (TADF) materials, as a new type of red emitters, can use triplet excitons to release fluorescence through reverse intersystem crossing process, which greatly improves the quantum efficiency. Therefore, red TADF materials have become a hot topic in recent years. Because of the structural advantages, quinoxaline and its derivative are promising building blocks for the construction of red TADF emitters. The research progress of the quinoxaline-based red TADF materials in recent years is summarized, the influence of molecular structure on the properties of materials is discussed, and the prospect is also provided.
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