 |
祁育, 副研究员, 硕导, 2012年本科毕业于吉林大学, 随后加入中国科学院大连化学物理研究所, 在李灿院士和章福祥研究员指导下获得博士学位. 2018年1月加入章福祥课题组, 主要研究方向为光催化Z机制全分解水制氢研究. |
 |
章福祥, 研究员, 博导, 国家杰出青年基金获得者, 英国皇家化学会会士, 入选国家百千万人才工程. 1999年获南开大学学士学位, 2004年获南开大学理学博士学位, 同年留校任教至2007年8月, 2007 年9月至2008年6月获法国CNRS博士后基金支持于巴黎第六大学做访问学者, 2008年7月至2011年9月在东京大学做博士后和特任助理教授, 2011年10月至今在中国科学院大连化学物理研究所工作. 目前主要从事宽光谱捕光催化剂全分解水制氢和太阳能光化学转化研究, 研究内容涉及宽光谱捕光光催化材料设计合成, 高效光生电荷分离体系构建以及光催化表面/界面反应机制等方面. 已在包括Nat. Commun., Nature Catal., Joule, J. Am. Chem. Soc., Angew. Chem. Int. Ed., Adv. Mater.等刊物上发表SCI/EI学术论文百余篇. 担任J. Energy Chem.期刊副主编, Sci. China Chem., eScience, Renewable, NSR和化学进展等期刊编委; 可再生能源学会光化学与光催化专业委员会委员, 全国催化青年专业委员会委员, 能源与环境专业委员会委员; 正主持承担国家自然科学基金委重点项目, 国家自然科学基金杰出青年基金项目, 科技部重点专项等. |
收稿日期: 2021-12-30
网络出版日期: 2022-03-29
基金资助
国家自然科学基金(21902156); 国家自然科学基金(21925206)
Photocatalytic Water Splitting for Hydrogen Production※
Received date: 2021-12-30
Online published: 2022-03-29
Supported by
National Natural Science Foundation of China(21902156); National Natural Science Foundation of China(21925206)
利用太阳能光催化分解水制氢是解决能源环境问题并实现太阳能有效转化和储存最有前途的技术之一, 这一“圣杯”式反应经过几十年不懈努力取得了诸多重要研究进展. 本文将综述光催化分解水制氢体系的基本概念、活性测试方法与注意事项、光催化材料种类等; 并从光催化分解水制氢的光吸收、光生电荷分离和表面催化反应等基本过程和关键科学问题的角度总结其重要研究进展, 最后对于太阳能光催化分解水制氢的挑战和潜在的发展方向进行分析和展望. 希望通过本综述的简要介绍能让刚从事光催化分解水制氢研究的青年科技人员清晰地了解掌握该领域的一些基本概念、操作规范、研究总体进展和现状等.
祁育 , 章福祥 . 太阳能光催化分解水制氢※[J]. 化学学报, 2022 , 80(6) : 827 -838 . DOI: 10.6023/A21120607
Photocatalytic water splitting to produce hydrogen is one of the most promising technologies to solve energy and environmental problems and realize the effective conversion and storage of solar energy. And the development of it has attracted more and more attention with the proposed target of peaking carbon dioxide emissions before 2030 and achieving carbon neutrality before 2060. After decades of unremitting efforts, this “Holy Grail” reaction has made many important research progresses. This article will review the basic concepts, activity test methods and precautions, types of photocatalytic reactions and means of measurement for efficiency. The development of photocatalytic materials including inorganic semiconductor including oxide, (oxy)nitride, sulfur oxides, oxyhalide, sulfide and solid solutions, sensitized photocatalytic materials, polymer, metal-organic framework materials, etc. are introduced. The important research progresses from the perspective of basic processes and key scientific issues such as light absorption, photo-generated charge separation and surface catalytic reaction of photocatalytic water splitting to produce hydrogen are summarized. The strategies for improving the charge separation such as construction of heterojunction, and the reduction/oxidation cocatalyst for promoting the surface catalysis are introduced. The research progress of hydrogen production by photocatalytic overall water splitting (OWS) using one-step or two-steps photo-excitation system is also summarized in details. For the one-step system, the different materials and the strategies of realizing OWS are introduced. Moreover, for two-step system, the types of electron transfer medium, the exploration of materials and the inhibition of competing reaction are mainly discussed. Finally, the challenges and potential development directions of photocatalytic water splitting to produce hydrogen are analyzed and prospected. It is hoped that through the brief introduction of this review, young scientific and technical personnel who have just been engaged in this research will have a clear understanding of some basic concepts, operating specifications, research progresses and current status in the field of photocatalytic water splitting.
| [1] | Şen, Z. Energy Combust. Sci. 2004, 30, 367. |
| [2] | Momirlan, M.; Veziroglu, T. N. Int. Hydrog. Energy. 2005, 30, 795. |
| [3] | Hisatomi, T.; Domen, K. Faraday Discuss. 2017, 198, 11. |
| [4] | Chen, S.; Takata, T.; Domen, K. Nat. Rev. Mater. 2017, 2, 17050. |
| [5] | Hisatomi, T.; Domen, K. Nat. Catal. 2019, 2, 387. |
| [6] | Fujishima, A.; Honda, K. Nature 1972, 238, 37. |
| [7] | Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. |
| [8] | Maeda, K.; Domen, K. J. Phys. Chem. C. 2007, 111, 7851. |
| [9] | Yang, J.; Wang, D.; Han, H.; Li, C. Acc. Chem. Res. 2013, 46, 1900. |
| [10] | Wang, Q.; Domen, K. Chem. Rev. 2020, 120, 919. |
| [11] | Maeda, K. J. Photochem. Photobiol. C: Photochem. Rev. 2011, 12, 237. |
| [12] | Hisatomi, T.; Minegishi, T.; Domen, K. Bull. Chem. Soc. Jpn. 2012, 85, 647. |
| [13] | Hisatomi, T.; Kubota, J.; Domen, K. Chem. Soc. Rev. 2014, 43, 7520. |
| [14] | Qureshi, M.; Takanabe, K. Chem. Mater. 2017, 29, 158. |
| [15] | Wang, Z.; Li, C.; Domen, K. Chem. Soc. Rev. 2019, 48, 2109. |
| [16] | Wang, Z.; Hisatomi, T.; Li, R.; Sayama, K.; Liu, G.; Domen, K.; Li, C.; Wang, L. Joule 2021, 5, 344. |
| [17] | Cui, J.; Li, C.; Zhang, F. ChemSusChem 2019, 12, 1872. |
| [18] | Chen, X.; Mao, S. S. Chem. Rev. 2007, 107, 2891. |
| [19] | Grabowska, E. Appl. Catal. B: Environ. 2016, 186, 97. |
| [20] | Ham, Y.; Hisatomi, T.; Goto, Y.; Moriya, Y.; Sakata, Y.; Yamakata, A.; Kubota, J.; Domen, K. J Mater. Chem. A 2016, 4, 3027. |
| [21] | Kato, H.; Kudo, A. J Phy. Chem. B 2001, 105, 4285. |
| [22] | Kato, H.; Asakura, K.; Kudo, A. J. Am. Chem. Soc. 2003, 125, 3082. |
| [23] | Kudo, A.; Sayama, K.; Tanaka, A.; Asakura, K.; Domen, K.; Maruya, K.; Onishi, T. J. Catal. 1989, 120, 337. |
| [24] | Sato, J.; Saito, N.; Nishiyama, H.; Inoue, Y. J Phy. Chem. B 2003, 107, 7965. |
| [25] | Sato, J.; Kobayashi, H.; Inoue, Y. J Phy. Chem. B 2003, 107, 7970. |
| [26] | Sato, J.; Saito, N.; Yamada, Y.; Maeda, K.; Takata, T.; Kondo, J. N.; Hara, M.; Kobayashi, H.; Domen, K.; Inoue, Y. J. Am. Chem. Soc. 2005, 127, 4150. |
| [27] | Chen, S.; Zhang, F. Chin. J. Catal. 2014, 35, 1431. |
| [28] | Chen, S.; Yang, J.; Ding, C.; Li, R.; Jin, S.; Wang, D.; Han, H.; Zhang, F.; Li, C. J Mater. Chem. A 2013, 1, 5651. |
| [29] | Chen, S.; Qi, Y.; Liu, G.; Yang, J.; Zhang, F.; Li, C. Chem. Commun. 2014, 50, 14415. |
| [30] | Dong, B.; Cui, J.; Qi, Y.; Zhang, F. Adv. Mater. 2021, 33, 2004697. |
| [31] | Fujito, H.; Kunioku, H.; Kato, D.; Suzuki, H.; Higashi, M.; Kageyama, H.; Abe, R. J. Am. Chem. Soc. 2016, 138, 2082. |
| [32] | Kunioku, H.; Higashi, M.; Tomita, O.; Yabuuchi, M.; Kato, D.; Fujito, H.; Kageyama, H.; Abe, R. J. Mater. Chem. A 2018, 6, 3100. |
| [33] | Kudo, A.; Kato, H.; Tsuji, I. Chem. Lett. 2004, 33, 1534. |
| [34] | Youngblood, W. J.; Lee, S.-H. A.; Maeda, K.; Mallouk, T. E. Acc. Chem. Res. 2009, 42, 1966. |
| [35] | Houlding, V. H.; Gratzel, M. J. Am. Chem. Soc. 1983, 105, 5695. |
| [36] | Youngblood, W. J.; Lee, S.-H. A.; Kobayashi, Y.; Hernandez-Pagan, E. A.; Hoertz, P. G.; Moore, T. A.; Moore, A. L.; Gust, D.; Mallouk, T. E. J. Am. Chem. Soc. 2009, 131, 926. |
| [37] | Yanagida, S.; Kabumoto, A.; Mizumoto, K.; Pac, C.; Yoshino, K. J. Chem. Soc., Chem. Commun. 1985, 474. |
| [38] | Wang, Y.; Vogel, A.; Sachs, M.; Sprick, R. S.; Wilbraham, L.; Moniz, S. J. A.; Godin, R.; Zwijnenburg, M. A.; Durrant, J. R.; Cooper, A. I.; Tang, J. Nat. Energy 2019, 4, 746. |
| [39] | Zhang, G.; Lan, Z.-A.; Wang, X. Angew. Chem. Int. Ed. 2016, 55, 15712. |
| [40] | Wang, X.; Maeda, K.; Thomas, A.; Takanabe, K.; Xin, G.; Carlsson, J. M.; Domen, K.; Antonietti, M. Nat. Mater. 2009, 8, 76. |
| [41] | Ma, W.; He, Y.; Liu, H. Acta Chim. Sinica 2021, 79, 914. (in Chinese) |
| [41] | (麻旺坪, 贺彦彦, 刘洪来, 化学学报, 2021, 79, 914.) |
| [42] | Lin, L.; Lin, Z.; Zhang, J.; Cai, X.; Lin, W.; Yu, Z.; Wang, X. Nat. Catal. 2020, 3, 649. |
| [43] | Lan, Z.-A.; Wu, M.; Fang, Z.; Zhang, Y.; Chen, X.; Zhang, G.; Wang, X. Angew. Chem., Int. Ed. 2022, DIO: 10. 1002/anie.202201482. |
| [44] | Meyer, K.; Ranocchiari, M.; van Bokhoven, J. A. Energ. Environ. Sci. 2015, 8, 1923. |
| [45] | Shi, Y.; Yang, A.-F.; Cao, C.-S.; Zhao, B. Coord. Chem. Rev. 2019, 390, 50. |
| [46] | Guo, X.; Liu, L.; Xiao, Y.; Qi, Y.; Duan, C.; Zhang, F. Coord. Chem. Rev. 2021, 435, 213785. |
| [47] | Wu, Q.; Zhang, C.; Sun, K.; Jiang, H. Acta Chim. Sinica 2020, 78, 688. (in Chinese) |
| [47] | (吴浅耶, 张晨曦, 孙康, 江海龙, 化学学报, 2020, 78, 688.) |
| [48] | Dhakshinamoorthy, A.; Asiri, A. M.; García, H. Angew. Chem. Int. Ed. 2016, 55, 5414. |
| [49] | Xu, M.; Li, D.; Sun, K.; Jiao, L.; Xie, C.; Ding, C.; Jiang, H.-L. Angew. Chem. Int. Ed. 2021, 60, 16372. |
| [50] | Hu, H.; Wang, Z.; Cao, L.; Zeng, L.; Zhang, C.; Lin, W.; Wang, C. Nat. Chem. 2021, 13, 358. |
| [51] | Linic, S.; Christopher, P.; Ingram, D. B. Nat. Mater. 2011, 10, 911. |
| [52] | Dong, H.; Sun, L.-D.; Yan, C.-H. Chem. Soc. Rev. 2015, 44, 1608. |
| [53] | Liu, G.; Niu, P.; Yin, L.; Cheng, H.-M. J. Am. Chem. Soc. 2012, 134, 9070. |
| [54] | Rahman, M. Z.; Kwong, C. W.; Davey, K.; Qiao, S. Z. Energy Environ. Sci. 2016, 9, 709. |
| [55] | Xu, X.; Randorn, C.; Efstathiou, P.; Irvine, J. T. S. Nat. Mater. 2012, 11, 595. |
| [56] | Maeda, K. Chem. Commun. 2013, 49, 8404. |
| [57] | Maeda, K.; Terashima, H.; Kase, K.; Higashi, M.; Tabata, M.; Domen, K. Bull. Chem. Soc. Jpn. 2008, 81, 927. |
| [58] | Jang, J. S.; Kim, H. G.; Lee, J. S. Cataly. Today 2012, 185, 270. |
| [59] | Xu, Y.; Li, A.; Yao, T.; Ma, C.; Zhang, X.; Shah, J. H.; Han, H. ChemSusChem 2017, 10, 4277. |
| [60] | Chen, S.; Qi, Y.; Hisatomi, T.; Ding, Q.; Asai, T.; Li, Z.; Ma, S. S. K.; Zhang, F.; Domen, K.; Li, C. Angew. Chem. Int. Ed. 2015, 54, 8498. |
| [61] | Qi, Y.; Chen, S.; Li, M.; Ding, Q.; Li, Z.; Cui, J.; Dong, B.; Zhang, F.; Li, C. Chem. Sci. 2017, 8, 437. |
| [62] | Zhang, J.; Xu, Q.; Feng, Z.; Li, M.; Li, C. Angew. Chem. Int. Ed. 2008, 47, 1766. |
| [63] | Wang, X.; Xu, Q.; Li, M.; Shen, S.; Wang, X.; Wang, Y.; Feng, Z.; Shi, J.; Han, H.; Li, C. Angew. Chem. Int. Ed. 2012, 51, 13089. |
| [64] | Chen, S.; Shen, S.; Liu, G.; Qi, Y.; Zhang, F.; Li, C. Angew. Chem. Int. Ed. 2015, 54, 3047. |
| [65] | Zhang, F.; Yamakata, A.; Maeda, K.; Moriya, Y.; Takata, T.; Kubota, J.; Teshima, K.; Oishi, S.; Domen, K. J. Am. Chem. Soc. 2012, 134, 8348. |
| [66] | Wen, F.; Wang, X.; Huang, L.; Ma, G.; Yang, J.; Li, C. ChemSusChem 2012, 5, 849. |
| [67] | Wen, F.; Yang, J.; Zong, X.; Ma, B.; Wang, D.; Li, C. J. Catal. 2011, 281, 318. |
| [68] | Yan, H.; Yang, J.; Ma, G.; Wu, G.; Zong, X.; Lei, Z.; Shi, J.; Li, C. Angew. Chem. Int. Ed. 2009, 266, 165. |
| [69] | Sakata, Y.; Hayashi, T.; Yasunaga, R.; Yanaga, N.; Imamura, H. Chem. Commun. 2015, 51, 12935. |
| [70] | Takata, T.; Jiang, J.; Sakata, Y.; Nakabayashi, M.; Shibata, N.; Nandal, V.; Seki, K.; Hisatomi, T.; Domen, K. Nature 2020, 581, 411. |
| [71] | Nishiyama, H.; Yamada, T.; Nakabayashi, M.; Maehara, Y.; Yamaguchi, M.; Kuromiya, Y.; Nagatsuma, Y.; Tokudome, H.; Akiyama, S.; Watanabe, T.; Narushima, R.; Okunaka, S.; Shibata, N.; Takata, T.; Hisatomi, T.; Domen, K. Nature 2021, 598, 304. |
| [72] | Zou, Z.; Ye, J.; Sayama, K.; Arakawa, H. Nature 2001, 414, 625. |
| [73] | Pan, C.; Takata, T.; Nakabayashi, M.; Matsumoto, T.; Shibata, N.; Ikuhara, Y.; Domen, K. Angew. Chem. Int. Ed. 2015, 54, 2955. |
| [74] | Maeda, K.; Teramura, K.; Lu, D.; Takata, T.; Saito, N.; Inoue, Y.; Domen, K. Nature 2006, 440, 295. |
| [75] | Bard, A. J. J. Photochem. 1979, 10, 59. |
| [76] | Kudo, A. MRS Bulletin 2011, 36, 32. |
| [77] | Maeda, K. ACS Catal. 2013, 3, 1486. |
| [78] | Li, H.; Tu, W.; Zhou, Y.; Zou, Z. Adv. Sci. 2016, 3, 1500389. |
| [79] | Wang, W.; Chen, J.; Li, C.; Tian, W. Nat. Commun. 2014, 5, 4647. |
| [80] | Ma, S. S. K.; Maeda, K.; Abe, R.; Domen, K. Energy Environ. Sci. 2012, 5, 8390. |
| [81] | Qi, Y.; Chen, S.; Cui, J.; Wang, Z.; Zhang, F.; Li, C. Appl. Catal. B: Environ. 2018, 224, 579. |
| [82] | Zhou, P.; Yu, J.; Jaroniec, M. Adv. Mater. 2014, 26, 4920. |
| [83] | Wang, Q.; Hisatomi, T.; Jia, Q.; Tokudome, H.; Zhong, M.; Wang, C.; Pan, Z.; Takata, T.; Nakabayashi, M.; Shibata, N.; Li, Y.; Sharp, I. D.; Kudo, A.; Yamada, T.; Domen, K. Nat. Mater. 2016, 15, 611. |
| [84] | Iwase, A.; Yoshino, S.; Takayama, T.; Ng, Y. H.; Amal, R.; Kudo, A. J. Am. Chem. Soc. 2016, 138, 10260. |
/
| 〈 |
|
〉 |
