刺激响应型树状分子凝胶的研究进展※
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刘志雄, 理学博士, 山西大同大学副教授, CSCP海洋污损防护技术专业委员会委员, 2014 年于中国科学院化学研究所获得理学博士学位, 2015～2019年在中国科学院宁波材料技术与工程研究所从事博士后研究, 2019年初调动至山西大同大学化学与化工学院工作至今, 主要研究方向包括: (1)高分子智能凝胶材料; (2)表界面功能材料. 主持了国家自然科学青年基金, 中国博士后科学基金特别资助、中国博士后科学基金面上资助, 宁波市“科技创新2025”重大专项等科研攻关项目10余项, 在Chem, Bi-omacromolecules, Chem. Mater.,和 Chem. Eng. J.等国际著名专业杂志发表研究论文30余篇, 授权国家发明专利6项. |
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初庆凯, 山西大同大学在读硕士研究生, 主要研究方向: 功能化凝胶材料在金属离子检测、吸附领域中的应用研究. |
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冯宇, 博士, 常州大学材料科学与工程学院教授. 中国科学院青年创新促进会会员、优秀会员. 2010年于中国科学院化学研究所获得理学博士学位, 同年留所工作, 任助理研究员、副研究员, 2016年10月至2018年1月期间在日本北陆先端科学技术大学院大学开展访问研究. 2022年初调动至常州大学材料科学与工程学院工作至今. 主要研究方向包括: (1)功能超分子凝胶; (2)手性功能分子的设计合成、组装及圆偏振发光性能研究; (3)不对称催化. 截至目前, 以项目负责人身份主持国家自然科学基金、中国科学院和中国科学院化学研究所等科研和人才项目10余项. 在Chem. Soc. Rev., Acc. Chem. Res., J. Am. Chem. Soc., Angew. Chem. Int. Ed.等期刊上发表SCI论文50余篇. |
收稿日期: 2022-08-19
网络出版日期: 2022-09-14
基金资助
国家自然科学基金(21871270); 国家自然科学基金(21472192); 山西大同大学博士启动基金(2019-B-01); 山西大同自然科学项目(2020YGZX011); 中国科学院海洋新材料与应用技术重点实验室开放基金(2021K02)
Progress in Stimulus-Responsive Dendritic Gels※
Received date: 2022-08-19
Online published: 2022-09-14
Supported by
National Natural Science Foundation of China(21871270); National Natural Science Foundation of China(21472192); Doctor Research Fund of Shanxi Datong University(2019-B-01); Science Foundation of Shanxi Datong University(2020YGZX011); Open Research Fund of Key Laboratory of Marine Materials and Related Technologies, CAS(2021K02)
近年来, 刺激响应型超分子凝胶作为一类智能软物质材料, 在离子识别材料、自修复材料、生物材料和药物缓释等领域展现出了非常好的应用前景, 受到人们广泛关注. 树状分子是一类具有高度支化结构的大分子, 其形成的凝胶兼具有机小分子凝胶和聚合物凝胶的双重优点, 树状分子丰富的多层次支化几何结构有利于修饰不同功能基团, 从而确保各功能基团彼此独立作用而不相互干扰, 这种特性使其在构筑多功能化凝胶材料, 尤其是多重环境刺激响应型凝胶材料方面具有独特优势. 基于此, 本综述从树状分子凝胶因子设计、成凝胶机理、响应性能和响应机理等方面详细归纳了刺激响应型树状分子凝胶的研究进展. 按照刺激源不同, 主要从光响应型、氧化还原响应型、离子响应型、触变响应型和多重响应型五个方面对刺激响应树状分子凝胶进行了系统归纳总结. 最后, 基于目前刺激响应树状分子凝胶存在的一些问题对该领域未来发展进行了展望.
刘志雄 , 初庆凯 , 冯宇 . 刺激响应型树状分子凝胶的研究进展※[J]. 化学学报, 2022 , 80(10) : 1424 -1435 . DOI: 10.6023/A22080363
In recent years, stimulus-responsive supramolecular gels, as a class of smart soft matter materials, have shown very promising applications in the fields of ion recognition materials, self-healing materials, biomaterials and drug release, and have attracted increasing attentions. Dendrimers and dendrons are highly branched macromolecules with well-defined molecular architecture and have been widely used as building blocks in the self-assembling of supramolecular gel-phase materials. The unique dendritic architectures make the dendritic molecules as ideal candidates to be modified with various different functional moieties to develop multiple functional soft materials, which ensure each functionality to work independently without interfering. This characteristic makes them show unique advantages in the construction of stimuli- responsive gels, especially multiple stimuli-responsive gels. The research progress of stimuli-responsive dendritic gels is summarized in detail from the aspects of dendritic gel design, gel-formation mechanism, response performance and response mechanism. Based on the different stimulus, the stimulus-responsive dendritic gels are classfied into the following categories: light-responsive dendritic gel, redox-responsive dendritic gel, ion-responsive dendritic gel, thixotropic-responsive dendritic gel and multiple-responsive dendritic gel. In addition, the current challenges and perspectives on stimulus-responsive dendritic gels are also discussed.
Key words： supramolecular gels; dendrimer; stimuli-responsive; smart materials; progress
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