用于锂金属电池的聚合物固态电解质的研究进展
 |
谷琪, 就读于南京邮电大学材料科学与工程学院, 2021级电子信息专业硕士生. 主要研究方向为聚离子液体基固态电解质的制备及其在锂金属电池中的应用. |
 |
刘夏夏, 就读于南京邮电大学材料科学与工程学院, 2022级电子信息专业硕士生. 主要研究方向为聚离子液体基固态电解质的制备及其在锂金属电池中的应用. |
 |
周鑫宇, 就读于南京邮电大学材料科学与工程学院, 2022级电子信息专业硕士生. 主要研究方向为聚离子液体基固态电解质的制备及其在锂硫电池中的应用. |
 |
李江, 就读于南京邮电大学材料科学与工程学院, 2022级电子信息专业硕士生. 主要研究方向为硅负极粘结剂的制备及其在锂电池中的应用. |
 |
林秀婧, 2015年博士毕业于复旦大学物理化学专业, 现任南京邮电大学材料科学与工程学院副教授. 主要研究方向为聚离子液体基高分子聚合物的设计合成及应用. |
 |
马延文, 2007年博士毕业于南京大学物理化学专业, 现任苏州工业职业技术学院院长、南京邮电大学材料科学与工程学院纳米材料研究所所长, 入选江苏省“333工程”第三层次培养对象、江苏省六大人才高峰(A类)、“青蓝工程”学术带头人. 长期致力于柔性能源电子器件、锂/钠离子电池和碱金属电池的研究和产业化应用. |
收稿日期: 2023-12-25
网络出版日期: 2024-03-22
基金资助
中国博士后科学基金(2020M681682); 有机电子与信息显示国家重点实验室资助项目(GZR2023010002); 南京邮电大学校级自然科学基金(NY222150)
Recent Progress on Polymer Solid Electrolytes for Lithium Metal Batteries
Received date: 2023-12-25
Online published: 2024-03-22
Supported by
China Postdoctoral Science Foundation(2020M681682); State Key Laboratory of Organic Electronics and Information Displays, Nanjing University of Posts and Telecommunications(GZR2023010002); Natural Science Foundation of Nanjing University of Posts and Telecommunications(NY222150)
谷琪 , 刘夏夏 , 周鑫宇 , 李江 , 林秀婧 , 马延文 . 用于锂金属电池的聚合物固态电解质的研究进展[J]. 化学学报, 2024 , 82(4) : 449 -457 . DOI: 10.6023/A23120541
Lithium metal is considered an ideal negative electrode material for its highest theoretical specific capacity and lowest redox potential. However, traditional lithium metal batteries have faced thorny challenges, primarily due to the growth of lithium dendrites and utilization of leaky, flammable organic liquid electrolyte, which would lead to battery failure and potential safety hazards. Replacing liquid electrolyte with solid-state electrolyte comes out to be a promising solution to the issues above. Recently, polymer solid electrolytes have garnered significant attention for their lightweight, safety, designable structure and excellent mechanical properties, which could restrain the uncontrollable growing of lithium dendrites. However, the high crystallinity and the resultant low ion conductivity at room temperature have impeded their widespread commercialization. Significant efforts have been directed towards the development of polymer solid electrolytes with superior performance. Herein, the recent development of polymer solid electrolyte is reviewed and summarized, including polyether polymers, polycarbonate polymers, fluorinated polymers, poly(ionic liquid) polymers, and single ion conductive polymers. Each of these polymer solid electrolytes offers unique advantages and challenges. The respective properties of different polymer electrolytes and the influence on the electrochemical performance are compared and discussed in detail. This article also focuses on the progress in structural designs and the innovation in synthesis process for different polymer matrixes in order to improve the ion conductivity at room temperature. For structural designs, grafting kinds of polar groups to the matrix structure, or designing various types of chain structures can reduce crystallinity, and thus enhance the ion transport. In addition to the conventional solution-casting method and phase inversion technique, electrospinning method, UV coating and other in-situ processes are utilized in the preparation of polymer solid electrolytes. Finally, in this paper, the existing fundamental research challenges and practical application issues associated with polymer solid electrolytes are thoroughly discussed. It is our sincere hope that this review will offer insights and references for the design, synthesis, and development of novel polymer solid electrolytes, which holds significant promise for electrochemical performance enhancement and safe operation of all-solid-state lithium metal batteries.
| [1] | Kong, Y.-M.; Wang, Z.-Q. Jilin Water Res. 2018, 437, 57. (in Chinese) |
| [1] | (孔玉明, 王志清, 吉林水利, 2018, 437, 57.) |
| [2] | Li, H.-J. China Plant Eng. 2023, 2, 189. (in Chinese) |
| [2] | (李海杰, 中国设备工程, 2023, 2, 189.) |
| [3] | Chen, L.-W.; Gao, R.-Z. Transp. Energy Conser. Envir. Protect. 2021, 17, 14. (in Chinese) |
| [3] | (陈力维, 高润泽, 交通节能与环保, 2021, 17, 14.) |
| [4] | Fan, X.; Zhong, C.; Liu, J.; Ding, J.; Deng, Y.; Han, X.; Zhang, L.; Hu, W.; Wilkinson, D. P.; Zhang, J. Chem. Rev. 2022, 122, 17155. |
| [5] | Lu, G.-L. Mod. Chem. Res. 2021, 20, 159. (in Chinese) |
| [5] | (卢国龙, 当代化工研究, 2021, 20, 159.) |
| [6] | Hu, M.; Wang, H.; Chen, Q. New Energy Vehicles 2020, 9, 8. (in Chinese) |
| [6] | (胡敏, 王恒, 陈琪, 新能源汽车, 2020, 9, 8.) |
| [7] | Ren, Y.-Y. Sci. Technol. Rev. 2017, 35, 26. (in Chinese) |
| [7] | (任耀宇, 科技导报, 2017, 35, 26.) |
| [8] | Du, X.-J.; Peng, H.-L.; Yu, H.-J.; Zhang, H.-B.; Wang, Y. Sci. Technol. Vis. 2019, 18, 91. (in Chinese) |
| [8] | (杜宪军, 彭慧丽, 于恒杰, 张会斌, 王瑛, 科技视界, 2019, 18, 91.) |
| [9] | Mao, J.-R.; Jia, Q.-F.; Zhao, X.; Chen, B.-S.; Zhao, T.-B. Polym. Bull. 2022, 9, 8. (in Chinese) |
| [9] | (毛家容, 贾其凡, 赵芯, 陈宝书, 赵天宝, 高分子通报, 2022, 9, 8.) |
| [10] | Chen, L.; Chi, S.-S.; Dong, Y.; Li, D.; Zhang, B.-C.; Fan, L.-Z. J. Chin. Silic. Soc. 2018, 46, 21. (in Chinese) |
| [10] | (陈龙, 池上森, 董源, 李丹, 张博晨, 范丽珍, 硅酸盐学报, 2018, 46, 21.) |
| [11] | Wei, T.; Lu, J.-H.; Wang, M.-T.; Sun, C.; Zhang, Q.; Wang, S.-J; Zhou, Y.-Y.; Chen, D.-F.; Lan, Y.-Q. Chinese J. Chem. 2023, 41, 1861. |
| [12] | Baskoro, F.; Wong, H. Q.; Yen, H. J. ACS Appl. Energy Mater. 2019, 2, 3937. |
| [13] | Wang, A.-L.; Ji, W.-X.; Chen, J.; Wang, X.-P.; Zhang, T.-Y.; Zhang, L.-Y. Polym. Bull. 2019, 9, 1. (in Chinese) |
| [13] | (王蔼廉, 计文希, 陈婧, 王晓鹏, 张韬毅, 张辽云, 高分子通报, 2019, 9, 1.) |
| [14] | Zhou, W.-D.; Huang, Q.; Xie, X.-X.; Chen, K.-J.; Li, W.; Qiu, J.-S. Energy Storage Sci. Technol. 2022, 11, 1788. (in Chinese) |
| [14] | (周伟东, 黄秋, 谢晓新, 陈科君, 李薇, 邱介山, 储能科学与技术, 2022, 11, 1788.) |
| [15] | Xi, L.; Zhang, D.-C.; Liu, J. Mater. China 2021, 40, 607. (in Chinese) |
| [15] | (习磊, 张德超, 刘军, 中国材料进展, 2021, 40, 607.) |
| [16] | Chen, L.; Huang, Y.; Ma, J.; Ling, H.; Kang, F.; He, Y. Energ Fuel. 2020, 34, 13456. |
| [17] | Liu, L.; Zhang, D.; Xu, X.; Liu, Z.; Liu, J. Chem. Res. Chin. Univ. 2021, 37, 210. |
| [18] | Zhang, D. F.; Liu, M.; Ma, J. B.; Yang, K.; Chen, Z.; Li, K. K.; Zhang, C.; Wei, Y. P.; Zhou, M.; Wang, P.; He, Y. B.; Lv, W.; He, Y. B. Nat. Commun. 2022, 13, 6966. |
| [19] | Fenton, D. M. J. Org. Chem. 1973, 38, 3192. |
| [20] | Berthier, L.; Richard, M.; Henri, D.; Emmanuel, B.; Philippe, J.; Alain, M. J. Agric. Food Chem. 1999, 47, 2193. |
| [21] | Fan, X.-H.; Deng, D.-R.; Wu, Q.-H. J. Jimei Univ., Nat. Sci. 2022, 57, 447. (in Chinese) |
| [21] | (樊晓红, 邓丁榕, 吴启辉, 集美大学学报, 2022, 57, 447.) |
| [22] | Chen, J.-M.; Xiong, J.-W.; Ji, S.-M.; Huo, Y.-P.; Zhao, J.-W.; Liang, L. Prog. Chem. 2021, 32, 481. (in Chinese) |
| [22] | (陈嘉苗, 熊靖雯, 籍少敏, 霍延平, 赵经纬, 梁亮, 化学进展, 2021, 32, 481.) |
| [23] | Choo, Y.; Halat, D. M.; Villaluenga, I.; Timachova, K.; Balsara, N. P. Prog. Polym. Sci. 2020, 103, 101220. |
| [24] | Shi, P. R.; Ma, J. B.; Liu, M.; Guo, S. K.; Huang, Y. F.; Wang, S. W.; Zhang, L. H.; Chen, L. K.; Yang, K.; Liu, X. T.; Li, Y. H.; An, X. F.; Zhang, D. F.; Cheng, X.; Li, Q. D.; Lv, W.; Zhong, G. M.; He, Y. B.; Kang, F. Y. Nat. Nanotechnol. 2023, 18, 602. |
| [25] | Xu, H.; Ye, W.; Wang, Q.; Han, B.; Wang, J.; Wang, C.; Deng, Y. J. Mater. Chem. A 2021, 9, 9826. |
| [26] | Yuan, Y.; Chen, L. K.; Li, Y. H.; An, X. F.; Lv, J. S.; Guo, K.; Cheng, X.; Zhao, Y.; Liu, M.; He, Y. B.; Kang, F. Y. Energy Materials and Devices 2023, 1, 9370004. |
| [27] | Hu, Y.; Xie, X.; Li, W.; Huang, Q.; Huang, H.; Hao, S.; Fan, L.; Zhou, W. ACS Sustain. Chem. Eng. 2023, 11, 1253. |
| [28] | Fu, F.-Y.; Xing, G.-E.; Wang, X.-H.; Gao, Z.-H.; Niu, L.-L. Chem. Bull. 2022, 85, 211. (in Chinese) |
| [28] | (付凤艳, 邢广恩, 王晓红, 高志华, 牛丽丽, 化学通报, 2022, 85, 211.) |
| [29] | Yin, K.; Zhang, Z.; Li, X.; Yang, L.; Tachibana, K.; Hirano, S. J. Mater. Chem. A. 2015, 3, 170. |
| [30] | Tian, S.-W.; Zhou, L.-X.; Zhang, B.-Q.; Zhang, J.-J.; Du, X.-P.; Zhang, H.; Hu, S.-J.; Yuan, Z.-X.; Han, P.-X.; Li, S.-L.; Zhao, W.; Zhou, X.-H.; Cui, G.-L. Acta Chim. Sinica 2022, 80, 56. (in Chinese) |
| [30] | (田宋炜, 周丽雪, 张秉乾, 张建军, 杜晓璠, 张浩, 胡思伽, 苑志祥, 韩鹏献, 李素丽, 赵伟, 周新红, 崔光磊, 化学学报, 2022, 80, 56.) |
| [31] | Song, Z. Y.; Chen, F. F.; Martinez-Iba?ez, M.; Feng, W. F.; Forsyth, M.; Zhou, Z. B.; Armand, M.; Zhang, H. Nat. Commun. 2023, 14, 4884. |
| [32] | Barbosa, J. C.; Goncalves, R.; Costa, C. M.; Lanceros-Mendez, S. ACS Omega 2022, 7, 14457. |
| [33] | Kang, S.-S.; Fan, S.-C.; Liu, Y.; Wei, Y.-C.; Li, Y.; Fang, J.-G.; Meng, C.-Z. Acta Chim. Sinica 2019, 77, 64. (in Chinese) |
| [33] | (康树森, 范少聪, 刘岩, 魏彦存, 李营, 房金刚, 孟垂舟, 化学学报, 2019, 77, 64.) |
| [34] | Qu, X.-X.; Guo, Y.; Liu, X.-K. Chinese J. Chem. 2022, 40, 2559. |
| [35] | Choi, W.; Kang, Y.; Kim, I. J.; Seong, B. G.; Yu, W. R.; Kim, D. W. ACS Appl. Mater. Interfaces 2021, 13, 35664. |
| [36] | Sun, Z.; Li, Y.; Zhang, S.; Shi, L.; Wu, H.; Bu, H.; Ding, S. J. Mater. Chem. A 2019, 7, 11069. |
| [37] | Sun, C.; Yusuf, A.; Li, S.; Qi, X.; Ma, Y.; Wang, D. Chem. Eng. J. 2021, 414, 524. |
| [38] | Caba?ero, M. A.; Boaretto, N.; Naylor, A. J.; Alcaide, F.; Salian, G. D.; Palombarini, F.; Ayerbe, E.; Borras, M.; Casas-Cabanas, M. Adv. Energy Mater. 2022, 12, 33. |
| [39] | Chen, L.; Fu, J.; Lu, Q.; Shi, L.; Li, M.; Dong, L.; Xu, Y.; Jia, R. Chem. Eng. J. 2019, 378, 1667. |
| [40] | Chen, R.; Li, Q.; Yu, X.; Chen, L.; Li, H. Chem. Rev. 2020, 120, 6820. |
| [41] | Yi, J.; Zhou, H. ChemSusChem 2016, 9, 2391. |
| [42] | Chai, J.; Liu, Z.; Ma, J.; Wang, J.; Liu, X.; Liu, H.; Zhang, J.; Cui, G.; Chen, L. Adv. Sci. (Weinh) 2017, 4, 1600377. |
| [43] | Xue, B. J.; Quesnel, F.; Wang, C.; Liu, W. Electrochim. Acta 2009, 44, 269. |
| [44] | Zheng, Z.-N.; Gao, X.; Luo, Y.-W.; Huang, J. J. Chem. Ind. Eng. 2022, 71, 421. (in Chinese) |
| [44] | (郑哲楠, 高翔, 罗英武, 黄杰, 化工学报, 2022, 71, 421.) |
| [45] | Goodenough, J. B. Annu. Rev. Mat. Res. 2003, 33, 91. |
| [46] | Shu, Z. X.; McMillan, R. S.; Murray, J. J. J. Electrochem. Soc. 1993, 140, 922. |
| [47] | Zhao, Y.; Bai, Y.; Li, W.; An, M.; Bai, Y.; Chen, G. Chem. Mater. 2020, 32, 6811. |
| [48] | Yang, J.; Zhang, H.; Zhou, Q.; Qu, H.; Dong, T.; Zhang, M.; Tang, B.; Zhang, J.; Cui, G. ACS Appl. Mater. Interfaces 2019, 11, 17109. |
| [49] | Huang, S.; Cui, Z.; Qiao, L.; Xu, G.; Zhang, J.; Tang, K.; Liu, X.; Wang, Q.; Zhou, X.; Zhang, B.; Cui, G. Electrochim. Acta 2019, 299, 820. |
| [50] | Sha, Y.; Yu, T.; Dong, T.; Wu, X.; Tao, H.; Zhang, H. ACS Appl. Energy Mater. 2021, 4, 14755. |
| [51] | Pan, Q.; Jiang, S.; Li, Z.; Liu, Y.; Du, Y.; Zhao, N.; Zhang, Y.; Liu, J. J. Membr. Sci. 2021, 636, 119601. |
| [52] | Yuan, J. M.; Mecerreyes, D. P.; Antonietti, M. Prog. Polym. Sci. 2013, 38, 1009. |
| [53] | Yu, B.; Zhou, F.; Wang, C.; Liu, W. Eur. Polym. J. 2007, 43, 2699. |
| [54] | Guo, C.; Cao, Y.; Li, J.; Li, H.; Kumar, S.; Oleksandr, S.; Chen, F. Appl. Energ. 2022, 323, 119571. |
| [55] | Lin, X. J.; Xu, S. Y.; Tong, Y. Q.; Liu, X. S.; Liu, Z. Y.; Li, P.; Liu, R. Q.; Feng, X. M.; Shi, L.; Ma, Y. W. Mater. Horiz. 2023, 10, 859. |
| [56] | Ye, Y.; Elabd, Y. Polymer 2011, 52, 1309. |
| [57] | Meng, N.; Ye, Y. N.; Yang, Z. X.; Li, H.; Lian, F. Adv. Funct. Mater. 2023, 33, 2305072. |
| [58] | Zhang, Y.-F.; Wang, J.-Y.; Li, X.-J.; Zhao, S.-Y.; He, Y.; Huo, S.-K.; Wang, Y.-Y.; Tan, C. J. Electrochem. 2021, 27, 413. (in Chinese) |
| [58] | (张运丰, 王佳颖, 李晓洁, 赵诗宇, 何阳, 霍士康, 王雅莹, 谭畅, 电化学, 2021, 27, 413.) |
| [59] | Renaud, B.; Sébastien, M.; Rachid, M.; Abdelmaula, A.; Livie, L.; Jean, P. B.; Trang, N. T.; Denis, B.; Didier, G.; Didier, D.; Denoyel, R.; Armand, M. Nat. Mater. 2013, 9, 1. |
| [60] | Qiao, L.; Rodriguez, P. S.; MartinezIbanez, M.; Santiago, A.; Aldalur, I.; Lobato, E.; SanchezDiez, E.; Zhang, Y.; Manzano, H.; Zhu, H.; Forsyth, M.; Armand, M.; Carrasco, J.; Zhang, H. J. Am. Chem. Soc. 2022, 144, 9806. |
| [61] | Zhang, Y.-F.; Dong, J.-M.; Tan, C.; Huo, S.-K.; Wang, J.-Y.; He, Y.; Wang, Y.-Y. J. Electrochem. 2021, 27, 108. (in Chinese) |
| [61] | (张运丰, 董佳明, 谭畅, 霍士康, 王佳颖, 何阳, 王雅莹, 电化学, 2021, 27, 108.) |
| [62] | Zhou, H.-L.; Ma, X.-Y.; Wang, Y.-F.; Guan, X.; Wang, B. Acta Chim. Sinica 2012, 70, 783. (in Chinese) |
| [62] | (周华龙, 马晓燕, 王毅霏, 管兴, 王波, 化学学报, 2012, 70, 783.) |
| [63] | Xie, J. B.; Xu, H. L.; Wang, Q. R.; Ke, R. H.; Han, B.; Chang, J.; Wang, J.; Deng, Y. H. J. Electrochem. Soc. 2022, 169, 562. |
| [64] | Liu, X.; Ding, G.; Zhou, X.; Li, S.; He, W.; Chai, J.; Pang, C.; Liu, Z.; Cui, G. J. Mater. Chem. A 2017, 5, 11124. |
| [65] | Chen, Z.-P.; Huang, S.-X.; Zhu, H.-B.; Feng, Y.-F. Insul. Mater. 2018, 51, 1. (in Chinese) |
| [65] | (陈志平, 黄孙息, 朱恒斌, 冯羽风, 绝缘材料, 2018, 51, 1.) |
| [66] | Wang, L.; Xu, S.; Wang, Z.; Yang, E.; Jiang, W.; Zhang, S.; Jian, X.; Hu, F. eScience 2023, 3, 100090. |
| [67] | Yang, Q.; Deng, N.-P.; Cheng, B.-W.; Kang, W.-M. Prog. Chem. 2022, 33, 2270. (in Chinese) |
| [67] | (杨琪, 邓南平, 程博闻, 康卫民, 化学进展, 2022, 33, 2270.) |
| [68] | Whba, R.; Su'ait, M. S.; TianKhoon, L.; Ibrahim, S.; Mohamed, N. S.; Ahmad, A. React. Funct. Polym. 2021, 164, 104938. |
| [69] | Tseng, Y.-C.; Hsiang, S.-H.; Lee, T.-Y.; Teng, H.; Jan, J.-S.; Kyu, T. ACS Appl. Energ. Mater. 2021, 4, 14309. |
| [70] | Zheng, T.; Liu, J.; Li, Y.; Lin, S.; Zhou, J. Chin. J. Power Sources 2021, 5, 569. (in Chinese) |
| [70] | (郑涛, 刘婧, 李杨, 林桑, 周江, 电源技术, 2021, 5, 569.) |
| [71] | Vijayakumar, V.; Anothumakkool, B.; Kurungot, S.; Winter, M.; Nair, J. R. Energy Environ. Sci. 2021, 14, 2708. |
| [72] | Niu, C.; Zhang, M.; Chen, G.; Cao, B.; Shi, J.; Du, J.; Chen, Y. Electrochim. Acta 2018, 283, 349. |
| [73] | Yan, Y. Y.; Ju, J. W.; Dong, S. M.; Wang, Y. T.; Huang, L.; Cui, L. F.; Jiang, F.; Wang, Q. L.; Zhang, Y. F.; Cui, G. Adv. Sci. 2021, 8, 2003887. |
| [74] | Tian, J.-X.; Guo, H.-J.; Wan, J.; Liu, G.-X.; Yan, H.-J.; Wen, R.; Wan, L. J. Acta Chim. Sinica 2021, 79, 1179. (in Chinese) |
| [74] | (田建鑫, 郭慧娟, 万静, 刘桂贤, 严会娟, 文锐, 万立骏, 化学学报, 2021, 79, 1179.) |
| [75] | Yang, K.; Zhao, L.; An, X. F.; Chen, L. K.; Ma, J. B.; Mi, J. S.; He, Y. B. Angew. Chem. Int. Ed. 2023, 62, e202302586. |
/
| 〈 |
|
〉 |
