Fabrication of Honeycomb Polymeric Films via Breath-figure Process under Methanol Atmosphere

doi:10.6023/A1107291

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (01): 45-50.DOI: 10.6023/A1107291 Previous Articles Next Articles

Full Papers

甲醇气氛静态呼吸图法制备蜂窝状有序多孔膜

兰平^a, 李剑^b, 龚剑亮^b, 李磊^b

a. 嘉兴学院高分子系, 嘉兴 314001;
b. 厦门大学材料学院, 厦门 361005

投稿日期:2011-07-29 修回日期:2011-09-17 发布日期:2012-02-25
通讯作者: 兰平, 李磊 E-mail:lanping007@126.com;lilei@xmu.edu.cn
基金资助:
国家自然科学基金(Nos.21174116,20974089,51035002)、福建省杰出青年基金(No.2009J06029)、教育部新世纪人才基金(No.NCET-08-0475)、浙江省自然科学基金(No.Y4110606)、浙江省重点科技创新团队(No.2010R50012)子项目及浙江嘉兴市生物医用高分子材料重点科技创新团队项目资助.

Fabrication of Honeycomb Polymeric Films via Breath-figure Process under Methanol Atmosphere

Lan Ping^a, Li Jian^b, Gong Jianliang^b, Li Lei^b

a. Institute of Polymer Material Engineering, Jiaxing University, Jiaxing 314001;
b. College of Materials, Xiamen University, Xiamen 361005

Received:2011-07-29 Revised:2011-09-17 Published:2012-02-25
Supported by:
Projects was supported by the National Natural Science Foundation of China(Nos.21174116,20974089,51035002),the Outstanding Youth Foundation of Fujian Province(No.2009J06029),New Century Talents Foundation from Ministry of Education of China(NCET-08-0475),Natural Science Foundation of Zhejiang Province(No.Y4110606),Sub-project of Key Technological Innovation Team of Zhejiang Province(No.2010R50012)and Key Technological In- novation Team of Biomedical Polymer Materials in Jiaxing City.

In this paper,highly ordered honeycomb polymeric films were prepared via a static breath-figure process under methanol atmosphere for the first time.The employed block copolymer, poly(dimethylsiloxane)-block-polystyrene(PDMS-b-PS),was synthesized by atom transfer radical polym- erization.The influences of vapor atmosphere and the concentration of polymer solution on the morphology of the porous films were also investigated.Versus the morphologies of honeycomb polymer films fabricated under the saturated relative humidity,it was found that the average pore size of honeycomb films increased and the cross-sectional view of pore appeared in a shape of“U”.This research may be helpful to explore the formation mechanism of honeycomb porous structures during the breath figure process.

Key words: static breath figure, block copolymer, honeycomb structure

Cite this article

Lan Ping, Li Jian, Gong Jianliang, Li Lei. Fabrication of Honeycomb Polymeric Films via Breath-figure Process under Methanol Atmosphere[J]. Acta Chimica Sinica, 2012, 70(01): 45-50.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

1(a)Aitken, J. In Proceedings of the Royal Society of Edin- burgh, Cambridge University, Cambridge 1893, pp. 94～97. (b)Aitken, J. Nature 1911, 86, 516. (c)Rayleigh, L. Nature 1911, 86, 416. (d)Rayleigh, L. Nature 1912, 90, 436. (e)Steyer, A. ; Guenoun, P. ; Beysens, D. Phys. Rev. B 1990, 42, 1086. (f)Knobler, C. ; Beysens, D. Europhys. Lett. 1988, 6, 707. (g)Bunz, U. H. F. Adv. Mater. 2006, 18, 973.

2 Widawski, G. ; Rawiso, M. ; Francois, B. Nature 1994, 369, 387.

3 Srinivasarao, M. ; Collings, D. ; Philips, A. ; Patel, S. Science2001, 292, 79.

4(a)Li, L. ; Zhong, Y. W. ; Ma, C. Y. ; Li, J. ; Chen, C. K. ; Zhang, A. J. ; Tang, D. L. ; Xie, S. Y. ; Ma, Z. Chem. Mater. 2009, 21, 4977. (b)Ma, C. Y. ; Zhong, Y. W. ; Li, J. ; Chen, C. K. ; Gong, J. L. ; Xie, S. Y. ; Li, L. ; Ma, Z. Chem. Mater. 2010, 22, 2367.

5 Li, X. F. ; Zhang, L. ; Wang, Y. X. ; Yang, X. L. ; Zhao, N. ; Zhang, X. L. ; Xu, J. J. Am. Chem. Soc. 2011, 133, 3736.

6 Li, L. ; Zhong, Y. W. ; Chen, C. K. ; Li, J. Acta Phys. -Chim. Sin. 2010, 26, 1135(in Chinese). (李磊, 钟雅文, 陈财康, 李剑, 物理化学学报, 2010, 26, 1135. )

7 Li, L. ; Zhong, Y. W. ; Gong, J. L. ; Li, J. ; Chen, C. K. ; Zeng, B. R. ; Ma, Z. Soft Matter 2011, 7, 546.

8 Li, L. ; Chen, C. K. ; Zhang, A. J. ; Liu, X. Y. ; Cui, K. ; Huang, J. ; Ma, Z. ; Han, Z. H. J. Colloid Interface Sci. 2009, 331, 446.

9 Li, L. ; Li, J. ; Zhong, Y. W. ; Chen, C. K. ; Ben, Y. ; Gong, J. L. ; Ma, Z. J. Mater. Chem. 2010, 20, 5446.

10 Li, L. ; Zhong, Y. W. ; Gong, J. L. ; Li, J. ; Huang, J. ; Ma, Z. J. Colloid Interface Sci. 2011, 354, 758.

11 Li, L. ; Chen, C. K. ; Li, J. ; Zhang, A. J. ; Liu, X. Y. ; Xu, B. ; Gao, S. B. ; Jin, G. H. ; Ma, Z. J. Mater. Chem. 2009, 19, 2789.

12 Li, L. ; Zhong, Y. W. ; Li, J. ; Chen, C. K. ; Zhang, A. J. ; Xu, J. ; Ma, Z. J. Mater. Chem. 2009, 19, 7222.

[1]	Weihua Li. “Bridge” Makes Differences to the Self-assembly of Block Copolymers [J]. Acta Chimica Sinica, 2021, 79(2): 133-138.
[2]	Li Rongye, Khiman Mehul, Sheng Li, Sun Jing. pH/Solvent Tunable Hierarchical Nanostructures Assembled from an Amphiphilic Polypeptide-containing Triblock Copolymer [J]. Acta Chimica Sinica, 2020, 78(11): 1235-1239.
[3]	Cui Huina, Qiu Feng, Peng Juan. Synthesis and Properties of an All-Conjugated Polythio-phene-Polyselenophene Diblock Copolymer [J]. Acta Chim. Sinica, 2018, 76(9): 691-700.
[4]	Liu Ming, Yang Yingzi, Qiu Feng. A Strong Segregation Theory for Ring Block Copolymers [J]. Acta Chim. Sinica, 2017, 75(9): 884-892.
[5]	Ding Yanchun, Yu Yanlei, Wei Jia. Synthesis and Self-assembly Behavior of Photo-responsive Diblock Copolymers with Different Hydrophilic/Hydrophobic Ratios [J]. Acta Chimica Sinica, 2014, 72(5): 602-608.
[6]	Zhang Guangmeng, Yang Jiping, Chen Gong. Self-assembly of Tetraaniline-PEG-Tetraaniline Block Copolymer Thin Films [J]. Acta Chimica Sinica, 2014, 72(1): 83-88.
[7]	Wang Ruijuan, Wang Yilin. Interaction of Anionic Sulfonate Gemini Surfactant with PEO-PPO-PEO Triblock Copolymers [J]. Acta Chimica Sinica, 2014, 72(1): 41-50.
[8]	Xia Binkai, Li Weihua, Qiu Feng. Self-assembling Behaviors of Symmetric Diblock Copolymers in C Homopolymers [J]. Acta Chimica Sinica, 2014, 72(1): 30-34.
[9]	Yang Hui, Peng Juan, Qiu Feng. The Influencing Factors on the Ring-shaped Morphology in PI-b-P2VP Diblock Copolymer [J]. Acta Chimica Sinica, 2013, 71(08): 1141-1148.
[10]	Pan Gaoxiang, Feng Ze, Wei Jia, Yu Yanlei. Synthesis and Self-assembly Behavior of a Thermo-/photo-dual Responsive Triblock Copolymer [J]. Acta Chimica Sinica, 2013, 71(05): 733-738.
[11]	Hu Fangzhen, Chen Shengdian, Li Hui, Sun Jingjing, Sheng Ruilong, Luo Ting, Cao Amin. Preparation of New Amphiphilic Liquid-Crystal Diblock Copolymers Bearing Side-on Cholesteryl Mesogen and Their Self-aggregation [J]. Acta Chimica Sinica, 2013, 71(03): 351-359.
[12]	Sun Nuannuan, Li Yiming, Wang Dongxiang, Bao Mutai, Tong Linjuan. Mesoscopic Simulation Studies on the Self-assembly of Pluronic at Oil/Water Interface [J]. Acta Chimica Sinica, 2013, 71(02): 186-192.
[13]	Ma Yuhong, Zhang Bing, Zhao Changwen, Liu Lianying, Jiang Shan, Liang Shujun, Yang Wantai. A Novel Macroinitiator Based on the Copolymer of α-Methylstyrene Synthesis and Its Application in Preparing Block and Graft Polymers [J]. Acta Chimica Sinica, 2013, 71(02): 151-158.
[14]	Lu Weitao, Yang Jiping. Synthesis and Characterization of Tetraaniline-Polyethylene Glycol Block and Star-shaped Copolymers [J]. Acta Chimica Sinica, 2013, 71(01): 121-125.
[15]	Liu Hongyan, Guo Hongyu, Zhou Jian. Computer Simulations on the Anticancer Drug Delivery System of Docetaxel and PLGA-PEG Copolymer [J]. Acta Chimica Sinica, 2012, 70(23): 2445-2450.

甲醇气氛静态呼吸图法制备蜂窝状有序多孔膜

Fabrication of Honeycomb Polymeric Films via Breath-figure Process under Methanol Atmosphere

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments