Reactivity of Dinuclear Ruthenium Complex Containing One μ-Se2 Unit and Two 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands toward (cyclo-C6H10)(OH)C≡CH

doi:10.6023/A13030346

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (06): 892-896.DOI: 10.6023/A13030346 Previous Articles Next Articles

Article

含桥连Se—Se基团和两个(S₂C₂B₁₀H₁₀)^2-离子的不饱和双核钌化合物与l-乙炔基环己醇的反应性

胡久荣^a,b, 彭化南^b, 胡昕^b, 叶红德^b, 燕红^a

a 南京大学化学化工学院配位化学国家重点实验室南京 210093;
b 上饶师范学院化学化工学院上饶 334001

投稿日期:2013-03-29 发布日期:2013-05-02
通讯作者: 胡久荣,hyan1965@nju.edu.cn;燕红,jiuronghu@163.com E-mail:hyan1965@nju.edu.cn;jiuronghu@163.com
基金资助:
项目受国家自然科学基金(Nos. 21261020, 21271102)、江西省高等学校科技落地计划(No. KJLD12094)和江西省普通高校重点实验室科研项目(No. GJJ12704)资助.

Reactivity of Dinuclear Ruthenium Complex Containing One μ-Se₂ Unit and Two 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands toward (cyclo-C₆H₁₀)(OH)C≡CH

Hu Jiurong^a,b, Peng Huanan^b, Hu Xin^b, Ye Hongde^b, Yan Hong^a

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Jiangsu 210093;
b School of Chemistry and Chemical Engineering, Shangrao Normal University, Jiangxi 334001

Received:2013-03-29 Published:2013-05-02
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21261020, 21271102), the Scientific and Technological Landing Project of Higher Education of Jiangxi Province (No. KJLD12094), and the Science and Technology Research Project of Key Laboratory of Higher Institutions of Jiangxi Province (No. GJJ12704).

Abstract

Treatment of (p-cymene)Ru₂(μ-Se₂)(S₂C₂B₁₀H₁₀)₂(1) with (cyclo-C₆H₁₀)(OH)C≡CH in dichloromethane led to addition complexes, (p-cymene)Ru₂(μ-Se₂)(S₂C₂B₁₀H₁₀)₂(R¹C=CR²) [R¹=H, R²=(cyclo-C₆H₁₀)(OH) (2); R¹=(cyclo-C₆H₁₀)(OH), R²=H (3)]. In boiling chloroform both 2 and 3 spontaneously lose water to generate two geometrical isomers (p-cymene)Ru₂(μ-Se₂)(S₂C₂B₁₀H₁₀)₂ (R¹C=CR²) [R¹=H, R²=cyclo-C₆H₉ (4); R¹=cyclo-C₆H₉, R²=H (5)], respectively. Complexes 4 and 5 could be interconverted in refluxing toluene. In all products alkyne addition occurs at the sulfur atoms of the two individual chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligands that leads to a change of the 16e Ru(IV) center in 1 to the 18e Ru(II) center in 2～5. The molecular structure of complex 2 has been determined by X-ray crystallography. All these complexes were characterized by elemental analysis, mass and NMR spectroscopy.

Key words: ortho-carborane, (cyclo-C₆H₁₀)(OH)C≡CH, chalcogenide element, ruthenium complexes, synthesis

Cite this article

Hu Jiurong, Peng Huanan, Hu Xin, Ye Hongde, Yan Hong. Reactivity of Dinuclear Ruthenium Complex Containing One μ-Se₂ Unit and Two 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands toward (cyclo-C₆H₁₀)(OH)C≡CH[J]. Acta Chimica Sinica, 2013, 71(06): 892-896.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] (a) Xie, Z. Coord. Chem. Rev. 2006, 250, 259; (b) Deng, L.; Xie, Z. Coord. Chem. Rev. 2007, 251, 2452; (c) Armstronga, A. F.; Valliant, J. F. Dalton Trans. 2007, 4240; (d) Liu, D.; Dang, L.; Sun, Y.; Chan, H. S.; Lin, Z.; Xie, Z. J. Am. Chem. Soc. 2008, 130, 16103.

[2] (a) Hawthorne, M. F.; Zink, J. I.; Skelton, J. M.; Bayer, M. J.; Liu, C.; Livshits, E.; Baer, R.; Neuhauser, D. Science 2004, 303, 1849; (b) Wedge, T. J.; Hawthorne, M. F. Coord. Chem. Rev. 2003, 240, 111; (c) Xie, Z. Acc. Chem. Res. 2003, 36, 1; (d) Lee, J. D.; Lee, Y. J.; Son, K. C.; Cheong, M.; Ko, J.; Kang, S. O. Organometallics 2007, 26, 3374.

[3] (a) Núñez, R.; Tutusaus, O.; Teixidor, F.; Viñas, C.; Sillanpää, R.; Kivekäs, R. Organometallics 2004, 23, 2273; (b) Chizhevsky, I. T. Coord. Chem. Rev. 2007, 251, 1590; (c) Juhasz, M.; Hoffmann, S.; Stoyanov, E.; Kim, K. C.; Reed, C. A. Angew. Chem., Int. Ed. 2004, 43, 5352.

[4] (a) Meng, X.; Wang, F. S.; Jin, G. X. Coord. Chem. Rev. 2010, 254, 1260; (b) Liu, S.; Han, Y. F.; Jin, G. X. Chem. Soc. Rev. 2007, 36, 1543; (c) Jin, G. X. Coord. Chem. Rev. 2004, 248, 587; (d) Yao, Z. J.; Jin, G. X. Organometallics 2011, 30, 5365; (e) Zhang, J. S.; Lin, Y. J.; Jin, G. X. J. Organomet. Chem. 2009, 694, 2069; (f) Yao, Z. J.; Su, G.; Jin, G. X. Chem. Eur. J. 2011, 17, 13298; (g) Yao, Z. J.; Jin, G. X. Coord. Chem. Rev. 2013, 257, in press (doi: 10.1016/j.ccr.2013.02.004).

[5] (a) Xu, B. H.; Peng, X. Q.; Li, Y. Z.; Yan, H. Chem. Eur. J. 2008, 14, 9347; (b) Xu, B. H.; Tao, J. C.; Li, Y. Z.; Li, S. H.; Yan, H. Organometallics 2008, 27, 334; (c) Li, Y. G.; Jiang, Q. B.; Zhang, X. L.; Li, Y. Z.; Yan, H.; Bregadze, V. I. Inorg. Chem. 2010, 49, 3911; (d) Ye, H. D.; Ding, G. Y.; Xie, M. S.; Li, Y. Z.; Yan, H. Dalton Trans. 2011, 40, 2036; (e) Li, Y. G.; Jiang, Q. B.; Li, Y. Z.; Yan, H.; Bregadze, V. I. Inorg. Chem. 2010, 49, 4.

[6] (a) Herberhold, M.; Yan, H.; Milius, W.; Wrackmeyer, B. J. Organomet. Chem. 2000, 604, 170; (b) Herberhold, M.; Yan, H.; Milius, W.; Wrackmeyer, B. Angew. Chem. Int. Ed. 1999, 38, 3689; (c) Wang, J. Q.; Cai, S. Y.; Jin, G. X.; Weng, L. H.; Herberhold, M. Chem. Eur. J. 2005, 11, 7342; (d) Jin, G. X.; Wang, J. Q.; Zhang, C.; Weng, L. H.; Herberhold, M. Angew. Chem. Int. Ed. 2005, 44, 259; (e) Zhang, J. S.; Lin, Y. J.; Jin, G. X. Dalton Trans. 2009, 111; (f) Wang, J. Q.; Ren, C. X.; Weng, L. H.; Jin, G. X. Chem. Commun. 2006, 162.

[7] (a) Hu, J. R.; Liu, G. F.; Jiang, Q. B.; Zhang, R.; Huang, W.; Yan, H. Inorg. Chem. 2010, 49, 11199; (b) Hu, J. R.; Wen, J. L.; Wu, D. H.; Zhang, R.; Liu, G. F.; Jiang, Q. B.; Li, Y. Z.; Yan, H. Organometallics 2011, 30, 298; (c) Hu, J. R.; Tang, X.; Liu, G. F.; Jiang, Q. B.; Duanmu, D. D.; Li, Y. Z.; Yan, H. J. Organomet. Chem. 2012, 721-722, 36.

[8] (a) Herberhold, M.; Yan, H.; Milius, W.; Wrackmeyer, B. Chem. Eur. J. 2000, 6, 3026; (b) Herberhold, M.; Yan, H.; Milius, W.; Wrackmeyer, B. Chem. Eur. J. 2002, 8, 388; (c) Wu, D. H.; Wu, C. H.; Li, Y. Z.; Guo, D. D.; Wang, X. M.; Yan, H. Dalton Trans. 2009, 285; (d) Herberhold, M.; Yan, H.; Milius, W. J. Organomet. Chem. 2000, 598, 142.

[9] (a) Wu, D. H.; Ji, C.; Li, Y. Z.; Yan, H. Organometallics 2007, 26, 1560; (b) Wu, D. H.; Xu, B. H.; Li, Y. Z.; Yan, H. Organometallics 2007, 26, 6300.

[10] Wu, D. H.; Li, Y. G.; Han, L.; Li, Y. Z.; Yan, H. Inorg. Chem. 2008, 47, 6524.

[11] Bennett, M. A.; Huang, T. N.; Matheson, T. W.; Smith, A. K. Inorg. Synth. 1982, 21, 74.

[12] Bruker, SMART (Version 5.0), SAINT (Version 6), SHELXTL (Version 6.1) and SADABS (Version 2.03). Bruker AXS Inc., Madison, Wisconsin, USA, 2000.

[1]	Lingyue Yang, Yunting Li, Chao Shu. Research Progress on Sultine [J]. Acta Chimica Sinica, 2024, 82(2): 171-189.
[2]	Yi Wan, Jianghua He, Yuetao Zhang. Research Progress in Precision Polymerization of Polar Olefin Monomers by Lewis Pairs^★ [J]. Acta Chimica Sinica, 2023, 81(9): 1215-1230.
[3]	Shaoyan Gan, Shengyu Zhong, Liting Wang, Lei Shi. Synthesis and Application of Organic Hypervalent Bromine Reagents [J]. Acta Chimica Sinica, 2023, 81(8): 1030-1042.
[4]	Mei Hong, Jinqiang Gao, Tong Li, Shihe Yang. In-situ Etching Strategy for Manipulation of Hierarchical Zeolite and Its Application^★ [J]. Acta Chimica Sinica, 2023, 81(8): 937-948.
[5]	Wenshan Zheng, Guanbin Gao, Hao Deng, Taolei Sun. Room Temperature Synthesis and Near-infrared Fluorescence Performance Optimization of Ag₂Se@Ag₂S Core-shell Quantum Dots [J]. Acta Chimica Sinica, 2023, 81(7): 763-770.
[6]	Yandong Zhang, Shoufei Zhu. Perspective for Phosphine Ligands with Cyclopropane Backbone^★ [J]. Acta Chimica Sinica, 2023, 81(7): 777-783.
[7]	Kanbinuer Nuermaimaiti, Chao Wang, Shiwei Luo, Abudu Rexit Abulikemu. Research on Selective Dehalogenation of α,α,α-Trihalogen (Chloro, Bromo) methyl Ketones Under Electrochemical Conditions [J]. Acta Chimica Sinica, 2023, 81(6): 582-587.
[8]	Li Liu, Gang Zheng, Guoqiang Fan, Hongguang Du, Jiajing Tan. Research Progress in Organic Reactions Involving 4-Acyl/Carbamoyl/Alkoxycarbonyl Substituted Hantzsch Esters [J]. Acta Chimica Sinica, 2023, 81(6): 657-668.
[9]	Wang Jun, Xu Xiaomei, Zhou Jiaolong, Zhao Yanan, Sun Xiuli, Tang Yong, He Sufang, Yang Hongmei. Synthesis of New Sulfur-free and Phosphorus-free Ether-ester and Study on Its Properties As Ashless Friction Modifier [J]. Acta Chimica Sinica, 2023, 81(5): 461-468.
[10]	Junchang Chen, Mingxing Zhang, Shuao Wang. Research Progress of Synthesis Methods for Crystalline Porous Materials [J]. Acta Chimica Sinica, 2023, 81(2): 146-157.
[11]	Yang Gao, Xuexin Zhang, Jinsheng Yu, Jian Zhou. Recent Advances in Catalytic Enantioselective Synthesis of α-Chiral Tertiary Azides^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1590-1608.
[12]	Hongdan Zhang, Xinyu Lan, Peng Cheng. Advances in Hydroxyl Free Radical Assisted Synthesis of Zeolite [J]. Acta Chimica Sinica, 2023, 81(1): 100-110.
[13]	Xiaochen Wang, Zeyao Ji, Jian Liu, Bingfu Wang, Hui Jin, Lixin Zhang. Advances in Organocatalytic Asymmetric Reactions Involving Thioesters [J]. Acta Chimica Sinica, 2023, 81(1): 64-83.
[14]	Zhiping Chen, Yongle Meng, Jing Lu, Wenwu Zhou, Zhiyuan Yang, Anning Zhou. Preparation of Fe@Si/S-34 Catalysts and Its Catalytic Performance for Syngas to Olefins [J]. Acta Chimica Sinica, 2023, 81(1): 14-19.
[15]	Zhihao Qi, Fujie Gao, Changkai Zhou, Yu Zeng, Qiang Wu, Lijun Yang, Xizhang Wang, Zheng Hu. Ruthenium Nanoparticles Anchored on Nitrogen-Doped Carbon Nanocages for Fischer-Tropsch Synthesis [J]. Acta Chimica Sinica, 2022, 80(8): 1100-1105.

含桥连Se—Se基团和两个(S₂C₂B₁₀H₁₀)^2-离子的不饱和双核钌化合物与l-乙炔基环己醇的反应性

Reactivity of Dinuclear Ruthenium Complex Containing One μ-Se₂ Unit and Two 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands toward (cyclo-C₆H₁₀)(OH)C≡CH

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

含桥连Se—Se基团和两个(S2C2B10H10)2-离子的不饱和双核钌化合物与l-乙炔基环己醇的反应性