Phase Transition Behavior of Zeolite Y under Hydrothermal Conditions

doi:10.6023/A17040169

Acta Chim. Sinica ›› 2017, Vol. 75 ›› Issue (7): 679-685.DOI: 10.6023/A17040169 Previous Articles Next Articles

Article

水热条件下Y型沸石的转晶行为

胡成玉, 闫文付, 徐如人

吉林大学化学学院无机合成与制备国家重点实验室长春 130012

投稿日期:2017-04-19 发布日期:2017-06-08
通讯作者: 闫文付 E-mail:yanw@jlu.edu.cn
基金资助:
项目受国家自然科学基金（Nos.21571075，21320102001，21621001）、国家重大研发计划（No.2016YFB0701100）和高等学校学科创新引智计划（No.B17020）资助.

Phase Transition Behavior of Zeolite Y under Hydrothermal Conditions

Hu Chengyu, Yan Wenfu, Xu Ruren

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012

Received:2017-04-19 Published:2017-06-08
Contact: 10.6023/A17040169 E-mail:yanw@jlu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos.21571075,21320102001,21621001),the National Key Research and Development Program of China (No.2016YFB0701100) and the Programme of Introducing Talents of Discipline to Universities (No.B17020).

1. Phase Transition Behavior of Zeolite Y under Hydrothermal Conditions.PDF(1613KB)

Abstract

The phase transition behavior of zeolite Y (HY and NaY) to zeolite MER in the KOH solution under hydrothermal conditions was systematically investigated.Zeolite MER has four types of 8-membered ring channels (3.1 Å×3.5 Å,2.7 Å×3.6 Å,3.4 Å×5.1 Å,3.3 Å×3.3 Å) and important potential applications in small molecule catalysis and separation.Seven to ten days are needed to synthesize highly crystalline zeolite MER with traditional hydrothermal synthesis.With phase transition of zeolite Y in the KOH solution under hydrothermal treatment,highly crystalline zeolite MER can be obtained within two days.The synthetic system contains zeolite Y (HY and NaY),KOH,and water,where KOH/SiO₂ and H₂O/SiO₂ are changeable.Hydrothermally treating the equivalent amorphous aluminosilicate gel resulted in the mixture of zeolite MER and zeolite LTL (for HY) or zeolite CHA (for NaY) with low degree of crystallinity.Phase transition of HY can be conducted at either 100 or 150℃,whereas that of NaY can only be conducted at 150℃.As a common process for the hydrothermal phase transition of zeolite Y to zeolite MER in the absence of organic templates,potassium hydroxide was first dissolved into deionized H₂O.After stirring at room temperature for 5 min,zeolite Y (HY or NaY) as aluminum and silicon sources was introduced into the potassium hydroxide solution.After further stirring for 1 h,the mixture was transferred into an autoclave for crystallization at elevated temperature (i.e.100 or 150℃).After filtrating,washing with deionized water and drying,zeolite products were obtained.The zeolite products were characterized by X-ray diffraction (XRD),scanning electron microscopy (SEM),thermogravimetric analysis (TGA),and inductively coupled plasma emission spectrometer (ICP).KOH/SiO₂ and H₂O/SiO₂ have significant influence on the phase transition behavior of zeolite Y.Highly crystalline zeolite MER can only be obtained with the optimized KOH/SiO₂ and H₂O/SiO₂.With this method,the synthesis period of zeolite MER is greatly reduced,which might be applied to the synthesis of other industrially important zeolites in a shortened time.

Key words: zeolite, hydrothermal synthesis, phase transition, zeolite Y, zeolite MER

Cite this article

Hu Chengyu, Yan Wenfu, Xu Ruren. Phase Transition Behavior of Zeolite Y under Hydrothermal Conditions[J]. Acta Chim. Sinica, 2017, 75(7): 679-685.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Xu, R. R.; Pang, W. Q.; Yu, J. H.; Huo, Q. S.; Chen, J. S. Chemistry of Zeolites and Related Porous Materials:Synthesis and Structure, John Wiley & Sons, Ltd, Singapore, 2010.
[2] Kulprathipanja, S. Zeolites in Industrial Separation and Ca-talysis, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, 2010.
[3] Cejka, J.; Corma, A.; Zones, S. Zeolites and Catalysis——Synthesis, Reactions and Applications, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, 2010.
[4] Vermeiren, W.; Gilson, J. P. Top. Catal. 2009, 52, 1131.
[5] Chester, A. W.; Derouane, E. G. Zeolite Characterization and Catalysis:A Tutorial, Springer, New York, 2009.
[6] Wu, X.; Hu, C.; Zhao, G. Q.; Yuan, Y.; Zhu, Z. R. Chin. J. Chem. 2016, 34, 1291.
[7] Li, Y. C.; Wang, H.; Dong, M.; Li, J. F.; Wang, G. F.; Qin, Z. F.; Fan, W. B.; Wang, J. G. Acta Chim. Sinica 2016, 74, 529. (李艳春, 王浩, 董梅, 李俊汾, 王国富, 秦张峰, 樊卫斌, 王建国, 化学学报, 2016, 74, 529.)
[8] Liang, D.; Li, Z. Q.; Li, P.; Chen, Y. H.; Zhang, S. M.; Wang, Y. G. Chin. J. Chem. 2015, 33, 1389.
[9] Moliner, M.; Martínez, C.; Corma, A. Chem. Mater. 2014, 26, 246.
[10] Corma, A.; Davis, M. E. ChemPhysChem 2004, 5, 304.
[11] Sun, M. L.; Zhao, T. B.; Wang, J.; Ma, Z. F.; Li, F. Y. Chin. J. Chem. 2015, 33, 1057.
[12] ?ejka, J.; Centi, G.; Perez-Pariente, J.; Roth, W. J. Catal. Today 2012, 179, 2.
[13] Morris, R. E. Top. Catal. 2010, 53, 1291.
[14] Coronas, J. Chem. Eng. J. 2010, 156, 236.
[15] Meng, X. J.; Xiao, F. S. Chem. Rev. 2014, 114, 1521.
[16] Cundy, C. S.; Cox, P. A. Microporous Mesoporous Mater. 2005, 82, 1.
[17] Lee, H.; Zones, S. I.; Davis, M. E. J. Phys. Chem. B 2005, 109, 2187.
[18] Herr, G. T. J. Phys. Chem. 1966, 70, 1047.
[19] Ji, Y. Y.; Wang, Y. Q.; Xie, B.; Xiao, F. S. Comments Inorg. Chem. 2016, 36, 1.
[20] Mou, Q.; Li, N.; Xiang, S. H. Microporous Mesoporous Mater. 2015, 212, 73.
[21] Imai, H.; Hayashida, N.; Yokoi, T.; Tatsumi, T. Microporous Mesoporous Mater. 2014, 196, 341.
[22] Cheng, X. W.; Mao, J. J.; Lv, X. C.; Hua, T.; Cheng, X. P.; Long, Y. C.; Tang, Y. J. Mater. Chem. A 2014, 2, 1247.
[23] Xie, B.; Song, J. W.; Ren, L. M.; Ji, Y. Y.; Li, J. X.; Xiao, F. S. Chem. Mater. 2008, 20, 4533.
[24] Bouizi, Y.; Paillaud, J. L.; Simon, L.; Valtchev, V. Chem. Mater. 2007, 19, 652.
[25] Kubota, Y.; Maekawa, H.; Miyata, S.; Tatsumi, T.; Sugi, Y. Mi-croporous Mesoporous Mater. 2007, 101, 115.
[26] Maekawa, H.; Kubota, Y.; Sugi, Y. Chem. Lett. 2004, 33, 1126.
[27] Zones, S. I.; Nakagawa, Y. Microporous Mater. 1994, 2, 557.
[28] Itabashi, K.; Kamimura, Y.; Iyoki, K.; Shimojima, A.; Okubo, T. J. Am. Chem. Soc. 2012, 134, 11542.
[29] Kamimura, Y.; Iyoki, K.; Elangovan, S. P.; Itabashi, K.; Shimojima, A.; Okubo, T. Microporous Mesoporous Mater. 2012, 163, 282.
[30] Zhang, H. Y.; Yang, C. G.; Meng, X. J.; Xiao, F. S. Acta Chim. Sinica 2012, 70, 2387. (张海燕, 杨承广, 孟祥举, 肖丰收, 化学学报, 2012, 70, 2387.)
[31] Zhou, R. F.; Li, Y. Q.; Liu, B.; Hu, N.; Chen, X. S.; Kita, H. Mi-croporous Mesoporous Mater. 2013, 179, 128.
[32] Yu, Q.; Zhang, Q.; Liu, J.; Li, C.; Cui, Q. CrystEngComm 2013, 15, 7680.
[33] Iyoki, K.; Takase, M.; Itabashi, K.; Muraoka, K.; Chaikittisilp, W.; Okubo, T. Microporous Mesoporous Mater. 2015, 215, 191.
[34] Zhang, Z. Z.; Qin, B.; Zhang, X. W.; Ling, F. X.; Sun, W. F.; Fang, X. C. J. Porous Mater. 2013, 20, 515.
[35] Nagase, T.; Kiyozumi, Y.; Nemoto, Y.; Hirano, N.; Hasegawa, Y.; Ikeda, T.; Inoue, T.; Nishide, T.; Mizukami, F. Microporous Mesoporous Mater. 2009, 126, 107.
[36] Pan, H. H.; Pan, Q. X.; Zhao, Y. S.; Luo, Y. B.; Shu, X. T.; He, M. Y. Ind. Eng. Chem. Res. 2010, 49, 7294.
[37] Xu, Q. H.; Gong, Y. J.; Xu, W. J.; Xu, J.; Deng, F.; Dou, T. J. Colloid Interface Sci. 2011, 358, 252.
[38] Wang, L.; Tian, P.; Yuan, Y.; Yang, M.; Fan, D.; Zhou, H.; Zhu, W.; Xu, S.; Liu, Z. Microporous Mesoporous Mater. 2014, 196, 89.
[39] Yu, Q. J.; Li, C. Y.; Tang, X. L.; Yi, H. H. J. Porous Mater. 2016, 23, 273.
[40] Martin, N.; Moliner, M.; Corma, A. Chem. Commun. 2015, 51, 9965.
[41] Nakazawa, N.; Inagaki, S.; Kubota, Y. Chem. Lett. 2016, 45, 919.
[42] Jun, J. W.; Khan, N. A.; Seo, P. W.; Kim, C. U.; Kim, H. J.; Jhung, S. H. Chem. Eng. J. 2016, 303, 667.
[43] Itakura, M.; Oumi, Y.; Sadakane, M.; Sano, T. Mater. Res. Bull. 2010, 45, 646.
[44] Jon, H.; Takahashi, S.; Sasaki, H.; Oumi, Y.; Sano, T. Mi-croporous Mesoporous Mater. 2008, 113, 56.
[45] Inagaki, S.; Tsuboi, Y.; Nishita, Y.; Syahylah, T.; Wakihara, T.; Kubota, Y. Chem. Eur. J. 2013, 19, 7780.
[46] Jon, H.; Ikawa, N.; Oumi, Y.; Sano, T. Chem. Mater. 2008, 20, 4135.
[47] Jon, H.; Nakahata, K.; Lu, B. W.; Oumi, Y.; Sano, T. Microporous Mesoporous Mater. 2006, 96, 72.
[48] Sasaki, H.; Jon, H.; Itakura, M.; Inoue, T.; Ikeda, T.; Oumi, Y.; Sano, T. J. Porous Mater. 2009, 16, 465.
[49] Zones, S. I.; Nakagawa, Y. Stud. Surf. Sci. Catal. 1995, 97, 45.
[50] Goel, S.; Zones, S. I.; Iglesia, E. Chem. Mater. 2015, 27, 2056.
[51] Van Tendeloo, L.; Gobechiya, E.; Breynaert, E.; Martens, J. A.; Kirschhock, C. E. Chem. Commun. 2013, 49, 11737.
[52] Takata, T.; Tsunoji, N.; Takamitsu, Y.; Sadakane, M.; Sano, T. Microporous Mesoporous Mater. 2016, 225, 524.
[53] Honda, K.; Yashiki, A.; Itakura, M.; Ide, Y.; Sadakane, M.; Sano, T. Microporous Mesoporous Mater. 2011, 142, 161.
[54] Honda, K.; Yashiki, A.; Sadakane, M.; Sano, T. Microporous Mesoporous Mater. 2014, 196, 254.
[55] Koningsveld, H. V. Compendium of Zeolite Framework Types Building Schemes and Type Characteristics, Elsevier, Amsterdam, 2007.
[56] Kim, S. H.; Kim, S. D.; Kim, Y. C.; Kim, C. S.; Hong, S. B. Mi-croporous Mesoporous Mater. 2001, 42, 121.
[57] Hasegawa, Y.; Nagase, T.; Kiyozumi, Y.; Mizukami, F. Sep. Purif. Technol. 2010, 73, 25.
[58] Nagase, T.; Kiyozumi, Y.; Hasegawa, Y.; Inoue, T.; Ikeda, T.; Mizukami, F. Chem. Lett. 2007, 36, 594.
[59] Skofteland, B. M.; Ellestad, O. H.; Lillerud, K. P. Microporous Mesoporous Mater. 2001, 43, 61.

水热条件下Y型沸石的转晶行为

Phase Transition Behavior of Zeolite Y under Hydrothermal Conditions

PDF

Supporting Info.

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yuqing Shi, Mingzhu Chu, Bo Han, Haojie Ma, Ran Li, Xueyan Hou, Yuqi Zhang, Ji-Jiang Wang. Smart Two-dimensional Photonic Crystal Hydrogel for Accurate Detection of Hg²⁺ [J]. Acta Chimica Sinica, 2024, 82(1): 9-15.
[2]	Xupan Xu, Kai Fan, Shengze Zhao, Jian Li, Shan Gao, Zhongbiao Wu, Xiangju Meng, Feng-Shou Xiao. Enhanced Performance for Mesoporous Beta Zeolites Supported Pd in the Methane Catalytic Combustion^★ [J]. Acta Chimica Sinica, 2023, 81(9): 1108-1112.
[3]	Mei Hong, Jinqiang Gao, Tong Li, Shihe Yang. In-situ Etching Strategy for Manipulation of Hierarchical Zeolite and Its Application^★ [J]. Acta Chimica Sinica, 2023, 81(8): 937-948.
[4]	Chen Jian, Cai Zhuoer, Jiao Shulin, Zhang Xiang, Hu Jinzhong, Liu Min, Sun Baiwang, Hua Xiuni. A Thermally Responsive Dielectric Switchable Zero-Dimensional Organic-Inorganic Hybrid Material: (C₃H₆NH₂)₂CoCl₄ [J]. Acta Chimica Sinica, 2023, 81(5): 480-485.
[5]	Junchang Chen, Mingxing Zhang, Shuao Wang. Research Progress of Synthesis Methods for Crystalline Porous Materials [J]. Acta Chimica Sinica, 2023, 81(2): 146-157.
[6]	Hongdan Zhang, Xinyu Lan, Peng Cheng. Advances in Hydroxyl Free Radical Assisted Synthesis of Zeolite [J]. Acta Chimica Sinica, 2023, 81(1): 100-110.
[7]	Xufa He, Kangle Jia, Longfei Yu, Mingjie Liu, Xiaoshan Zheng, Huanling Li, Jinlan Xin, Linjia Huang. pH-Responsive Pickering Emulsions Synergistically Stabilized by Maleopimaric Acid and Alumina Nanoparticles [J]. Acta Chimica Sinica, 2022, 80(6): 765-771.
[8]	Huibo Jiang, Shanshan Lin, Yuping Xu, Jing Sun, Zhongning Xu, Guocong Guo. Lewis Acid in NaY Zeolite High Selectively Catalyze Methanol to Dimethoxymethane via Methyl Nitrite^※ [J]. Acta Chimica Sinica, 2022, 80(4): 438-443.
[9]	Lei He, Qiuxiang Yao, Ming Sun, Xiaoxun Ma. Progress in Preparation and Catalysis of Two-dimensional (2D) and Three-dimensional (3D) Zeolites [J]. Acta Chimica Sinica, 2022, 80(2): 180-198.
[10]	Yumiao Lu, Wei Chen, Yanlei Wang, Feng Huo, Yihui Dong, Li Wei, Hongyan He. Research Progress on the Preparation and Properties of Two Dimensional Structure of Ionic Liquids [J]. Acta Chimica Sinica, 2021, 79(4): 443-458.
[11]	Aodi Shi, Si Chen, Songsheng Zheng, Zhaolin Wang. Correlation between the Pseudo-Capacitance Behavior and the Second-Order Phase Transition in the Li⁺ Insertion/Desertion in Cu₃Si [J]. Acta Chimica Sinica, 2021, 79(12): 1511-1517.
[12]	Zhang Mengting, Yan Tingting, Dai Weili, Guan Naijia, Li Landong. Zeolite Stabilized Isolated Molybdenum Species for Catalytic Oxidative Desulfurization [J]. Acta Chimica Sinica, 2020, 78(12): 1404-1410.
[13]	Zhao Jiongpeng, Wang Weiwei, Han Songde, Li Quanwen, Li Na, Liu Fuchen, Bu Xianhe. Construction, Magnetic and Dielectric Properties of Mixed-Valence Iron Formate with Methylammonium Guest [J]. Acta Chimica Sinica, 2020, 78(11): 1223-1228.
[14]	Wang Haixu, Yang Guang, Cheng Tianshu, Wang Ning, Sun Rong, Wong Ching-Ping. Recent Advances in Hydrothermal Synthesis of Low Dimensional Boron Nitride Nanostructures [J]. Acta Chim. Sinica, 2019, 77(4): 316-322.
[15]	Feng Aihu, Yu Yang, Yu Yun, Song Lixin. Recent Progress in the Removal of Volatile Organic Compounds by Zeolite and Its Supported Catalysts [J]. Acta Chim. Sinica, 2018, 76(10): 757-773.