Applications of Metal-organic Frameworks (MOFs) Materials in Lithium-ion Battery/Lithium-metal Battery Electrolytes

doi:10.6023/A20090442

Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (2): 139-145.DOI: 10.6023/A20090442 Previous Articles Next Articles

Special Issue: 多孔材料：金属有机框架(MOF)

Perspective

金属有机框架(MOFs)材料在锂离子电池及锂金属电池电解液中的应用

常智^b^,^c, 乔羽^b, 杨慧军^b^,^c, 邓瀚^b^,^c, 朱星宇^b^,^c, 何平^a, 周豪慎^a^,^b^,^c^,^*()

a 南京大学储能材料与技术中心现代工程与应用科学学院固体微结构国家重点实验室人工微结构科学与技术协同创新中心中国南京 210093
b 产业技术综合研究所(AIST) 能源技术研究所筑波305-8568 日本
c 日本国立筑波大学(University of Tsukuba) 系统与信息工程研究生院筑波305-8573 日本

投稿日期:2020-09-23 发布日期:2020-11-10
通讯作者: 周豪慎

作者简介:

常智, 2017年4月于南京航空航天大学材料科学与技术学院取得硕士学位. 2020年9月于日本国立筑波大学和日本产业技术综合研究所(AIST)取得博士学位. 主要研究方向为高比能锂金属电池体系研发, 具体涉及: 锂-硫电池、锂金属负极以及相应的电解液/质体系.

周豪慎, 1985年获南京大学物理系学士学位, 1994年获日本国立东京大学博士学位. 现任南京大学现代工程与应用科学学院教授, 长江学者. 兼任日本国立产业技术综合研究所(AIST)首席研究员、日本国立筑波大学教授. 兼任Science Bulletin常务副主编, Energy Storage Materials副主编. 长期从事能源材料、气体传感器、太阳能电池、超级电容器、二次电池、锂离子电池、锂硫电池、锂空气电池、下一代储能器件等的研究和开发.

* E-mail: hszhou@nju.edu.cn

基金资助:
国家重点研究发展计划(2016YFB0100203); 国家自然科学基金(21673166); 国家自然科学基金(21633003); 国家自然科学基金(u1801252)

Applications of Metal-organic Frameworks (MOFs) Materials in Lithium-ion Battery/Lithium-metal Battery Electrolytes

Zhi Chang^b^,^c, Yu Qiao^b, Huijun Yang^b^,^c, Han Deng^b^,^c, Xingyu Zhu^b^,^c, Ping He^a, Haoshen Zhou^a^,^b^,^c^,^*()

a Center of Energy Storage Materials & Technology, College of Engineering and Applied Sciences, National Laboratory of Solid State Microstructures, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
b Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 305-8568, Japan
c Graduate School of System and Information Engineering, University of Tsukuba, 1-1-1, Tennoudai, Tsukuba 305-8573, Japan

Received:2020-09-23 Published:2020-11-10
Contact: Haoshen Zhou
Supported by:
National Key Research and Development Program of China(2016YFB0100203); National Natural Science Foundation of China(21673166); National Natural Science Foundation of China(21633003); National Natural Science Foundation of China(u1801252)

This perspective summarizes the research progress of metal-organic frameworks (MOFs) materials used in lithium-ion battery/lithium-metal electrolytes. By summarizing several long-standing defects of lithium-ion batteries/lithium- metal batteries, MOFs materials are subsequently used as ion sieves, artificial electrode protective layers, quasi-solid electrolytes and used to adjust electrolytes’ configuration, the performance of batteries has been significantly improved. Finally, based on the characteristics of MOFs materials themselves, this perspective also makes a reasonable forward-looking outlook on the subsequent applications of MOFs materials in the field of electrochemical energy storage.

Key words: metal-organic framework (MOF), lithium-ion battery, ion sieves, negative electrode protection, quasi-solid electrolyte

Cite this article

Zhi Chang, Yu Qiao, Huijun Yang, Han Deng, Xingyu Zhu, Ping He, Haoshen Zhou. Applications of Metal-organic Frameworks (MOFs) Materials in Lithium-ion Battery/Lithium-metal Battery Electrolytes[J]. Acta Chimica Sinica, 2021, 79(2): 139-145.

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Fig. & Tab. 5

Figure 1. Metal-organic frameworks (MOFs) act as an ion sieves to improve the electrochemical performance of lithium-sulfur (Li-S) batteries. (a~c) CuBTC MOF used as a Li-S battery separator to inhibit lithium polysulfide shuttling and improve the electrochemical performance of Li-S batteries[37]. Reprinted with permission from ref. [37], copyright 2016 Nature Publishing Group. (d~f) Two-dimensional layered conductive Ni3(HITP)2 MOF is used as a lithium polysulfide molecular sieve to improve the cycle stability of Li-S batteries[38]. Reprinted with permission from ref. [38], copyright 2018 Wiley-VCH.

Figure 2. MOF acts as an ion sieves to improve the electrochemical performance of lithium ion batteries. (a~c) CuBTC MOF is used as a separator to separate two different electrolytes, inhibited the mutual shuttle of electrolytes, realized the battery design of combined electrolytes, and finally improved the electrochemical performance of LNMO//Graphite battery[41]. Reprinted with permission from ref. [41], copyright 2018 Wiley-VCH.

Figure 3. (a) Schematic diagram of the growth of lithium dendrites: a schematic diagram of a lithium metal electrode after cycling using the original electrolyte (top); a schematic diagram of a lithium metal electrode after cycling with a MOF protective layer (bottom). (b) Schematic diagram of lithium ion conduction inside MOF channels. (c) Comparison of electrochemical performance of Li//Li symmetric batteries using conventional electrolyte and MOF protective layer and (d) comparison of the corresponding electrode morphologies after cycling[46]. Reprinted with permission from ref. [46], copyright 2018 Wiley- VCH.

Figure 4. The metal organic framework serves as a quasi-solid electrolyte to improve the electrochemical performance of lithium metal batteries. (a, b) UiO-67 MOF serves as a lithium ion conductor to improve the electrochemical performance of LiCoO2//Li batteries[47]. Reprinted with permission from ref. [47], copyright 2018 Elsevier. (c~e) MOF is used as a quasi-solid electrolyte for LiFePO4//Li batteries after being filled with part of the liquid electrolyte[48]. Reprinted with permission from ref. [48], copyright 2018 Wiley-VCH.

Figure 5. Raman spectrum of electrolyte in MOF (ZIF-7) channel. (a) A schematic diagram of DME molecules with different configurations and the corresponding stability under different circumstances, and Raman spectra of (b) DME molecules, (c) Li-DME interaction and (d) TFSI-. (e) A schematic diagram of the structure of the electrolyte in the MOF hole drawn according to the experimental results. (f) Linear sweep volt-ampere (LSV) curve results of each electrolyte. (g) The electrochemical cycling performance of NCM-811//Li full-cell based on limited metal lithium (two times excess Li) using "Li+ desolvated ether-based electrolyte"[49]. Reprinted with permission from ref. [49], copyright 2020 Cell Press.

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金属有机框架(MOFs)材料在锂离子电池及锂金属电池电解液中的应用

Applications of Metal-organic Frameworks (MOFs) Materials in Lithium-ion Battery/Lithium-metal Battery Electrolytes

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