Research Progress of Bis(terpyridine)-Ruthenium(II) Complexes★

doi:10.6023/A23050201

Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (10): 1447-1461.DOI: 10.6023/A23050201 Previous Articles Next Articles

Special Issue: 庆祝《化学学报》创刊90周年合辑

Review

双三联吡啶钌配合物的研究进展^★

李志凯^a, 罗思琪^a, 陈敏^a, 於秀君^a^,^*(), 李霄鹏^a^,^b^,^*()

a 深圳大学化学与环境工程学院广东深圳 518060
b 深圳大学临床医学院深圳大学总医院广东深圳 518055

投稿日期:2023-05-04 发布日期:2023-06-27

作者简介:

李志凯, 2014年和2020年于苏州大学分别获得学士和博士学位, 2018~2019年在美国南佛罗里达大学联合培养, 2020~2023年在深圳大学从事博士后研究, 目前为深圳大学化学与环境工程学院副研究员. 主要研究方向为金属-超分子聚合物的可控制备.

於秀君, 深圳大学助理教授、特聘副研究员, 2009年和2012年于郑州大学分别获得学士学位和硕士学位, 2016年于德国法兰克福大学获博士学位, 2017~2020年在韩国基础科学研究院从事博士后研究, 2021年入职深圳大学. 主要研究方向为超分子自组装和有机-无机杂化稀土功能材料, 目前已在J. Am. Chem. Soc., Angew. Chem. Int. Ed和Chem、Adv. Mater.等知名期刊发表学术论文30余篇, 曾获“韩国基础科学研究院杰出研究奖”和“青年配位化学家海报奖”, 主持国家自然科学基金委员会青年科学基金项目和广东省普通高校青年创新人才项目, 是2022年度广东省“珠江人才计划”引进创新创业团队的核心成员之一.

李霄鹏, 深圳大学特聘教授, 2004年于郑州大学获化学学士学位, 2008年于美国克里夫兰州立大学获化学博士学位, 2009~2012年在阿克伦大学从事博士后研究. 2012年起在德克萨斯州立大学任助理教授, 2016年转入南佛罗里达大学, 2019年晋升终身副教授, 2020年入职深圳大学任“腾讯创始人校友团队”冠名特聘教授. 主要研究兴趣集中在质谱仪器研制及表征技术, 配位键自组装超分子化学和超分子材料, 在Science, Nature和Nature Chem.等学术期刊发表论文240余篇. 曾获美国Cottrell学者奖(2015年)、中美华人化学与化学生物学教授协会杰出青年教授奖(2017年)、英国皇家化学会会士(2017年)、英国皇家化学会Cram Lehn Pedersen超分子化学奖(2019年)、国家自然科学基金委杰出青年基金(2021年)、中国化学会超分子化学青年创新学术讲座奖(2021年)、珠江团队领军人才(2022年)等荣誉和奖项.

^★庆祝《化学学报》创刊90周年.

基金资助:
国家自然科学基金(22125106); 国家自然科学基金(22101184); 深圳市优秀科技创新人才培养项目(RCJC20200714114556036); 广东省“珠江人才计划”引进创新创业团队项目(2021ZT09C289)

Research Progress of Bis(terpyridine)-Ruthenium(II) Complexes^★

Zhikai Li^a, Siqi Luo^a, Min Chen^a, Xiujun Yu^a(), Xiaopeng Li^a^,^b()

a College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518060
b Shenzhen University General Hospital, Shenzhen University Clinical Medical Academy, Shenzhen, Guangdong 518055

Received:2023-05-04 Published:2023-06-27
Contact: *E-mail: xiujunyu@szu.edu.cn; xiaopengli@szu.edu.cn
About author:
^★Dedicated to the 90th anniversary of Acta Chimica Sinica.
Supported by:
National Natural Science Foundation of China(22125106); National Natural Science Foundation of China(22101184); the Developmental Fund for Science and Technology of Shenzhen(RCJC20200714114556036); the Guangdong Province “Pearl River Talents Plan” Innovative and Entrepreneurial Teams Project(2021ZT09C289)

Over the past decades, thanks to the excellent directivity and stability of coordination bond between terpyridine and ruthenium ions, a large number of bis(terpyridine)-ruthenium(II) complexes have been constructed and reported through three synthetic strategies, i.e., direct coordination assembly, stepwise coordination assembly and post-assembly modification. Moreover, due to the unique photoelectric properties of bis(terpyridine)-ruthenium(II) complexes, these structures have shown great promise for applications in photothermal conversion, photovoltaic materials, electronic memory and anion exchange membranes. Therefore, this review summarizes the research progress of bis(terpyridine)-ruthenium(II) complexes with particular focus on small molecules, discrete supramolecules and polymers. Furthermore, current challenges and opportunities are briefly discussed.

Key words: complex compound, terpyridine, ruthenium complex, coordination supramolecule, metallopolymer

Cite this article

Zhikai Li, Siqi Luo, Min Chen, Xiujun Yu, Xiaopeng Li. Research Progress of Bis(terpyridine)-Ruthenium(II) Complexes^★[J]. Acta Chimica Sinica, 2023, 81(10): 1447-1461.

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Fig. & Tab. 12

Figure 1. Conformational changes before and after the coordination of pyridine rings in the terpyridine group

Figure 2. Three synthetic strategies of bis(terpyridine)-ruthenium(II) complexes

Figure 3. (a) The bite angles of ∠N-Ru-N in the bis(terpyridine)- ruthenium(II) complexes. (b) Two strategies for enhancing the luminescence properties of bis(terpyridine)-ruthenium(II) complexes. (c) Representative structure of bis(terpyridine)-ruthenium(II) complexes constructed by expanded terpyridine groups. (d) Structure of neutral bis(terpyridine)-ruthenium(II) complexes obtained from reductive electrocrystallization

Figure 4. Homonuclear coordination supramolecules based on bis(terpyridine)-ruthenium(II) complexes. The “Nanosphere” structure was reproduced with permission[150]. Copyright 2014, American Chemical Society

Figure 5. The design (A) and synthesis (B) of the ligands for G3 Pascal triangle and Sierpiński triangle and their self-assembly (C) through retrosynthetic analysis[155]

Figure 6. (a) Construction of coordination supramolecules based on the shape complementarity of triangular elements. (b) Enhancing the construction controllability of coordination supramolecules based on hexagonal elements through increasing the density of coordination sites. (c) Stabilizing the coordination supramolecules constructed from rhomboid elements via using templates or embedded triangular and hexagonal elements

Figure 7. Construction of complex discrete supramolecules via sequence-specific module strategy[83]

Figure 8. Representative multidimensional mass spectrometry (MS) of discrete coordination supramolecules, including electrospray ionization-MS (ESI-MS), ion mobility-MS (IM-MS) and tandem MS (gMS2)[185]

Figure 9. Structure and corresponding STM image of hexagonal grid-shaped heteronuclear coordination supramolecules based on bis(terpyridine)-ruthenium(II) complexes. Reproduced with permission[184]. Copyright 2020, Springer Nature

Figure 10. (a) The preparation of cyclic brush polymers and the corresponding TEM and AFM images. Reproduced with permission[201]. Copyright 2013, American Chemical Society. (b) The preparation of hyperbranched dendritic polymers and the corresponding TEM images as well as the electronic memory performance. Reproduced with permission[200]. Copyright 2017, American Chemical Society. (c) The preparation of cross-linked polymers for anion exchange membranes. Reproduced with permission[71]. Copyright 2012, American Chemical Society

Figure 11. (a) The preparation of polymers with triangular and hexamer supramolecules as the repeat units. Reproduced with permission[203]. Copyright 2020, American Chemical Society. (b) The preparation of metal-organic frameworks based on bis(terpyridine)-ruthenium(II) complexes. Reproduced with permission[80]. Copyright 2019, American Chemical Society

Figure 12. (a) The structure of bis(terpyridine)-ruthenium(II) complexes based polymers PS20-Ru-PEO70 and the corresponding GPC curves at different conditions. Reproduced with permission[212]. Copyright 2003, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. (b) The structure of bis(terpyridine)-ruthenium(II) complexes based polymers with the building blocks of triangular supramolecule as the side chains and the corresponding MALDI-TOF mass spectra. Reproduced with permission[213]. Copyright 2022, American Chemical Society

双三联吡啶钌配合物的研究进展^★

Research Progress of Bis(terpyridine)-Ruthenium(II) Complexes^★

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双三联吡啶钌配合物的研究进展★

Research Progress of Bis(terpyridine)-Ruthenium(II) Complexes★

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双三联吡啶钌配合物的研究进展^★

Research Progress of Bis(terpyridine)-Ruthenium(II) Complexes^★