Studies on the identification and syntheses of insect pheromones XXIV: Synthesis of (7R,8S)-(+)- and (7S,8R)-(-)-sex pheromone of gypsy moth and stereochemistry of \b-hydroxysilane

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (1): 40-46. Previous Articles Next Articles

Original Articles

昆虫信息素的结构鉴定和合成XXIV: (TR,8S)-(+)-和(7S,8R)-(-)-午毒蛾性信息素的合成及β-羟基硅烷的立体化学

周维善;王志民;林国强

中国科学院上海有机化学研究所

发布日期:1987-01-15

Studies on the identification and syntheses of insect pheromones XXIV: Synthesis of (7R,8S)-(+)- and (7S,8R)-(-)-sex pheromone of gypsy moth and stereochemistry of \b-hydroxysilane

ZHOU WEISHAN;WANG ZHIMIN;LIN GUOQIANG

Published:1987-01-15

Abstract

Title compounds I and II [R = Me2CH(CH2)4] were prepared starting from condensation of I and II (R = CHO) with Me3SiCHLiCH2CH2CHMe2. The absolute configuration of intermediates III and IV was determine

Key words: EPOXIDATION REACTION, HOMOGENEOUS CATALYSIS, HYDROGENATION, ELIMINATION REACTION, STEREOCHEMISTRY, EPOXIDE, ALDEHYDES, SILANE P, INSECT HORMONE, SEX PHEROMONE

CLC Number:

O629
TQ45

Cite this article

ZHOU WEISHAN;WANG ZHIMIN;LIN GUOQIANG. Studies on the identification and syntheses of insect pheromones XXIV: Synthesis of (7R,8S)-(+)- and (7S,8R)-(-)-sex pheromone of gypsy moth and stereochemistry of \b-hydroxysilane[J]. Acta Chimica Sinica, 1987, 45(1): 40-46.

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昆虫信息素的结构鉴定和合成XXIV: (TR,8S)-(+)-和(7S,8R)-(-)-午毒蛾性信息素的合成及β-羟基硅烷的立体化学

Studies on the identification and syntheses of insect pheromones XXIV: Synthesis of (7R,8S)-(+)- and (7S,8R)-(-)-sex pheromone of gypsy moth and stereochemistry of \b-hydroxysilane

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