The vibrational spectra of organometallic compounds I: On the calculation of force constant for metallocene

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (2): 131-136. Previous Articles Next Articles

Original Articles

有机金属化合物的振动光谱I:环戊二烯夹心化合物的力常数计算

冯艳;刘举正;赵文运;张刚;梁映秋

吉林大学理论化学研究所

发布日期:1988-02-15

The vibrational spectra of organometallic compounds I: On the calculation of force constant for metallocene

FENG YAN;LIU JUZHENG;ZHAO WENYUN;ZHANG GANG;LIANG YINGQIU

Published:1988-02-15

Abstract

On the basis of FT-IR and laser Raman spectra of (h5-Cp)2M (Cp = C5H5; M = Mn, Fe, Ru), the force constants of the given compounds have been calculated by a G-F matrix program and the nature of the Cp-M chem. bond has been discussed.

Key words: CALCULATION, CYCLOPENTADIENE P, SPECTROGRAPHIC ANALYSIS, ORGANOMETALLIC COMPOUNDS, METALLOCENES, VIBRATIONAL SPECTRA, FORCE CONSTANT

CLC Number:

O627

Cite this article

FENG YAN;LIU JUZHENG;ZHAO WENYUN;ZHANG GANG;LIANG YINGQIU. The vibrational spectra of organometallic compounds I: On the calculation of force constant for metallocene[J]. Acta Chimica Sinica, 1988, 46(2): 131-136.

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有机金属化合物的振动光谱I:环戊二烯夹心化合物的力常数计算

The vibrational spectra of organometallic compounds I: On the calculation of force constant for metallocene

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