Study of nw compounds containing both phosphorus and pyrethroid skeleton I: Synthesis of 3-[1'-(substituted phosphinyloxy)-2'-chlorovinyl]-2,-dimethylcyclopropane carboxylate and study of its geometrical isomer

Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (4): 388-392. Previous Articles Next Articles

Original Articles

含磷拟除虫菊酯的研究I:3-[1'-磷(膦)酸酯基-2'-氯代乙烯基]-2,-二甲基环丙烷羧酸酯的合成及其几何异构体的研究

陈茹玉;邵瑞链;张和胜;王水平

南开大学元素有机化学研究所

发布日期:1990-04-15

Study of nw compounds containing both phosphorus and pyrethroid skeleton I: Synthesis of 3-[1'-(substituted phosphinyloxy)-2'-chlorovinyl]-2,-dimethylcyclopropane carboxylate and study of its geometrical isomer

CHEN RUYU;SHAO RUILIAN;ZHANG HESHEN;WANG SHUIPING

Published:1990-04-15

Abstract

The title compounds were prepared and their structures were established. The steric factor of the phosphites exhibits significant influence on the E, Z ratio of the reaction products.

Key words: INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, MOLECULAR STRUCTURE, MASS SPECTROGRAPHY, SYNTHETIC PYRETHROID-INSECTICIDES, CYCLOPROPANE P, CARBOXYLIC ACID ESTER, ETHYLENE P, PROTON MAGNETIC RESONANCE SPECTROMETRY, ISOMER

CLC Number:

O621

Cite this article

CHEN RUYU;SHAO RUILIAN;ZHANG HESHEN;WANG SHUIPING. Study of nw compounds containing both phosphorus and pyrethroid skeleton I: Synthesis of 3-[1'-(substituted phosphinyloxy)-2'-chlorovinyl]-2,-dimethylcyclopropane carboxylate and study of its geometrical isomer[J]. Acta Chimica Sinica, 1990, 48(4): 388-392.

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含磷拟除虫菊酯的研究I:3-[1'-磷(膦)酸酯基-2'-氯代乙烯基]-2,-二甲基环丙烷羧酸酯的合成及其几何异构体的研究

Study of nw compounds containing both phosphorus and pyrethroid skeleton I: Synthesis of 3-[1'-(substituted phosphinyloxy)-2'-chlorovinyl]-2,-dimethylcyclopropane carboxylate and study of its geometrical isomer

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