Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (4): 393-398. Previous Articles     Next Articles

Original Articles

含磷拟除虫菊酯的研究II:含笼状双环磷的取代环丙烷羧酸酯的合成及反应研究

邵瑞链;王水平;成俊然   

  1. 南开大学元素有机化学研究所
  • 发布日期:1990-04-15

Study of novel compounds containing both phosphorus and pyrethroid skeleton II: Synthesis of compounds containing bicyclic phosphate and 3-substituted-2,2-dimethylcyclopropane carboxylate and study of its reaction

SHAO RUILIAN;WANG SHUIPING;CHENG JUNRAN   

  • Published:1990-04-15

The title esters can be prepared in high yield and excellent purity by the reaction of various chrysanthemic chlorides and 4-hydroxymethyl-1-phospha-2,6,7-trioxabiyclo[2.2.2]octane-1-sulfide (oxide) in the presence of base.

Key words: CONDENSATION REACTION, CARBOXYLIC ACID, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, MASS SPECTROGRAPHY, SYNTHETIC PYRETHROID-INSECTICIDES, PYROLYSIS, CARBOXYLIC ACID ESTER, PROTON MAGNETIC RESONANCE SPECTROMETRY, OXYGEN HETEROCYCLICS

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