Formation and sructure of [Co1(CO)(dppe-P, P')2]2.[Co^1^12(u-dppeo)Cl6].2CH3OH

Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (8): 770-777. Previous Articles Next Articles

Original Articles

[Co^I(CO)(dppe-P,P')2]2[Co2^I^I(μ-dppeo)Cl6].2CH3OH的合成和结构

姚心侃;王宏根;张正之;王序昆;席真

南开大学中心实验室;南开大学元素有机化学研究所

发布日期:1990-08-15

Formation and sructure of [Co1(CO)(dppe-P, P')2]2.[Co^1^12(u-dppeo)Cl6].2CH3OH

YAO XINKAN;WANG HONGGEN;ZHANG ZHENGZHI;WANG XUKUN;XI ZHEN

Published:1990-08-15

Abstract

Ph2P(O)CH2CH2P(O)Ph2] ion-pair complex with mixed valence states was synthesized. Its structure was determine by x-ray diffraction. Triclinic, space group P1 , a 11.761(3), b 12.860(2), c 21.428(3) ? a 81.45(2), b 82.47(2), g 79.84(2)? Z = 1, R = 0.065, Rw = 0.075. CoI and CoII possess different polyhedral configurations, resp. The stability of the complex is explained by MO calculation

Key words: CRYSTAL STRUCTURE, MOLECULAR STRUCTURE, X-RAY DIFFRACTION ANALYSIS, QUANTUM CHEMISTRY, ETHANE, CARBONYL COMPOUNDS, COBALT COMPLEX, DIPHENYLPHOSPHINE, POLYNUCLEAR COMPLEX

CLC Number:

O611.662

Cite this article

YAO XINKAN;WANG HONGGEN;ZHANG ZHENGZHI;WANG XUKUN;XI ZHEN. Formation and sructure of [Co1(CO)(dppe-P, P')2]2.[Co^1^12(u-dppeo)Cl6].2CH3OH[J]. Acta Chimica Sinica, 1990, 48(8): 770-777.

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[Co^I(CO)(dppe-P,P')2]2[Co2^I^I(μ-dppeo)Cl6].2CH3OH的合成和结构

Formation and sructure of [Co1(CO)(dppe-P, P')2]2.[Co^1^12(u-dppeo)Cl6].2CH3OH

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