Dynamic calculations on the collinear hydrogen atom transfer reaction II: Vibrational deexcitation of HCl(ν=1,2,3) by Cl atoms on a reactive potential energy surface

Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (1): 1-4. Next Articles

Original Articles

氢原子共线交换反应的动力学计算 II: 在反应势能面上Cl+HCl(ν)碰撞对的振动去激

陈德展;居冠之

山东师范大学化学系;山东大学化学系

发布日期:1992-01-15

Dynamic calculations on the collinear hydrogen atom transfer reaction II: Vibrational deexcitation of HCl(ν=1,2,3) by Cl atoms on a reactive potential energy surface

CHEN DEZHAN;JU GUANZHI

Published:1992-01-15

Abstract

The reactive and nonreactive inelastic probabilities are calculated for the collisional deexcitation of vibrationally excited HCl (v = 1,2,3) by Cl aotms using a collinear exact quantum method. Both reactive and nonreactive inelstic collisions are equally effective in the deexcitation of HCl (v = 1,2,3) in good agreement with the results of R. L. Wilkins (1975). The corresponding probabilities Pvv1 are interrelated.

Key words: CALCULATION, REACTION KINETICS, REACTION KINETICS, CHLORINE, POTENTIAL ENERGY, EXCHANGE REACTION, HYDROGEN CHLORIDE, HYDROGEN ATOM, COLLISON

CLC Number:

O643

Cite this article

CHEN DEZHAN;JU GUANZHI. Dynamic calculations on the collinear hydrogen atom transfer reaction II: Vibrational deexcitation of HCl(ν=1,2,3) by Cl atoms on a reactive potential energy surface[J]. Acta Chimica Sinica, 1992, 50(1): 1-4.

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氢原子共线交换反应的动力学计算 II: 在反应势能面上Cl+HCl(ν)碰撞对的振动去激

Dynamic calculations on the collinear hydrogen atom transfer reaction II: Vibrational deexcitation of HCl(ν=1,2,3) by Cl atoms on a reactive potential energy surface

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