Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (7): 668-671. Previous Articles     Next Articles

Original Articles

交流示波极谱法中i~f-E曲线的研究 7:基于i~f-E曲线的定量分析方法

沈雪明;陈洪渊;高鸿   

  1. 南京大学化学系
  • 发布日期:1992-07-15

Investigations on i~f-E curve in cyclic derivative chronopotentiometry.pt 7:quantitative analysis based on i~f-E curves

SHEN XUEMING;CHEN HONGYUAN;GAO HONG   

  • Published:1992-07-15

Quant. anal. in cyclic derivative chronopotentiometry with if-E curve is based on measurement of the height of peak on the if-E curve. The main advantage of the method over the classical dE/dt-E curve method is in its accuracy and sensitivity. In this paper, Tl+, Pb2+, Cd2+, Zn2+, Mn2+, and Ga3+ were determine with the microcomputer-based electrochem. data acquisition system, which was constructed in the laboratory Experimental results have shown that in the if-E curve method the accuracy is 2 to 5 times better and the sensitivity is one order of magnitude higher.

Key words: OSCILLOSCOPIC POLAROGRAPHY, QUANTITATIVE ANALYSIS, ZINC, MANGANESE, CADMIUM, TITANIUM, LEAD, CURVE, GALLIUM

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