Study on the effect of the intermolecular force to the capacity ratio in HPLC by sealed particle theory

Abstract

To study the effect of the intermol. force to the capacity ratio in HPLC, the scaled particle theory and the two dimension lattice theory were resp. applied to study intermol. interaction between the solvent mols. and the solute mols. in the liquid phase and on the stationary phase. The authors also derived a quant. relationship between retention value and the intermol. force, and the equation was testified by experimentc

Key words: LIQUID CHROMATOGRAPHY, SCALED PARTICLE THEORY, STATISTICAL THERMODYNAMICS, INTERMOLECULAR INTERACTION

CLC Number:

O642

Cite this article

ZHANG WEIBING;SHI JINGJIANG. Study on the effect of the intermolecular force to the capacity ratio in HPLC by sealed particle theory[J]. Acta Chimica Sinica, 1993, 51(10): 943-949.

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