Acta Chimica Sinica ›› 1994, Vol. 52 ›› Issue (8): 763-766. Previous Articles     Next Articles

Original Articles

锂在[Mn~2O~4]中的电化学嵌入反应I.热力学性质

余爱水;吴浩青   

  1. 复旦大学化学系
  • 发布日期:1994-08-15

The electrochemical intercalation reaction of lithium into spinel phase [Mn~2O~4] I. thermodynamic behavior

YU AISHUI;WU HAOQING   

  • Published:1994-08-15

Thermodn. of Li intercalation reactions into spinel phase phase [Mn2O4] were investigated by coulombic titration with Li/LixMn2O4 intercalation cell. The functions, DG.DH, DS, were derived from the emf.(x) data and are in good agreement with the structure of [Mn2O4].

Key words: THERMODYNAMIC PROPERTIES, CRYSTAL STRUCTURE, LITHIUM, INTERCALATION REACTION

CLC Number: