Transition metal thiolato complexes as synthons II. Syntheses and structural characteristics of bidentate phosphine and bidentate thiolato complexes of cobalt and nickel

Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (1): 58-67. Previous Articles Next Articles

Original Articles

含硫过渡金属基元的反应 2: 双膦及双齿巯基混合配位钴, 镍化合物的合成和结构特征

康北笙;陈忠宁;高汉荣;周忠远;伍伯牧;麦松威;林璋

中山大学化学系;香港中文大学化学系;中国科学院福建物质结构研究所;中国科学院结构化学国家重点实验室

发布日期:1998-01-15

Transition metal thiolato complexes as synthons II. Syntheses and structural characteristics of bidentate phosphine and bidentate thiolato complexes of cobalt and nickel

KANG BEISHENG;CHEN ZHONGNING;GAO HANRONG;ZHOU ZHONGYUAN;WU BOMU;MAK THOMAS C.W.;LIN ZHANG

Published:1998-01-15

Abstract

Mononuclear complexes Co(bdt)(dppe)(1), Ni(tdt)(dppm)(2), and Ni(tsal)(dppe)(3) containing both bidentate phosphine (P-P) and bidentate thiolato (S-X, X=S, O) ligands were synthesized and structurally characterized. The metal centers are all square planar in geometry composed of SXP2 from the two ligands forming four-, five-, or six- membered chelate rings. Structural characteristics of the complexes are summarized and the resistance of these complexes to the construction into polynuclear cluster compounds is discussed.

Key words: MERCAPTO COMPOUNDS, CRYSTAL STRUCTURE, PHOSPHINE, COBALT COMPLEX, NICKEL COMPLEX, COBALT CHLORIDE, NICKEL CHLORIDE

CLC Number:

O627

Cite this article

KANG BEISHENG;CHEN ZHONGNING;GAO HANRONG;ZHOU ZHONGYUAN;WU BOMU;MAK THOMAS C.W.;LIN ZHANG. Transition metal thiolato complexes as synthons II. Syntheses and structural characteristics of bidentate phosphine and bidentate thiolato complexes of cobalt and nickel[J]. Acta Chimica Sinica, 1998, 56(1): 58-67.

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含硫过渡金属基元的反应 2: 双膦及双齿巯基混合配位钴, 镍化合物的合成和结构特征

Transition metal thiolato complexes as synthons II. Syntheses and structural characteristics of bidentate phosphine and bidentate thiolato complexes of cobalt and nickel

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